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Manganese(II) Sulfide
Manganese(II) sulfide is a chemical compound of manganese and sulfur. It occurs in nature as the mineral alabandite (isometric), rambergite (hexagonal), and recently found browneite (isometric, with sphalerite-type structure, extremely rare, known only from a meteorite).Mindat, http://www.mindat.org/min-42751.html Synthesis Manganese(II) sulfide can be prepared by reacting a manganese(II) salt (such as manganese(II) chloride) with ammonium sulfide: : + → 2 + MnS Properties The crystal structure of manganese(II) sulfide is similar to that of sodium chloride. The pink color of MnS likely results from poor coupling between the lowest energy unoccupied Mn orbitals, resulting in discrete states rather than a delocalized band. Thus the lowest energy band-to-band electronic transition requires very high energy (ultraviolet) photons. See also *Alabandite, cubic MnS. * Manganese disulfide, MnS2, also known as Manganese(IV) Sulfide *Manganese(II) sulfate, MnSO4 *Rambergite Rambergi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alabandite
Alabandite or alabandine is a rarely occurring manganese sulfide mineral. It crystallizes in the cubic crystal system with the chemical composition Mn2+ S and develops commonly massive to granular aggregates, but rarely also cubic or octahedral crystals to 1 cm. Etymology and History Alabandite was first described in 1784 by Franz-Joseph Müller von Reichenstein. The mineral name is derived from its supposed discovery locality at Alabanda (Aïdin) in Turkey. Occurrence Alabandite forms in epithermal polymetallic sulfide veins and low-temperature manganese deposits. It occurs with acanthite, calcite, chalcopyrite, galena, pyrite, quartz, rhodochrosite, rhodonite, sphalerite and native tellurium. Sometimes it was found in meteorites. Localities are several areas in Antarctica, Argentina, Armenia, Australia, Bolivia, Brazil, Bulgaria, Canada, China, Czech Republic, Finland, France, Germany, Ghana, Greece, Greenland, India, Italy, Japan, Kyrgyzstan, Mexico, New Zealand, No ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfur
Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula S8. Elemental sulfur is a bright yellow, crystalline solid at room temperature. Sulfur is the tenth most abundant element by mass in the universe and the fifth most on Earth. Though sometimes found in pure, native form, sulfur on Earth usually occurs as sulfide and sulfate minerals. Being abundant in native form, sulfur was known in ancient times, being mentioned for its uses in ancient India, ancient Greece, China, and ancient Egypt. Historically and in literature sulfur is also called brimstone, which means "burning stone". Today, almost all elemental sulfur is produced as a byproduct of removing sulfur-containing contaminants from natural gas and petroleum.. Downloahere The greatest commercial use of the element is the production o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Manganese(II) Compounds
Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy uses, particularly in stainless steels. It improves strength, workability, and resistance to wear. Manganese oxide is used as an oxidising agent; as a rubber additive; and in glass making, fertilisers, and ceramics. Manganese sulfate can be used as a fungicide. Manganese is also an essential human dietary element, important in macronutrient metabolism, bone formation, and free radical defense systems. It is a critical component in dozens of proteins and enzymes. It is found mostly in the bones, but also the liver, kidneys, and brain. In the human brain, the manganese is bound to manganese metalloproteins, most notably glutamine synthetase in astrocytes. Manganese was first isolated in 1774. It is familiar in the laboratory in the form of the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rambergite
Rambergite is a manganese sulfide mineral with formula . It has been found in anoxic marine sediments, rich in organic matter of the Gotland Deep, Baltic Sea and also in skarn in the Garpenberg area, Dalarna, Sweden. It was named after the mineralogist, Hans Ramberg (1917–1998).http://webmineral.com/data/Rambergite.shtml Webmineral data It is a member of the wurtzite group and is chemically related to Hauerite Hauerite is a manganese sulfide mineral with the chemical formula Mn S2. It forms reddish brown or black octahedral crystals with the pyrite structure and it is usually found associated with the sulfides of other transition metals such as ramber .... References Sulfide minerals Manganese(II) minerals Hexagonal minerals Minerals in space group 186 Minerals described in 1996 {{Manganese minerals ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Manganese(II) Sulfate
Manganese(II) sulfate usually refers to the inorganic compound with the formula MnSO4·H2O. This pale pink deliquescent solid is a commercially significant manganese(II) salt. Approximately 260,000 tonnes of manganese(II) sulfate were produced worldwide in 2005. It is the precursor to manganese metal and many other chemical compounds. Manganese-deficient soil is remediated with this salt. Structure The structure of MnSO4·H2O has been determined by X-ray crystallography. Like many metal sulfates, manganese sulfate forms a variety of hydrates: monohydrate, tetrahydrate, pentahydrate, and heptahydrate. All of these salts dissolve in water to give faintly pink solutions of the aquo complex n(H2O)6sup>2+. Applications and production Typically, manganese ores are purified by their conversion to manganese(II) sulfate. Treatment of aqueous solutions of the sulfate with sodium carbonate leads to precipitation of manganese carbonate, which can be calcined to give the oxides MnO''x' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium Chloride
