PH Indicator
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PH Indicator
A pH indicator is a halochromic chemical compound added in small amounts to a solution so the pH (acidity or basicity) of the solution can be determined visually or spectroscopically by changes in absorption and/or emission properties. Hence, a pH indicator is a chemical detector for hydronium ions (H3O+) or hydrogen ions (H+) in the Arrhenius model. Normally, the indicator causes the color of the solution to change depending on the pH. Indicators can also show change in other physical properties; for example, olfactory indicators show change in their odor. The pH value of a neutral solution is 7.0 at 25°C ( standard laboratory conditions). Solutions with a pH value below 7.0 are considered acidic and solutions with pH value above 7.0 are basic. Since most naturally occurring organic compounds are weak electrolytes, such as carboxylic acids and amines, pH indicators find many applications in biology and analytical chemistry. Moreover, pH indicators form one of the three main ...
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Analytical Chemistry
Analytical chemistry studies and uses instruments and methods to separate, identify, and quantify matter. In practice, separation, identification or quantification may constitute the entire analysis or be combined with another method. Separation isolates analytes. Qualitative analysis identifies analytes, while quantitative analysis determines the numerical amount or concentration. Analytical chemistry consists of classical, wet chemical methods and modern, instrumental methods. Classical qualitative methods use separations such as precipitation, extraction, and distillation. Identification may be based on differences in color, odor, melting point, boiling point, solubility, radioactivity or reactivity. Classical quantitative analysis uses mass or volume changes to quantify amount. Instrumental methods may be used to separate samples using chromatography, electrophoresis or field flow fractionation. Then qualitative and quantitative analysis can be performed, often with t ...
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Phenolphthalein
Phenolphthalein ( ) is a chemical compound with the chemical formula, formula carbon, C20hydrogen, H14oxygen, O4 and is often written as "HIn", "HPh", "phph" or simply "Ph" in shorthand notation. Phenolphthalein is often used as an indicator in acid–base titrations. For this application, it turns colorless in acidic solutions and pink in base (chemistry), basic solutions. It belongs to the class of dyes known as phthalein dyes. Phenolphthalein is slightly soluble in water and usually is dissolved in Alcohol (chemistry), alcohols for use in experiments. It is a weak acid, which can lose H+ ions in solution. The nonionized phenolphthalein molecule is colorless and the double deprotonated phenolphthalein ion is Fuchsia (color), fuchsia. Further loss of proton in higher pH occurs slowly and leads to a colorless form. Phenolphthalein ion in concentrated sulfuric acid is orange red due to sulfonation. Uses pH indicator Phenolphthalein's common use is as an indicator in acid-base t ...
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Acid Dissociation Constant
In chemistry, an acid dissociation constant (also known as acidity constant, or acid-ionization constant; denoted ) is a quantitative measure of the strength of an acid in solution. It is the equilibrium constant for a chemical reaction :HA A^- + H^+ known as dissociation in the context of acid–base reactions. The chemical species HA is an acid that dissociates into , the conjugate base of the acid and a hydrogen ion, . The system is said to be in equilibrium when the concentrations of its components will not change over time, because both forward and backward reactions are occurring at the same rate. The dissociation constant is defined by :K_\text = \mathrm, or :\mathrmK_\ce = - \log_ K_\text = \log_\frac where quantities in square brackets represent the concentrations of the species at equilibrium. Theoretical background The acid dissociation constant for an acid is a direct consequence of the underlying thermodynamics of the dissociation reaction; the p''K''a v ...
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Common Logarithm
In mathematics, the common logarithm is the logarithm with base 10. It is also known as the decadic logarithm and as the decimal logarithm, named after its base, or Briggsian logarithm, after Henry Briggs, an English mathematician who pioneered its use, as well as standard logarithm. Historically, it was known as ''logarithmus decimalis'' or ''logarithmus decadis''. It is indicated by , , or sometimes with a capital (however, this notation is ambiguous, since it can also mean the complex natural logarithmic multi-valued function). On calculators, it is printed as "log", but mathematicians usually mean natural logarithm (logarithm with base e ≈ 2.71828) rather than common logarithm when they write "log". To mitigate this ambiguity, the ISO 80000 specification recommends that should be written , and should be . Before the early 1970s, handheld electronic calculators were not available, and mechanical calculators capable of multiplication were bulky, expensive and not widely ...
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Henderson–Hasselbalch Equation
In chemistry and biochemistry, the Henderson–Hasselbalch equation :\ce = \ceK_\ce + \log_ \left( \frac \right) relates the pH of a chemical solution of a weak acid to the numerical value of the acid dissociation constant, ''K''a, of acid and the ratio of the concentrations, \frac of the acid and its conjugate base in an equilibrium. : \mathrm For example, the acid may be acetic acid :\mathrm The Henderson–Hasselbalch equation can be used to estimate the pH of a buffer solution by approximating the actual concentration ratio as the ratio of the analytical concentrations of the acid and of a salt, MA. The equation can also be applied to bases by specifying the protonated form of the base as the acid. For example, with an amine, \mathrm :\mathrm Derivation, assumptions and limitations A simple buffer solution consists of a solution of an acid and a salt of the conjugate base of the acid. For example, the acid may be acetic acid and the salt may be sodium acetate. Th ...
