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Mori–Zwanzig Formalism
The Zwanzig projection operator is a mathematical device used in statistical mechanics. It operates in the linear space of phase space functions and projects onto the linear subspace of "slow" phase space functions. It was introduced by Robert Zwanzig to derive a generic master equation. It is mostly used in this or similar context in a formal way to derive equations of motion for some "slow" collective variables. Slow variables and scalar product The Zwanzig projection operator operates on functions in the 6N-dimensional phase space \Gamma=\ of N point particles with coordinates \mathbf_i and momenta \mathbf_i. A special subset of these functions is an enumerable set of "slow variables" A(\Gamma)=\. Candidates for some of these variables might be the long-wavelength Fourier components \rho_k(\Gamma) of the mass density and the long-wavelength Fourier components \mathbf_\mathbf(\Gamma) of the momentum density with the wave vector \mathbf identified with n. The Zwanzig projection ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Projection Operator
In linear algebra and functional analysis, a projection is a linear transformation P from a vector space to itself (an endomorphism) such that P\circ P=P. That is, whenever P is applied twice to any vector, it gives the same result as if it were applied once (i.e. P is idempotent). It leaves its image unchanged. This definition of "projection" formalizes and generalizes the idea of graphical projection. One can also consider the effect of a projection on a geometrical object by examining the effect of the projection on points in the object. Definitions A projection on a vector space V is a linear operator P : V \to V such that P^2 = P. When V has an inner product and is complete (i.e. when V is a Hilbert space) the concept of orthogonality can be used. A projection P on a Hilbert space V is called an orthogonal projection if it satisfies \langle P \mathbf x, \mathbf y \rangle = \langle \mathbf x, P \mathbf y \rangle for all \mathbf x, \mathbf y \in V. A projection on a Hilbert ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Statistical Mechanics
In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. It does not assume or postulate any natural laws, but explains the macroscopic behavior of nature from the behavior of such ensembles. Statistical mechanics arose out of the development of classical thermodynamics, a field for which it was successful in explaining macroscopic physical properties—such as temperature, pressure, and heat capacity—in terms of microscopic parameters that fluctuate about average values and are characterized by probability distributions. This established the fields of statistical thermodynamics and statistical physics. The founding of the field of statistical mechanics is generally credited to three physicists: *Ludwig Boltzmann, who developed the fundamental interpretation of entropy in terms of a collection of microstates *James Clerk Maxwell, who developed models of probability distr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Phase Space
In dynamical system theory, a phase space is a space in which all possible states of a system are represented, with each possible state corresponding to one unique point in the phase space. For mechanical systems, the phase space usually consists of all possible values of position and momentum variables. It is the outer product of direct space and reciprocal space. The concept of phase space was developed in the late 19th century by Ludwig Boltzmann, Henri Poincaré, and Josiah Willard Gibbs. Introduction In a phase space, every degree of freedom or parameter of the system is represented as an axis of a multidimensional space; a one-dimensional system is called a phase line, while a two-dimensional system is called a phase plane. For every possible state of the system or allowed combination of values of the system's parameters, a point is included in the multidimensional space. The system's evolving state over time traces a path (a phase-space trajectory for the system) ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Robert Zwanzig
Robert Walter Zwanzig (born Brooklyn, New York, 9 April 1928 – died Bethesda, Maryland, May 15, 2014) was an American theoretical physicist and chemist who made important contributions to the statistical mechanics of irreversible processes, protein folding, and the theory of liquids and gases. Background Zwanzig received his bachelor's degree from Brooklyn Polytechnic Institute in 1948 and his master's degree from 1950 at the University of Southern California. In 1952 he completed a doctorate in physical chemistry at Caltech under the supervision of John G. Kirkwood. His thesis title was ''Quantum Hydrodynamics: a statistical mechanical theory of light scattering from simple non-polar fluids''. From 1951 to 1954 he worked as a post-doctoral researcher in theoretical chemistry at Yale University, and from 1954 to 1958 he was an assistant professor in chemistry at Johns Hopkins University. From 1958 to 1966 he was a physical chemist at the National Bureau of Standards and from 1 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Master Equation
In physics, chemistry and related fields, master equations are used to describe the time evolution of a system that can be modelled as being in a probabilistic combination of states at any given time and the switching between states is determined by a transition rate matrix. The equations are a set of differential equations – over time – of the probabilities that the system occupies each of the different states. Introduction A master equation is a phenomenological set of first-order differential equations describing the time evolution of (usually) the probability of a system to occupy each one of a discrete set of states with regard to a continuous time variable ''t''. The most familiar form of a master equation is a matrix form: : \frac=\mathbf\vec, where \vec is a column vector (where element ''i'' represents state ''i''), and \mathbf is the matrix of connections. The way connections among states are made determines the dimension of the problem; it is either *a d ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Collective Variables
A collective is a group of entities that share or are motivated by at least one common issue or interest, or work together to achieve a common objective. Collectives can differ from cooperatives in that they are not necessarily focused upon an economic benefit or saving, but can be that as well. The term "collective" is sometimes used to describe a species as a whole—for example, the human collective. For political purposes, a collective is defined by decentralized, or "majority-rules" decision making styles. Types of groups Collectives are sometimes characterised by attempts to share and exercise political and social power and to make decisions on a consensus-driven and egalitarian basis. A commune or intentional community, which may also be known as a "collective household", is a group of people who live together in some kind of dwelling or residence, or in some other arrangement (e.g., sharing land). Collective households may be organized for a specific purpose (e.g., ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hamilton Function
