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Niobium(IV) Fluoride
Niobium(IV) fluoride is a chemical compound with the formula . It is a nonvolatile black solid. Properties absorbs vapor strongly and turns into in moist air. It reacts with water to form a brown solution and a brown precipitate whose components are unknown. It is stable between 275 °C and 325 °C when heated in a vacuum. However, it disproportionates at 350 °C rapidly to form niobium(V) fluoride and niobium(III) fluoride: : (at 350 °C) Structure Niobium(IV) fluoride adopts a crystal structure analogous to that of tin(IV) fluoride Tin(IV) fluoride is a chemical compound of tin and fluorine with the chemical formula SnF4 and is a white solid with a melting point above 700 °C. SnF4 can be prepared by the reaction of tin metal with fluorine gas: :Sn + 2F2 → SnF4 Howev ..., in which each niobium atom is surrounded by six fluorine atoms forming an octahedron. Of the six fluorine atoms surrounding a single niobium atom, four are bridging to adjacent octahedra, lea ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Formula
In science, a formula is a concise way of expressing information symbolically, as in a mathematical formula or a ''chemical formula''. The informal use of the term ''formula'' in science refers to the general construct of a relationship between given quantities. The plural of ''formula'' can be either ''formulas'' (from the most common English plural noun form) or, under the influence of scientific Latin, ''formulae'' (from the original Latin). In mathematics In mathematics, a formula generally refers to an identity which equates one mathematical expression to another, with the most important ones being mathematical theorems. Syntactically, a formula (often referred to as a ''well-formed formula'') is an entity which is constructed using the symbols and formation rules of a given logical language. For example, determining the volume of a sphere requires a significant amount of integral calculus or its geometrical analogue, the method of exhaustion. However, having done t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Solid
Solid is one of the State of matter#Four fundamental states, four fundamental states of matter (the others being liquid, gas, and Plasma (physics), plasma). The molecules in a solid are closely packed together and contain the least amount of kinetic energy. A solid is characterized by structural rigidity and resistance to a force applied to the surface. Unlike a liquid, a solid object does not flow to take on the shape of its container, nor does it expand to fill the entire available volume like a gas. The atoms in a solid are bound to each other, either in a regular geometric lattice (crystal, crystalline solids, which include metals and ordinary ice), or irregularly (an amorphous solid such as common window glass). Solids cannot be compressed with little pressure whereas gases can be compressed with little pressure because the molecules in a gas are loosely packed. The branch of physics that deals with solids is called solid-state physics, and is the main branch of condens ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Niobium(V) Fluoride
Niobium(V) fluoride, also known as niobium pentafluoride, is the inorganic compound with the formula NbF5. The solid consists of tetramers bF5sub>4. It is a colorless solid that is rarely used. Preparation and reactions Niobium pentafluoride is obtained by treatment of any niobium compound with fluorine: :2 Nb + 5 F2 → 2 NbF5 :2 NbCl5 + 5 F2 → 2 NbF5 + 5 Cl2 It reacts with hydrogen fluoride to give H2NbF7, a superacid. Related compounds In hydrofluoric acid Hydrofluoric acid is a Solution (chemistry), solution of hydrogen fluoride (HF) in water. Solutions of HF are colourless, acidic and highly Corrosive substance, corrosive. It is used to make most fluorine-containing compounds; examples include th ..., NbF5 converts to bF7sup>2- and bF5Osup>2-. The relative solubility of these potassium salts and related tantalum fluorides is the basis of the Marignac process for separation of Nb and Ta. NbCl5 forms a dimeric structure (edge-shared bioctahedron) in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Niobium(III) Fluoride
Niobium is a chemical element with chemical symbol Nb (formerly columbium, Cb) and atomic number 41. It is a light grey, crystalline, and ductile transition metal. Pure niobium has a Mohs hardness rating similar to pure titanium, and it has similar ductility to iron. Niobium oxidizes in Earth's atmosphere very slowly, hence its application in jewelry as a hypoallergenic alternative to nickel. Niobium is often found in the minerals pyrochlore and columbite, hence the former name "columbium". Its name comes from Greek mythology: Niobe, daughter of Tantalus, the namesake of tantalum. The name reflects the great similarity between the two elements in their physical and chemical properties, which makes them difficult to distinguish. English chemist Charles Hatchett reported a new element similar to tantalum in 1801 and named it columbium. In 1809, English chemist William Hyde Wollaston wrongly concluded that tantalum and columbium were identical. German chemist Hein ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tin(IV) Fluoride
Tin(IV) fluoride is a chemical compound of tin and fluorine with the chemical formula SnF4 and is a white solid with a melting point above 700 °C. SnF4 can be prepared by the reaction of tin metal with fluorine gas: :Sn + 2F2 → SnF4 However, a passivating metal fluoride layer will be created and the surface will eventually become unreactive. An alternative synthesis is the reaction of SnCl4 with anhydrous hydrogen fluoride: :SnCl4 + 4HF → SnF4 + 4HCl With alkali metal fluorides (e.g. KF) hexafluorostannates are produced (e.g.K2SnF6), which contain the octahedral SnF62− anion. SnF4 behaves as a Lewis acid and adducts L2·SnF4 and L·SnF4 have been produced. Structure Unlike the other tin tetrahalides, tin(IV) chloride, tin(IV) bromide, and tin(IV) iodide, which contain tetrahedrally coordinated tin, tin(IV) fluoride contains planar layers of octahedrally coordinated tin, where the octahedra share four corners and there are two terminal, unshared, fluorine atoms ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Niobium(IV) Compounds
Niobium is a chemical element with chemical symbol Nb (formerly columbium, Cb) and atomic number 41. It is a light grey, crystalline, and ductile transition metal. Pure niobium has a Mohs hardness rating similar to pure titanium, and it has similar ductility to iron. Niobium oxidizes in Earth's atmosphere very slowly, hence its application in jewelry as a hypoallergenic alternative to nickel. Niobium is often found in the minerals pyrochlore and columbite, hence the former name "columbium". Its name comes from Greek mythology: Niobe, daughter of Tantalus, the namesake of tantalum. The name reflects the great similarity between the two elements in their physical and chemical properties, which makes them difficult to distinguish. English chemist Charles Hatchett reported a new element similar to tantalum in 1801 and named it columbium. In 1809, English chemist William Hyde Wollaston wrongly concluded that tantalum and columbium were identical. German chemist Heinrich Rose determi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fluorides
Fluoride (). According to this source, is a possible pronunciation in British English. is an inorganic, monatomic anion of fluorine, with the chemical formula (also written ), whose salts are typically white or colorless. Fluoride salts typically have distinctive bitter tastes, and are odorless. Its salts and minerals are important chemical reagents and industrial chemicals, mainly used in the production of hydrogen fluoride for fluorocarbons. Fluoride is classified as a weak base since it only partially associates in solution, but concentrated fluoride is corrosive and can attack the skin. Fluoride is the simplest fluorine anion. In terms of charge and size, the fluoride ion resembles the hydroxide ion. Fluoride ions occur on Earth in several minerals, particularly fluorite, but are present only in trace quantities in bodies of water in nature. Nomenclature Fluorides include compounds that contain ionic fluoride and those in which fluoride does not dissociate. The nomenc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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