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Concentration
In chemistry, concentration is the abundance of a constituent divided by the total volume of a mixture. Several types of mathematical description can be distinguished: '' mass concentration'', ''molar concentration'', ''number concentration'', and ''volume concentration''. The concentration can refer to any kind of chemical mixture, but most frequently refers to solutes and solvents in solutions. The molar (amount) concentration has variants, such as normal concentration and osmotic concentration. Etymology The term concentration comes from the word concentrate, from the French , from con– + center, meaning “to put at the center”. Qualitative description Often in informal, non-technical language, concentration is described in a qualitative way, through the use of adjectives such as "dilute" for solutions of relatively low concentration and "concentrated" for solutions of relatively high concentration. To concentrate a solution, one must add more solute (for example, ...
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Conjugate Acid
A conjugate acid, within the Brønsted–Lowry acid–base theory, is a chemical compound formed when an acid donates a proton () to a base—in other words, it is a base with a hydrogen ion added to it, as in the reverse reaction it loses a hydrogen ion. On the other hand, a conjugate base is what is left over after an acid has donated a proton during a chemical reaction. Hence, a conjugate base is a species formed by the removal of a proton from an acid, as in the reverse reaction it is able to gain a hydrogen ion. Because some acids are capable of releasing multiple protons, the conjugate base of an acid may itself be acidic. In summary, this can be represented as the following chemical reaction: :acid + base conjugate\ base + conjugate\ acid Johannes Nicolaus Brønsted and Martin Lowry introduced the Brønsted–Lowry theory, which proposed that any compound that can transfer a proton to any other compound is an acid, and the compound that accepts the proton is a b ...
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Titration
Titration (also known as titrimetry and volumetric analysis) is a common laboratory method of quantitative chemical analysis to determine the concentration of an identified analyte (a substance to be analyzed). A reagent, termed the ''titrant'' or ''titrator'', is prepared as a standard solution of known concentration and volume. The titrant reacts with a solution of ''analyte'' (which may also be termed the ''titrand'') to determine the analyte's concentration. The volume of titrant that reacted with the analyte is termed the ''titration volume''. History and etymology The word "titration" descends from the French word ''titrer'' (1543), meaning the proportion of gold or silver in coins or in works of gold or silver; i.e., a measure of fineness or purity. ''Tiltre'' became ''titre'', which thus came to mean the "fineness of alloyed gold", and then the "concentration of a substance in a given sample". In 1828, the French chemist Joseph Louis Gay-Lussac first used ''titre'' as ...
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Redox Titration
A redox titration is a type of titration based on a redox reaction between the analyte and titrant. It may involve the use of a redox indicator and/or a potentiometer. A common example of a redox titration is treating a solution of iodine with a reducing agent to produce iodide using a starch indicator to help detect the endpoint. Iodine (I2) can be reduced to iodide (I−) by, say, thiosulfate (, and when all iodine is spent the blue colour disappears. This is called an iodometric titration. Most often of all, the reduction of iodine to iodide is the last step in a series of reactions where the initial reactions are used to convert an unknown amount of the solute (the substance being analyzed) to an equivalent amount of iodine, which may then be titrated. Sometimes other halogens (or haloalkanes) than iodine are used in the intermediate reactions because they are available in better measurable standard solutions and/or react more readily with the solute. The extra steps in ...
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Redox Indicator
A redox indicator (also called an oxidation-reduction indicator) is an indicator which undergoes a definite color change at a specific electrode potential. The requirement for fast and reversible color change means that the oxidation-reduction equilibrium for an indicator redox system needs to be established very quickly. Therefore, only a few classes of organic redox systems can be used for indicator purposes. There are two common classes of redox indicators: * metal complexes of phenanthroline and bipyridine. In these systems, the metal changes oxidation state. * organic redox systems such as methylene blue. In these systems, a proton participant in the redox reaction. Therefore, sometimes redox indicators are also divided into two general groups: independent or dependent on pH. The most common redox indicator are organic compounds. Redox Indicator example: The molecule 2,2'- Bipyridine is a redox Indicator. In solution, it changes from light blue to red at an electrode po ...
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BDH Chemicals
BDH is a three-letter abbreviation that may refer to: *The AMEX code for ML BRDBND HLDR12/40 (a broadband diversification instrument). *The National Rail station code for Bedhampton railway station, Havant, England * Beta-hydroxyDeHydrogenase, enzyme that takes beta-Hydroxybutyric acid as a substrate *Peace and Democracy Movement (''Bariş ve Demokrasi Hareketi''), a political party in the Turkish Republic of Northern Cyprus *Big Children's Choir (''Большой Детский Хор''), one of the most popular children's choirs in the ex-USSR. *''The Brown Daily Herald'', the student newspaper of Brown University *''British Drug Houses'', a big chemical company that was merged with Merck KGaA *Bryce Dallas Howard Bryce Dallas Howard (born March 2, 1981) is an American actress and director. Howard was born in Los Angeles and attended New York University's Tisch School of the Arts, initially leaving in 2002 to take roles on Broadway but officially graduati ..., actress in Juras ...
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