|
Photoelectrochemical Process
Photoelectrochemical processes are processes in photoelectrochemistry; they usually involve transforming light into other forms of energy. These processes apply to photochemistry, optically pumped lasers, sensitized solar cells, luminescence, and photochromism. Electron excitation Electron excitation is the movement of an electron to a higher energy state. This can either be done by photoexcitation (PE), where the original electron absorbs the photon and gains all the photon's energy or by electrical excitation (EE), where the original electron absorbs the energy of another, energetic electron. Within a semiconductor crystal lattice, thermal excitation is a process where lattice vibrations provide enough energy to move electrons to a higher energy band. When an excited electron falls back to a lower energy state again, it is called electron relaxation. This can be done by radiation of a photon or giving the energy to a third spectator particle as well. In physics there is a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photoelectrochemistry
Photoelectrochemistry is a subfield of study within physical chemistry concerned with the interaction of light with electrochemical systems. It is an active domain of investigation. One of the pioneers of this field of electrochemistry was the German electrochemist Heinz Gerischer. The interest in this domain is high in the context of development of renewable energy conversion and storage technology. Historical approach Photoelectrochemistry has been intensively studied in the 1970-80s because of the first peak oil crisis. Because fossil fuels are non-renewable, it is necessary to develop processes to obtain renewable resources and use clean energy. Artificial photosynthesis, photoelectrochemical water splitting and regenerative solar cells are of special interest in this context. The photovoltaic effect was discovered by Alexandre Edmond Becquerel. Heinz Gerischer, H. Tributsch, AJ. Nozik, AJ. Bard, A. Fujishima, K. Honda, PE. Laibinis, K. Rajeshwar, TJ Meyer, PV. Kamat, N.S ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photochemistry
Photochemistry is the branch of chemistry concerned with the chemical effects of light. Generally, this term is used to describe a chemical reaction caused by absorption of ultraviolet (wavelength from 100 to 400 nm), visible light (400–750 nm) or infrared radiation (750–2500 nm). In nature, photochemistry is of immense importance as it is the basis of photosynthesis, vision, and the formation of vitamin D with sunlight. Photochemical reactions proceed differently than temperature-driven reactions. Photochemical paths access high energy intermediates that cannot be generated thermally, thereby overcoming large activation barriers in a short period of time, and allowing reactions otherwise inaccessible by thermal processes. Photochemistry can also be destructive, as illustrated by the photodegradation of plastics. Concept Grotthuss–Draper law and Stark-Einstein law Photoexcitation is the first step in a photochemical process where the reactant is elevated ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Journal Of Physical Chemistry B
''The Journal of Physical Chemistry B'' is a peer-reviewed scientific journal that covers research on several fields of material chemistry (macromolecules, soft matter, and surfactants) as well as statistical mechanics, thermodynamics, and biophysical chemistry. It has been published weekly since 1997 by the American Chemical Society. According to the ''Journal Citation Reports'', the journal had an impact factor of 3.466 for 2021. Due to the growing amount of research in the fields it covers, the journal was split into two at the beginning of 2007, with '' The Journal of Physical Chemistry C'' specializing in nanostructures, the structures and properties of surfaces and interfaces, electronics, and related topics. List of editors-in-chief The following persons have been editor-in-chief: * 1997–2005 Mostafa El-Sayed * 2005–2019 George C. Schatz * 2020–Present Joan-Emma Shea See also * ''The Journal of Physical Chemistry A'' * '' The Journal of Physical Chemistr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
3D Optical Data Storage
3D optical data storage is any form of optical data storage in which information can be recorded or read with three-dimensional resolution (as opposed to the two-dimensional resolution afforded, for example, by CD). This innovation has the potential to provide petabyte-level mass storage on DVD-sized discs (120mm). Data recording and readback are achieved by focusing lasers within the medium. However, because of the volumetric nature of the data structure, the laser light must travel through other data points before it reaches the point where reading or recording is desired. Therefore, some kind of nonlinearity is required to ensure that these other data points do not interfere with the addressing of the desired point. No commercial product based on 3Doptical data storage has yet arrived on the mass market, although several companies are actively developing the technology and claim that it may become available 'soon'. Overview Current optical data storage media, such as the CD ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
DVD-RW
DVD recordable and DVD rewritable are optical disc recording technologies. Both terms describe DVD optical discs that can be written to by a DVD recorder, whereas only 'rewritable' discs are able to erase and rewrite data. Data is written ('burned') to the disc by a laser, rather than the data being 'pressed' onto the disc during manufacture, like a DVD-ROM. Pressing is used in mass production, primarily for the distribution of home video. Like CD-Rs, DVD recordable uses dye to store the data. During the burning of a single bit, the laser's intensity affects the reflective properties of the burned dye. By varying the laser intensity quickly, high density data is written in precise tracks. Since written tracks are made of darkened dye, the data side of a recordable DVD has a distinct color. Burned DVDs have a higher failure-to-read rate than pressed DVDs, due to differences in the reflective properties of dye compared to the aluminum substrate of pressed discs. Comparing recordab ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
CD-RW
