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Number Operator
In quantum mechanics, for systems where the total number of particles may not be preserved, the number operator is the observable that counts the number of particles. The number operator acts on Fock space. Let :, \Psi\rangle_\nu=, \phi_1,\phi_2,\cdots,\phi_n\rangle_\nu be a Fock state, composed of single-particle states , \phi_i\rangle drawn from a basis of the underlying Hilbert space of the Fock space. Given the corresponding creation and annihilation operators a^(\phi_i) and a(\phi_i)\, we define the number operator by :\hat \ \stackrel\ a^(\phi_i)a(\phi_i) and we have :\hat, \Psi\rangle_\nu=N_i, \Psi\rangle_\nu where N_i is the number of particles in state , \phi_i\rangle. The above equality can be proven by noting that :\begin a(\phi_i) , \phi_1,\phi_2,\cdots,\phi_,\phi_i,\phi_,\cdots,\phi_n\rangle_\nu &=& \sqrt , \phi_1,\phi_2,\cdots,\phi_,\phi_,\cdots,\phi_n\rangle_\nu \\ a^(\phi_i) , \phi_1,\phi_2,\cdots,\phi_,\phi_,\cdots,\phi_n\rangle_\nu &=& \sqrt , \phi_1,\phi ...
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Quantum Mechanics
Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, quantum field theory, quantum technology, and quantum information science. Classical physics, the collection of theories that existed before the advent of quantum mechanics, describes many aspects of nature at an ordinary (macroscopic) scale, but is not sufficient for describing them at small (atomic and subatomic) scales. Most theories in classical physics can be derived from quantum mechanics as an approximation valid at large (macroscopic) scale. Quantum mechanics differs from classical physics in that energy, momentum, angular momentum, and other quantities of a bound system are restricted to discrete values ( quantization); objects have characteristics of both particles and waves (wave–particle duality); and there are limits to ...
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Particle Number
The particle number (or number of particles) of a thermodynamic system, conventionally indicated with the letter ''N'', is the number of constituent particles in that system. The particle number is a fundamental parameter in thermodynamics which is conjugate to the chemical potential. Unlike most physical quantities, particle number is a dimensionless quantity. It is an extensive parameter, as it is directly proportional to the size of the system under consideration, and thus meaningful only for closed systems. A constituent particle is one that cannot be broken into smaller pieces at the scale of energy ''k·T'' involved in the process (where ''k'' is the Boltzmann constant and ''T'' is the temperature). For example, for a thermodynamic system consisting of a piston containing water vapour, the particle number is the number of water molecules in the system. The meaning of constituent particle, and thereby of particle number, is thus temperature-dependent. Determining the particle ...
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Observable
In physics, an observable is a physical quantity that can be measured. Examples include position and momentum. In systems governed by classical mechanics, it is a real-valued "function" on the set of all possible system states. In quantum physics, it is an operator, or gauge, where the property of the quantum state can be determined by some sequence of operations. For example, these operations might involve submitting the system to various electromagnetic fields and eventually reading a value. Physically meaningful observables must also satisfy transformation laws that relate observations performed by different observers in different frames of reference. These transformation laws are automorphisms of the state space, that is bijective transformations that preserve certain mathematical properties of the space in question. Quantum mechanics In quantum physics, observables manifest as linear operators on a Hilbert space representing the state space of quantum states. ...
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Fock Space
The Fock space is an algebraic construction used in quantum mechanics to construct the quantum states space of a variable or unknown number of identical particles from a single particle Hilbert space . It is named after V. A. Fock who first introduced it in his 1932 paper "Konfigurationsraum und zweite Quantelung" (" Configuration space and second quantization"). M.C. Reed, B. Simon, "Methods of Modern Mathematical Physics, Volume II", Academic Press 1975. Page 328. Informally, a Fock space is the sum of a set of Hilbert spaces representing zero particle states, one particle states, two particle states, and so on. If the identical particles are bosons, the -particle states are vectors in a symmetrized tensor product of single-particle Hilbert spaces . If the identical particles are fermions, the -particle states are vectors in an antisymmetrized tensor product of single-particle Hilbert spaces (see symmetric algebra and exterior algebra respectively). A general state in Foc ...
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Fock State
In quantum mechanics, a Fock state or number state is a quantum state that is an element of a Fock space with a well-defined number of particles (or quanta). These states are named after the Soviet physicist Vladimir Fock. Fock states play an important role in the second quantization formulation of quantum mechanics. The particle representation was first treated in detail by Paul Dirac for bosons and by Pascual Jordan and Eugene Wigner for fermions. The Fock states of bosons and fermions obey useful relations with respect to the Fock space creation and annihilation operators. Definition One specifies a multiparticle state of N non-interacting identical particles by writing the state as a sum of tensor products of N one-particle states. Additionally, depending on the integrality of the particles' spin, the tensor products must be alternating (anti-symmetric) or symmetric products of the underlying one-particle Hilbert space. Specifically: * Fermions, having half-integer spin ...
