NMHC
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NMHC
Non-methane volatile organic compounds (NMVOCs) are a set of organic compounds that are typically photochemically reactive in the atmosphere—marked by the exclusion of methane. NMVOCs include a large variety of chemically different compounds, such as benzene, ethanol, formaldehyde, cyclohexane, 1,1,1-trichloroethane and acetone. Essentially, NMVOCs are identical to volatile organic compounds (VOCs), but with methane excluded. Methane is excluded in air-pollution contexts because it is not toxic. It is however a very potent greenhouse gas, with low reactivity and thus a long lifetime in the atmosphere. An important subset of NMVOCs are the non-methane hydrocarbons (NMHCs). Sometimes NMVOC is also used as a sum parameter for emissions, where all NMVOC emissions are added up ''per weight'' into one figure. In absence of more detailed data, this can be a very coarse parameter for pollution (e.g. for summer smog or indoor air pollution). The major sources of NMVOCs include vegetati ...
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Photochemical Reaction
Organic photochemistry encompasses organic reactions that are induced by the action of light. The absorption of ultraviolet light by organic molecules often leads to reactions. In the earliest days, sunlight was employed, while in more modern times ultraviolet lamps are employed. Organic photochemistry has proven to be a very useful synthetic tool. Complex organic products can be obtained simply. History Early examples were often uncovered by the observation of precipitates or color changes from samples that were exposed to sunlights. The first reported case was by Ciamician that sunlight converted santonin to a yellow photoproduct: An early example of a precipitate was the photodimerization of anthracene, characterized by Yulii Fedorovich Fritzsche and confirmed by Elbs. Similar observations focused on the dimerization of cinnamic acid to truxillic acid. Many photodimers are now recognized, e.g. pyrimidine dimer, thiophosgene, diamantane. Another example was uncovered by Egbe ...
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Ground Level Ozone
Ground-level ozone (O3), also known as surface-level ozone and tropospheric ozone, is a trace gas in the troposphere (the lowest level of the atmosphere of Earth, Earth's atmosphere), with an average concentration of 20–30 parts per billion by volume (ppbv), with close to 100 ppbv in polluted areas. Ozone is also an important constituent of the stratosphere, where the ozone layer (2 to 8 parts per million ozone) exists which is located between 10 and 50 kilometers above the Earth's surface. The troposphere extends from the ground up to a variable height of approximately 14 kilometers above sea level. Ozone is least concentrated in the ground layer (or planetary boundary layer) of the troposphere. Ground-level or tropospheric ozone is created by chemical reactions between NOx gases (oxides of nitrogen produced by combustion) and volatile organic compounds (VOCs). The combination of these chemicals in the presence of sunlight form ozone. Its concentration increases as height above s ...
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