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Plutonium Carbide
Plutonium carbide comes in several stoichiometries (PuC and Pu2C3). It can be used as a nuclear fuel for nuclear reactors in conjunction with uranium carbide Uranium carbide, a carbide of uranium, is a hard refractory ceramic material. It comes in several stoichiometries (''x'' differs in ), such as uranium methanide (UC, CAS number 12070-09-6), uranium sesquicarbide (U2C3, CAS number 12076-62-9), a .... The mixture is also labeled as uranium-plutonium carbide (UPuC). References {{Plutonium compounds Carbides Plutonium compounds Rock salt crystal structure ...
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Stoichiometry
Stoichiometry refers to the relationship between the quantities of reactants and products before, during, and following chemical reactions. Stoichiometry is founded on the law of conservation of mass where the total mass of the reactants equals the total mass of the products, leading to the insight that the relations among quantities of reactants and products typically form a ratio of positive integers. This means that if the amounts of the separate reactants are known, then the amount of the product can be calculated. Conversely, if one reactant has a known quantity and the quantity of the products can be empirically determined, then the amount of the other reactants can also be calculated. This is illustrated in the image here, where the balanced equation is: : Here, one molecule of methane reacts with two molecules of oxygen gas to yield one molecule of carbon dioxide and two molecules of water. This particular chemical equation is an example of complete combustion. St ...
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Nuclear Fuel
Nuclear fuel is material used in nuclear power stations to produce heat to power turbines. Heat is created when nuclear fuel undergoes nuclear fission. Most nuclear fuels contain heavy fissile actinide elements that are capable of undergoing and sustaining nuclear fission. The three most relevant fissile isotopes are uranium-233, uranium-235 and plutonium-239. When the unstable nuclei of these atoms are hit by a slow-moving neutron, they frequently split, creating two daughter nuclei and two or three more neutrons. In that case, the neutrons released go on to split more nuclei. This creates a self-sustaining chain reaction that is controlled in a nuclear reactor, or uncontrolled in a nuclear weapon. Alternatively, if the nucleus absorbs the neutron without splitting, it creates a heavier nucleus with one additional neutron. The processes involved in mining, refining, purifying, using, and disposing of nuclear fuel are collectively known as the nuclear fuel cycle. Not all typ ...
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Uranium Carbide
Uranium carbide, a carbide of uranium, is a hard refractory ceramic material. It comes in several stoichiometries (''x'' differs in ), such as uranium methanide (UC, CAS number 12070-09-6), uranium sesquicarbide (U2C3, CAS number 12076-62-9), and uranium acetylide (UC2, CAS number 12071-33-9). Like uranium dioxide and some other uranium compounds, uranium carbide can be used as a nuclear fuel for nuclear reactors, usually in the form of pellets or tablets. Uranium carbide fuel was used in late designs of nuclear thermal rockets. Uranium carbide pellets are used as fuel kernels for the US version of pebble bed reactors; the German version uses uranium dioxide instead. As nuclear fuel, uranium carbide can be used either on its own, or mixed with plutonium carbide (PuC and Pu2C3). The mixture is also labeled as uranium-plutonium carbide ( (U,Pu)C ). Uranium carbide is also a popular target material for particle accelerators. Ammonia synthesis from nitrogen and hydrogen is sometim ...
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Carbides
In chemistry, a carbide usually describes a compound composed of carbon and a metal. In metallurgy, carbiding or carburizing is the process for producing carbide coatings on a metal piece. Interstitial / Metallic carbides The carbides of the group 4, 5 and 6 transition metals (with the exception of chromium) are often described as interstitial compounds. These carbides have metallic properties and are refractory. Some exhibit a range of stoichiometries, being a non-stoichiometric mixture of various carbides arising due to crystal defects. Some of them, including titanium carbide and tungsten carbide, are important industrially and are used to coat metals in cutting tools. The long-held view is that the carbon atoms fit into octahedral interstices in a close-packed metal lattice when the metal atom radius is greater than approximately 135 pm: *When the metal atoms are cubic close-packed, (ccp), then filling all of the octahedral interstices with carbon achieves 1:1 stoich ...
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Plutonium Compounds
Plutonium compounds are compounds containing the element plutonium (Pu). At room temperature, pure plutonium is silvery in color but gains a tarnish when oxidized. The element displays four common ionic oxidation states in aqueous solution and one rare one: * Pu(III), as Pu3+ (blue lavender) * Pu(IV), as Pu4+ (yellow brown) * Pu(V), as (light pink) * Pu(VI), as (pink orange) * Pu(VII), as (green)-the heptavalent ion is rare. The color shown by plutonium solutions depends on both the oxidation state and the nature of the acid anion. It is the acid anion that influences the degree of complexing—how atoms connect to a central atom—of the plutonium species. Additionally, the formal +2 oxidation state of plutonium is known in the complex (2.2.2-cryptand) uIICp″3 Cp″ = C5H3(SiMe3)2. A +8 oxidation state is possible as well in the volatile tetroxide . Though it readily decomposes via a reduction mechanism similar to , can be stabilized in alkaline solutions and chloroform ...
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