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Basis (linear Algebra)
In mathematics, a set of vectors in a vector space is called a basis if every element of may be written in a unique way as a finite linear combination of elements of . The coefficients of this linear combination are referred to as components or coordinates of the vector with respect to . The elements of a basis are called . Equivalently, a set is a basis if its elements are linearly independent and every element of is a linear combination of elements of . In other words, a basis is a linearly independent spanning set. A vector space can have several bases; however all the bases have the same number of elements, called the ''dimension'' of the vector space. This article deals mainly with finite-dimensional vector spaces. However, many of the principles are also valid for infinite-dimensional vector spaces. Definition A basis of a vector space over a field (such as the real numbers or the complex numbers ) is a linearly independent subset of that spans . This me ...
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Creation And Annihilation Operators
Creation operators and annihilation operators are mathematical operators that have widespread applications in quantum mechanics, notably in the study of quantum harmonic oscillators and many-particle systems. An annihilation operator (usually denoted \hat) lowers the number of particles in a given state by one. A creation operator (usually denoted \hat^\dagger) increases the number of particles in a given state by one, and it is the adjoint of the annihilation operator. In many subfields of physics and chemistry, the use of these operators instead of wavefunctions is known as second quantization. They were introduced by Paul Dirac. Creation and annihilation operators can act on states of various types of particles. For example, in quantum chemistry and many-body theory the creation and annihilation operators often act on electron states. They can also refer specifically to the ladder operators for the quantum harmonic oscillator. In the latter case, the raising operator is in ...
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Harmonic Oscillator
In classical mechanics, a harmonic oscillator is a system that, when displaced from its Mechanical equilibrium, equilibrium position, experiences a restoring force ''F'' Proportionality (mathematics), proportional to the displacement ''x'': \vec F = -k \vec x, where ''k'' is a positive coefficient, constant. If ''F'' is the only force acting on the system, the system is called a simple harmonic oscillator, and it undergoes simple harmonic motion: sinusoidal oscillations about the equilibrium point, with a constant amplitude and a constant frequency (which does not depend on the amplitude). If a frictional force (Damping ratio, damping) proportional to the velocity is also present, the harmonic oscillator is described as a damped oscillator. Depending on the friction coefficient, the system can: * Oscillate with a frequency lower than in the Damping ratio, undamped case, and an amplitude decreasing with time (Damping ratio, underdamped oscillator). * Decay to the equilibrium p ...
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Quantum Harmonic Oscillator
量子調和振動子 は、 古典調和振動子 の 量子力学 類似物です。任意の滑らかな ポテンシャル は通常、安定した 平衡点 の近くで 調和ポテンシャル として近似できるため、最も量子力学における重要なモデル系。さらに、これは正確な 解析解法が知られている数少ない量子力学系の1つである。 author=Griffiths, David J. , title=量子力学入門 , エディション=2nd , 出版社=プレンティス・ホール , 年=2004 , isbn=978-0-13-805326-0 , author-link=David Griffiths (物理学者) , URL アクセス = 登録 , url=https://archive.org/details/introductiontoel00grif_0 One-dimensional harmonic oscillator Hamiltonian and energy eigenstates 粒子の ハミルトニアン は次のとおりです。 \hat H = \frac + \frac k ^2 = \frac + \frac m \omega^2 ^2 \, , ここで、 は粒子の質量、 は力定数、\omega = \sqrt は 動子の [角周波数 ...
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Second Quantization
Second quantization, also referred to as occupation number representation, is a formalism used to describe and analyze quantum many-body systems. In quantum field theory, it is known as canonical quantization, in which the fields (typically as the wave functions of matter) are thought of as field operators, in a manner similar to how the physical quantities (position, momentum, etc.) are thought of as operators in first quantization. The key ideas of this method were introduced in 1927 by Paul Dirac, and were later developed, most notably, by Pascual Jordan and Vladimir Fock. In this approach, the quantum many-body states are represented in the Fock state basis, which are constructed by filling up each single-particle state with a certain number of identical particles. The second quantization formalism introduces the creation and annihilation operators to construct and handle the Fock states, providing useful tools to the study of the quantum many-body theory. Quantum many-body ...
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Quantum Field Theory
In theoretical physics, quantum field theory (QFT) is a theoretical framework that combines classical field theory, special relativity, and quantum mechanics. QFT is used in particle physics to construct physical models of subatomic particles and in condensed matter physics to construct models of quasiparticles. QFT treats particles as excited states (also called Quantum, quanta) of their underlying quantum field (physics), fields, which are more fundamental than the particles. The equation of motion of the particle is determined by minimization of the Lagrangian, a functional of fields associated with the particle. Interactions between particles are described by interaction terms in the Lagrangian (field theory), Lagrangian involving their corresponding quantum fields. Each interaction can be visually represented by Feynman diagrams according to perturbation theory (quantum mechanics), perturbation theory in quantum mechanics. History Quantum field theory emerged from the wo ...
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Thermodynamics
Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to a wide variety of topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering and mechanical engineering, but also in other complex fields such as meteorology. Historically, thermodynamics developed out of a desire to increase the efficiency of early steam engines, particularly through the work of French physicist Sadi Carnot (1824) who believed that engine efficiency was the key that could help France win the Napoleonic Wars. Scots-Irish physicist Lord Kelvin was the first to formulate a ...
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