Hamilton may refer to: People * Hamilton (name), a common British surname and occasional given name, usually of Scottish origin, including a list of persons with the surname ** The Duke of Hamilton, the premier peer of Scotland ** Lord Hamilton (other), several Scottish, Irish and British peers, and some members of the judiciary, who may be referred to simply as ''Hamilton'' ** Clan Hamilton, an ancient Scottish kindred * Alexander Hamilton (1755–1804), first U.S. Secretary of the Treasury and one of the Founding Fathers of the United States * Lewis Hamilton, a British Formula One driver *William Rowan Hamilton (1805–1865), Irish physicist, astronomer, and mathematician for whom ''Hamiltonian mechanics'' is named *Hamílton (footballer) (born 1980), Togolese footballer Places Australia * Hamilton, New South Wales, suburb of Newcastle * Hamilton Hill, Western Australia, suburb of Perth * Hamilton, South Australia * Hamilton, Tasmania * Hamilton, Victoria Queensl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Microcanonical Ensemble
In statistical mechanics, the microcanonical ensemble is a statistical ensemble that represents the possible states of a mechanical system whose total energy is exactly specified. The system is assumed to be isolated in the sense that it cannot exchange energy or particles with its environment, so that (by conservation of energy) the energy of the system does not change with time. The primary macroscopic variables of the microcanonical ensemble are the total number of particles in the system (symbol: ), the system's volume (symbol: ), as well as the total energy in the system (symbol: ). Each of these is assumed to be constant in the ensemble. For this reason, the microcanonical ensemble is sometimes called the ensemble. In simple terms, the microcanonical ensemble is defined by assigning an equal probability to every microstate whose energy falls within a range centered at . All other microstates are given a probability of zero. Since the probabilities must add up to 1, the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Poisson Bracket
In mathematics and classical mechanics, the Poisson bracket is an important binary operation in Hamiltonian mechanics, playing a central role in Hamilton's equations of motion, which govern the time evolution of a Hamiltonian dynamical system. The Poisson bracket also distinguishes a certain class of coordinate transformations, called ''canonical transformations'', which map canonical coordinate systems into canonical coordinate systems. A "canonical coordinate system" consists of canonical position and momentum variables (below symbolized by q_i and p_i, respectively) that satisfy canonical Poisson bracket relations. The set of possible canonical transformations is always very rich. For instance, it is often possible to choose the Hamiltonian itself H =H(q, p, t) as one of the new canonical momentum coordinates. In a more general sense, the Poisson bracket is used to define a Poisson algebra, of which the algebra of functions on a Poisson manifold is a special case. There are ot ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Langevin Equation
In physics, a Langevin equation (named after Paul Langevin) is a stochastic differential equation describing how a system evolves when subjected to a combination of deterministic and fluctuating ("random") forces. The dependent variables in a Langevin equation typically are collective (macroscopic) variables changing only slowly in comparison to the other (microscopic) variables of the system. The fast (microscopic) variables are responsible for the stochastic nature of the Langevin equation. One application is to Brownian motion, which models the fluctuating motion of a small particle in a fluid. Brownian motion as a prototype The original Langevin equation describes Brownian motion, the apparently random movement of a particle in a fluid due to collisions with the molecules of the fluid, m\frac=-\lambda \mathbf+\boldsymbol\left( t\right). Here, \mathbf is the velocity of the particle, and m is its mass. The force acting on the particle is written as a sum of a viscous force ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Liouville's Theorem (Hamiltonian)
In physics, Liouville's theorem, named after the French mathematician Joseph Liouville, is a key theorem in classical statistical and Hamiltonian mechanics. It asserts that ''the phase-space distribution function is constant along the trajectories of the system''—that is that the density of system points in the vicinity of a given system point traveling through phase-space is constant with time. This time-independent density is in statistical mechanics known as the classical a priori probability. There are related mathematical results in symplectic topology and ergodic theory; systems obeying Liouville's theorem are examples of incompressible dynamical systems. There are extensions of Liouville's theorem to stochastic systems. Liouville equations The Liouville equation describes the time evolution of the ''phase space distribution function''. Although the equation is usually referred to as the "Liouville equation", Josiah Willard Gibbs was the first to recognize the impor ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nakajima–Zwanzig Equation
The Nakajima–Zwanzig equation (named after the physicists who developed it, Sadao Nakajima and Robert Zwanzig) is an integral equation describing the time evolution of the "relevant" part of a quantum-mechanical system. It is formulated in the density matrix formalism and can be regarded a generalization of the master equation. The equation belongs to the Mori-Zwanzig formalism within the statistical mechanics of irreversible processes (named after Hazime Mori). By means of a projection operator the dynamics is split into a slow, collective part (''relevant part'') and a rapidly fluctuating ''irrelevant'' part. The goal is to develop dynamical equations for the collective part. Derivation The starting pointA derivation analogous to that presented here is found, for instance, in Breuer, Petruccione ''The theory of open quantum systems'', Oxford University Press 2002, S.443ff is the quantum mechanical version of the von Neumann equation, also known as the Liouville equation: ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
