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C Test
A spot test in lichenology is a spot analysis used to help identify lichens. It is performed by placing a drop of a chemical reagent on different parts of the lichen and noting the colour change (or lack thereof) associated with application of the chemical. The tests are routinely encountered in dichotomous keys for lichen species, and they take advantage of the wide array of lichen products (secondary metabolites) produced by lichens and their uniqueness among taxa. As such, spot tests reveal the presence or absence of chemicals in various parts of a lichen. They were first proposed as a method to help identify species by the Finnish lichenologist William Nylander (botanist), William Nylander in 1866. Three common spot tests use either 10% aqueous potassium hydroxide, KOH solution (K test), saturated aqueous solution of bleaching powder or calcium hypochlorite (C test), or 5% alcoholic p-phenylenediamine, ''p''-phenylenediamine solution (P test). The colour changes occur due to pr ...
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Lichenology
Lichenology is the branch of mycology that studies the lichens, symbiotic organisms made up of an intimate symbiotic association of a microscopic alga (or a cyanobacterium) with a Hypha, filamentous fungus. Lichens are chiefly characterized by this symbiosis. Study of lichens draws knowledge from several disciplines: mycology, phycology, microbiology and botany. Scholars of lichenology are known as lichenologists. Study of lichens is conducted by both professional and amateur lichenologists. Methods for species identification include reference to single-access keys on lichens. An example reference work is ''Lichens of North America'' (2001) by Irwin M. Brodo, Sylvia Sharnoff and Stephen Sharnoff and that book's 2016 expansion, ''Keys to Lichens of North America: Revised and Expanded'' by the same three authors joined by Susan Laurie-Bourque. A chemical spot test (lichen), spot test can be used to detect the presence of certain lichen products which can be characteristic of a gi ...
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Punctelia Borreri 149849
''Punctelia'' is a genus of foliose lichens belonging to the large family Parmeliaceae. The genus, which contains about 50 species, was segregated from genus '' Parmelia'' in 1982. Characteristics that define ''Punctelia'' include the presence of hook-like to thread-like conidia (asexual spores), simple rhizines (root-like structures that attach the lichen thallus to its substrate), and point-like pseudocyphellae (tiny pores on the thallus surface that facilitate gas exchange). It is this last feature that is alluded to in the vernacular names speckled shield lichens or speckleback lichens. ''Punctelia'' lichens grow on bark, wood, and rocks. The genus has a worldwide distribution, occurring on all continents but Antarctica. Species are found in temperate to subtropical locations. ''Punctelia'' has centres of distribution in the Neotropics and Africa; about half of the known species occur in South America. The photobiont partners of ''Punctelia'' are green algae in the genus ...
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Depsidone
Depsidones (+ " depside" + "one") are chemical compounds that are sometimes found as secondary metabolites in lichens. They are esters that are both depsides and cyclic ethers. An example is norstictic acid Norstictic acid is a depsidone produced as a secondary metabolites in lichens. The compound contains both an aldehyde carbonyl group and an adjacent hydroxyl In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical fo .... References {{reflist Biochemistry Carboxylate esters ...
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Orcinol
Orcinol is an organic compound with the formula CH3C6H3(OH)2. It occurs in many species of lichens including ''Roccella tinctoria'' and ''Lecanora''. Orcinol has been detected in the "toxic glue" of the ant species ''Camponotus saundersi''. It is a colorless solid. It is related to resorcinol, 1,3-C6H4(OH)2. Synthesis and reactions Orcinol was first prepared by dehydroacetic acid, a conversion that involved ring-opening of the pyrone to a triketone. This early experiment helped establish the rich condensation chemistry of polyketides. It can be obtained by fusing extract of aloes with potash, followed by acidification. It undergoes ''O''-methylation with dimethylsulfate. It is used in the production of the dye orcein and as a reagent in some chemical tests for pentoses, such as Bial's Test. It may be synthesized from toluene; more interesting is its production when acetone dicarboxylic ester is condensed with the aid of sodium. It crystallizes in colorless prisms with one m ...
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Thamnolic Acid
Thamnolic acid is a β-orcinol depside with the molecular formula C19H16O11. Thamnolic acid was first isolated from the lichen '' Thamnolia vermicularis'', but it also occur in ''Cladonia ''Cladonia'' is a genus of moss-like lichenized fungi in the family Cladoniaceae. They are the primary food source for reindeer/caribou. ''Cladonia'' species are of economic importance to reindeer-herders, such as the Sami in Scandinavia or th ...'' species. References Further reading * * * Lichen products Polyphenols Carboxylic acids Methoxy compounds {{Ether-stub ...
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Atranorin
Atranorin is a chemical substance produced by some species of lichen. It is a secondary metabolite belonging to a group of compounds known as depsides. Atranorin has analgesic, anti-inflammatory, antibacterial, antifungal, cytotoxic, antioxidant, antiviral, and immunomodulatory properties. In rare cases, people can have an allergic reaction Allergies, also known as allergic diseases, are various conditions caused by hypersensitivity of the immune system to typically harmless substances in the environment. These diseases include Allergic rhinitis, hay fever, Food allergy, food al ... to atranorin. References Further reading * * * * Polyphenols Lichen products {{organic-compound-stub ...
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Depside
A depside is a type of polyphenolic compound composed of two or more monocyclic aromatic units linked by an ester group. Depsides are most often found in lichens, but have also been isolated from higher plants, including species of the Ericaceae, Lamiaceae, Papaveraceae and Myrtaceae. Certain depsides have antibiotic, anti-HIV, antioxidant, and anti-proliferative activity ''in vitro''. As inhibitors of prostaglandin synthesis and leukotriene B4 biosynthesis, some depsides have ''in vitro'' anti-inflammatory activity. A depsidase is a type of enzyme that cuts depside bonds. One such enzyme is tannase. Examples Gyrophoric acid, found in the lichen '' Cryptothecia rubrocincta'', is a depside. Merochlorophaeic acid, isolated from lichens of the genus '' Cladonia'', is an inhibitor of prostaglandin synthesis. Some depsides are described as anti-HIV. See also * Salsalate homodimer formed from self-condensation of salicylic acid Salicylic acid is an organic compound with t ...
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Terphenylquinones
Terphenylquinones are fungal dyes from the group of Phenyl group, phenyl-substituted P-Benzoquinone, ''p''-benzoquinones having the following general structure. General chemical structure of terphenylquinones Also derivatives with a central O-Benzoquinone, ''o''-benzoquinone structure are known. Biosynthesis The biosynthesis of terphenylquinones is carried out by Dimerization (chemistry), dimerization of substituted Phenylpyruvic acid, oxophenylpropanoic acids (phenylpyruvic acids). Occurrence Terphenylquinones are typical constituents of the Boletales. Examples :{, class="wikitable sortable" !Name, , Structure, , CAS-Nr., , Origin , - , Polyporic acid, , , , 548-59-4, , Polypore of the order Aphyllophorales, lichen ''Yarrumia coronata'' , - , Atromentin, , , , 519-67-5, , ''Paxillus atrotomentosus'' (Basidiomycota) , - , Aurantiacin, , , , 548-32-3, , ''Hydnellum aurantiacum'' (Basidiomycota) , - , Phlebiarubron, , , , 7204-23-1, , Cultures of ''Phlebia strigosozonata'' a ...
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