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Particle Statistics
Particle statistics is a particular description of multiple particles in statistical mechanics. A key prerequisite concept is that of a statistical ensemble (an idealization comprising the state space of possible states of a system, each labeled with a probability) that emphasizes properties of a large system as a whole at the expense of knowledge about parameters of separate particles. When an ensemble describes a system of particles with similar properties, their number is called the particle number and usually denoted by ''N''. Classical statistics In classical mechanics, all particles (elementary particle, fundamental and composite particles, atoms, molecules, electrons, etc.) in the system are considered identity (philosophy), distinguishable. This means that individual particles in a system can be tracked. As a consequence, switching the positions of any pair of particles in the system leads to a different configuration of the system. Furthermore, there is no restriction on p ...
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Particle
In the Outline of physical science, physical sciences, a particle (or corpuscule in older texts) is a small wikt:local, localized physical body, object which can be described by several physical property, physical or chemical property, chemical properties, such as volume, density, or mass. They vary greatly in size or quantity, from subatomic particles like the electron, to microscopic scale, microscopic particles like atoms and molecules, to macroscopic scale, macroscopic particles like powder (substance), powders and other granular materials. Particles can also be used to create scientific models of even larger objects depending on their density, such as humans moving in a crowd or celestial bodies in motion (physics), motion. The term ''particle'' is rather general in meaning, and is refined as needed by various scientific fields. Anything that is composed of particles may be referred to as being particulate. However, the noun ''particulates, particulate'' is most frequently ...
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Lepton
In particle physics, a lepton is an elementary particle of half-integer spin ( spin ) that does not undergo strong interactions. Two main classes of leptons exist: charged leptons (also known as the electron-like leptons or muons), and neutral leptons (better known as neutrinos). Charged leptons can combine with other particles to form various composite particles such as atoms and positronium, while neutrinos rarely interact with anything, and are consequently rarely observed. The best known of all leptons is the electron. There are six types of leptons, known as '' flavours'', grouped in three '' generations''. The first-generation leptons, also called ''electronic leptons'', comprise the electron () and the electron neutrino (); the second are the ''muonic leptons'', comprising the muon () and the muon neutrino (); and the third are the ''tauonic leptons'', comprising the tau () and the tau neutrino (). Electrons have the least mass of all the charged leptons. The heavi ...
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Permutation Group
In mathematics, a permutation group is a group ''G'' whose elements are permutations of a given set ''M'' and whose group operation is the composition of permutations in ''G'' (which are thought of as bijective functions from the set ''M'' to itself). The group of ''all'' permutations of a set ''M'' is the symmetric group of ''M'', often written as Sym(''M''). The term ''permutation group'' thus means a subgroup of the symmetric group. If then Sym(''M'') is usually denoted by S''n'', and may be called the ''symmetric group on n letters''. By Cayley's theorem, every group is isomorphic to some permutation group. The way in which the elements of a permutation group permute the elements of the set is called its group action. Group actions have applications in the study of symmetries, combinatorics and many other branches of mathematics, physics and chemistry. Basic properties and terminology Being a subgroup of a symmetric group, all that is necessary for a set of permutatio ...
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Spin–statistics Theorem
In quantum mechanics, the spin–statistics theorem relates the intrinsic spin of a particle (angular momentum not due to the orbital motion) to the particle statistics it obeys. In units of the reduced Planck constant ''ħ'', all particles that move in 3 dimensions have either integer spin or half-integer spin. Background Quantum states and indistinguishable particles In a quantum system, a physical state is described by a state vector. A pair of distinct state vectors are physically equivalent if they differ only by an overall phase factor, ignoring other interactions. A pair of indistinguishable particles such as this have only one state. This means that if the positions of the particles are exchanged (i.e., they undergo a permutation), this does not identify a new physical state, but rather one matching the original physical state. In fact, one cannot tell which particle is in which position. While the physical state does not change under the exchange of the particles' po ...
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Symmetry (physics)
In physics, a symmetry of a physical system is a physical or mathematical feature of the system (observed or intrinsic) that is preserved or remains unchanged under some transformation. A family of particular transformations may be ''continuous'' (such as rotation of a circle) or ''discrete'' (e.g., reflection of a bilaterally symmetric figure, or rotation of a regular polygon). Continuous and discrete transformations give rise to corresponding types of symmetries. Continuous symmetries can be described by Lie groups while discrete symmetries are described by finite groups (see '' Symmetry group''). These two concepts, Lie and finite groups, are the foundation for the fundamental theories of modern physics. Symmetries are frequently amenable to mathematical formulations such as group representations and can, in addition, be exploited to simplify many problems. Arguably the most important example of a symmetry in physics is that the speed of light has the same value in all fra ...