CD-RW (Compact Disc-Rewritable) is a digital media, digital optical disc data storage device, storage format introduced in 1997. A CD-RW compact disc (CD-RWs) can be written, read, erased, and re-written. CD-RWs, as opposed to CDs, require specialized readers that have sensitive laser optics. Consequently, CD-RWs cannot be read in many CD readers built prior to the introduction of CD-RW. CD-ROM drives with a "MultiRead" certification are compatible. CD-RWs must be erased or blanked before reuse. Erasure methods include full blanking where the entire surface of the disc is erased and fast blanking where only metadata areas, such as PMA (CD), PMA, TOC (CD), TOC and pregap, are cleared. Fast blanking is quicker and usually sufficient to allow rewriting the disc. Full blanking removes all traces of the previous data, and is often used for confidentiality purposes. CD-RWs can sustain fewer re-writes compared to other storage media (ca. 1,000 compared up to 100,000). Ideal use is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pigment
A pigment is a colored material that is completely or nearly insoluble in water. In contrast, dyes are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often inorganic compounds. Pigments of prehistoric and historic value include ochre, charcoal, and lapis lazuli. Economic impact In 2006, around 7.4 million tons of inorganic, organic, and special pigments were marketed worldwide. Estimated at around US$14.86 billion in 2018 and will rise at over 4.9% CAGR from 2019 to 2026. The global demand for pigments was roughly US$20.5 billion in 2009. According to an April 2018 report by ''Bloomberg Businessweek'', the estimated value of the pigment industry globally is $30 billion. The value of titanium dioxide – used to enhance the white brightness of many products – was placed at $13.2 billion per year, while the color Ferrari red is valued at $300 million each year. Physical principles ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Isomer
In chemistry, isomers are molecules or polyatomic ions with identical molecular formulae – that is, same number of atoms of each element – but distinct arrangements of atoms in space. Isomerism is existence or possibility of isomers. Isomers do not necessarily share similar chemical or physical properties. Two main forms of isomerism are structural or constitutional isomerism, in which ''bonds'' between the atoms differ; and stereoisomerism or spatial isomerism, in which the bonds are the same but the ''relative positions'' of the atoms differ. Isomeric relationships form a hierarchy. Two chemicals might be the same constitutional isomer, but upon deeper analysis be stereoisomers of each other. Two molecules that are the same stereoisomer as each other might be in different conformational forms or be different isotopologues. The depth of analysis depends on the field of study or the chemical and physical properties of interest. The English word "isomer" () is a back-for ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molecule
A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and ''molecule'' is often used when referring to polyatomic ions. A molecule may be homonuclear, that is, it consists of atoms of one chemical element, e.g. two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, e.g. water (two hydrogen atoms and one oxygen atom; H2O). In the kinetic theory of gases, the term ''molecule'' is often used for any gaseous particle regardless of its composition. This relaxes the requirement that a molecule contains two or more atoms, since the noble gases are individual atoms. Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are typically not consid ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemistry
Chemistry is the science, scientific study of the properties and behavior of matter. It is a natural science that covers the Chemical element, elements that make up matter to the chemical compound, compounds made of atoms, molecules and ions: their composition, structure, properties, behavior and the changes they undergo during a Chemical reaction, reaction with other Chemical substance, substances. Chemistry also addresses the nature of chemical bonds in chemical compounds. In the scope of its subject, chemistry occupies an intermediate position between physics and biology. It is sometimes called the central science because it provides a foundation for understanding both Basic research, basic and Applied science, applied scientific disciplines at a fundamental level. For example, chemistry explains aspects of plant growth (botany), the formation of igneous rocks (geology), how atmospheric ozone is formed and how environmental pollutants are degraded (ecology), the properties ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Azobenzene Isomerization
Azobenzene is a photoswitchable chemical compound composed of two phenyl rings linked by a N=N double bond. It is the simplest example of an aryl azo compound. The term 'azobenzene' or simply 'azo' is often used to refer to a wide class of similar compounds. These azo compounds are considered as derivatives of diazene (diimide), and are sometimes referred to as 'diazenes'. The diazenes absorb light strongly and are common dyes. Structure and synthesis ''trans''-Azobenzene is planar. The N-N distance is 1.189 Å. ''cis''-Azobenzene is nonplanar with a C-N=N-C dihedral angle of 173.5°. The N-N distance is 1.251 Å. Azobenzene was first described by Eilhard Mitscherlich in 1834. Yellowish-red crystalline flakes of azobenzene were obtained in 1856. Its original preparation is similar to the modern one. According to the 1856 method, nitrobenzene is reduced by iron filings in the presence of acetic acid. In the modern synthesis, zinc is the reductant in the presence of a base. I ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Military Laser Experiment
A military, also known collectively as armed forces, is a heavily armed, highly organized force primarily intended for warfare. It is typically authorized and maintained by a sovereign state, with its members identifiable by their distinct military uniform. It may consist of one or more military branches such as an army, navy, air force, space force, marines, or coast guard. The main task of the military is usually defined as defence of the state and its interests against external armed threats. In broad usage, the terms ''armed forces'' and ''military'' are often treated as synonymous, although in technical usage a distinction is sometimes made in which a country's armed forces may include both its military and other paramilitary forces. There are various forms of irregular military forces, not belonging to a recognized state; though they share many attributes with regular military forces, they are less often referred to as simply ''military''. A nation's military may f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