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Macromolecule
A macromolecule is a very large molecule important to biophysical processes, such as a protein or nucleic acid. It is composed of thousands of covalently bonded atoms. Many macromolecules are polymers of smaller molecules called monomers. The most common macromolecules in biochemistry are biopolymers (nucleic acids, proteins, and carbohydrates) and large non-polymeric molecules such as lipids, nanogels and macrocycles. Synthetic fibers and experimental materials such as carbon nanotubes are also examples of macromolecules. Definition The term ''macromolecule'' (''macro-'' + ''molecule'') was coined by Nobel laureate Hermann Staudinger in the 1920s, although his first relevant publication on this field only mentions ''high molecular compounds'' (in excess of 1,000 atoms). At that time the term ''polymer'', as introduced by Berzelius in 1832, had a different meaning from that of today: it simply was another form of isomerism for example with benzene and acetylene and had litt ...
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Molecule
A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and ''molecule'' is often used when referring to polyatomic ions. A molecule may be homonuclear, that is, it consists of atoms of one chemical element, e.g. two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, e.g. water (two hydrogen atoms and one oxygen atom; H2O). In the kinetic theory of gases, the term ''molecule'' is often used for any gaseous particle regardless of its composition. This relaxes the requirement that a molecule contains two or more atoms, since the noble gases are individual atoms. Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are typically not consid ...
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Ammonia
Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous waste, particularly among aquatic organisms, and it contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to 45% of the world's food and fertilizers. Around 70% of ammonia is used to make fertilisers in various forms and composition, such as urea and Diammonium phosphate. Ammonia in pure form is also applied directly into the soil. Ammonia, either directly or indirectly, is also a building block for the synthesis of many pharmaceutical products and is used in many commercial cleaning products. It is mainly collected by downward displacement of both air and water. Although common in nature—both terrestrially and in the outer planets of the Solar System—and in wide use, ammonia is both caust ...
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Liquid Helium
Liquid helium is a physical state of helium at very low temperatures at standard atmospheric pressures. Liquid helium may show superfluidity. At standard pressure, the chemical element helium exists in a liquid form only at the extremely low temperature of . Its boiling point and critical point depend on which isotope of helium is present: the common isotope helium-4 or the rare isotope helium-3. These are the only two stable isotopes of helium. See the table below for the values of these physical quantities. The density of liquid helium-4 at its boiling point and a pressure of one atmosphere (101.3 kilopascals) is about , or about one-eighth the density of liquid water. Liquefaction Helium was first liquefied on July 10, 1908, by the Dutch physicist Heike Kamerlingh Onnes at the University of Leiden in the Netherlands. At that time, helium-3 was unknown because the mass spectrometer had not yet been invented. In more recent decades, liquid helium has been used as a cryogenic ref ...
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Quantum State
In quantum physics, a quantum state is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the quantum state together with the rules for the system's evolution in time exhausts all that can be predicted about the system's behavior. A mixture of quantum states is again a quantum state. Quantum states that cannot be written as a mixture of other states are called pure quantum states, while all other states are called mixed quantum states. A pure quantum state can be represented by a ray in a Hilbert space over the complex numbers, while mixed states are represented by density matrices, which are positive semidefinite operators that act on Hilbert spaces. Pure states are also known as state vectors or wave functions, the latter term applying particularly when they are represented as functions of position or momentum. For example, when dealing with the energy spectrum of the electron in a hydrogen at ...
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Atom
Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. Atoms are extremely small, typically around 100 picometers across. They are so small that accurately predicting their behavior using classical physics, as if they were tennis balls for example, is not possible due to quantum effects. More than 99.94% of an atom's mass is in the nucleus. The protons have a positive electric charge, the electrons have a negative electric charge, and the neutrons have no electric charge. If the number of protons and electrons are equal, then the atom is electrically neutral. If an atom has more or fewer electrons than protons, then it has an overall negative or positive charge, respectively – such atoms are called ions. The electrons of an atom are a ...
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Quantum Number
In quantum physics and chemistry, quantum numbers describe values of conserved quantities in the dynamics of a quantum system. Quantum numbers correspond to eigenvalues of operators that commute with the Hamiltonian—quantities that can be known with precision at the same time as the system's energyspecifically, observables \widehat that commute with the Hamiltonian are simultaneously diagonalizable with it and so the eigenvalues a and the energy (eigenvalues of the Hamiltonian) are not limited by an uncertainty relation arising from non-commutativity.—and their corresponding eigenspaces. Together, a specification of all of the quantum numbers of a quantum system fully characterize a basis state of the system, and can in principle be measured together. An important aspect of quantum mechanics is the quantization of many observable quantities of interest.Many observables have discrete spectra (sets of eigenvalues) in quantum mechanics, so the quantities can only be measure ...
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