Sodium chloride , commonly known as salt (although sea salt also contains other chemical salts), is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chloride ions. With molar masses of 22.99 and 35.45 g/mol respectively, 100 g of NaCl contains 39.34 g Na and 60.66 g Cl. Sodium chloride is the salt most responsible for the salinity of seawater and of the extracellular fluid of many multicellular organisms. In its edible form, salt (also known as ''table salt'') is commonly used as a condiment and food preservative. Large quantities of sodium chloride are used in many industrial processes, and it is a major source of sodium and chlorine compounds used as feedstocks for further chemical syntheses. Another major application of sodium chloride is de-icing of roadways in sub-freezing weather. Uses In addition to the familiar domestic uses of salt, more dominant applications of the approximately 250 million tonnes per year production (2008 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ammonium Sulfide
Ammonium hydrosulfide is the chemical compound with the formula . Composition It is the salt derived from the ammonium cation and the hydrosulfide anion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve .... The salt exists as colourless, water-soluble, micaceous crystals. On Earth the compound is encountered mainly as a solution, not as the solid, but ice is believed to be a substantial component of the cloud decks of the gas-giant planets Jupiter and Saturn, with sulfur produced by its photolysis responsible for the color of some of those planets' clouds. It can be generated by mixing hydrogen sulfide and ammonia. Preparation Solutions of ammonium hydrosulfide can be prepared by passing hydrogen sulfide gas through concentrated ammonia solution. According to a detailed 1895 rep ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Manganese(II) Chloride
Manganese(II) chloride is the dichloride salt of manganese, MnCl2. This inorganic chemical exists in the anhydrous form, as well as the dihydrate (MnCl2·2H2O) and tetrahydrate (MnCl2·4H2O), with the tetrahydrate being the most common form. Like many Mn(II) species, these salts are pink, with the paleness of the color being characteristic of transition metal complexes with high spin d5 configurations. Preparation Manganese chloride is produced by treating manganese(IV) oxide with concentrated hydrochloric acid. :MnO2 + 4 HCl → MnCl2 + 2 H2O + Cl2 This reaction was once used for the manufacture of chlorine. By carefully neutralizing the resulting solution with MnCO3, one can selectively precipitate iron salts, which are common impurities in manganese dioxide.. In the laboratory, manganese chloride can be prepared by treating manganese metal or manganese(II) carbonate with hydrochloric acid: :Mn + 2 HCl + 4 H2O → MnCl2(H2O)4 + H2 :MnCO3 + 2 HCl + 3 H2O ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rambergite
Rambergite is a manganese sulfide mineral with formula . It has been found in anoxic marine sediments, rich in organic matter of the Gotland Deep, Baltic Sea and also in skarn in the Garpenberg area, Dalarna, Sweden. It was named after the mineralogist, Hans Ramberg (1917–1998).http://webmineral.com/data/Rambergite.shtml Webmineral data It is a member of the wurtzite group and is chemically related to Hauerite Hauerite is a manganese sulfide mineral with the chemical formula Mn S2. It forms reddish brown or black octahedral crystals with the pyrite structure and it is usually found associated with the sulfides of other transition metals such as ramber .... References Sulfide minerals Manganese(II) minerals Hexagonal minerals Minerals in space group 186 Minerals described in 1996 {{Manganese minerals ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alabandite
Alabandite or alabandine is a rarely occurring manganese sulfide mineral. It crystallizes in the cubic crystal system with the chemical composition Mn2+ S and develops commonly massive to granular aggregates, but rarely also cubic or octahedral crystals to 1 cm. Etymology and History Alabandite was first described in 1784 by Franz-Joseph Müller von Reichenstein. The mineral name is derived from its supposed discovery locality at Alabanda (Aïdin) in Turkey. Occurrence Alabandite forms in epithermal polymetallic sulfide veins and low-temperature manganese deposits. It occurs with acanthite, calcite, chalcopyrite, galena, pyrite, quartz, rhodochrosite, rhodonite, sphalerite and native tellurium. Sometimes it was found in meteorites. Localities are several areas in Antarctica, Argentina, Armenia, Australia, Bolivia, Brazil, Bulgaria, Canada, China, Czech Republic, Finland, France, Germany, Ghana, Greece, Greenland, India, Italy, Japan, Kyrgyzstan, Mexico, New Zealand, No ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Compound
A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element is therefore not a compound. A compound can be transformed into a different substance by a chemical reaction, which may involve interactions with other substances. In this process, bonds between atoms may be broken and/or new bonds formed. There are four major types of compounds, distinguished by how the constituent atoms are bonded together. Molecular compounds are held together by covalent bonds; ionic compounds are held together by ionic bonds; intermetallic compounds are held together by metallic bonds; coordination complexes are held together by coordinate covalent bonds. Non-stoichiometric compounds form a disputed marginal case. A chemical formula specifies the number of atoms of each element in a compound molecule, using the s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Halite
Halite (), commonly known as rock salt, is a type of salt, the mineral (natural) form of sodium chloride ( Na Cl). Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, pink, red, orange, yellow or gray depending on inclusion of other materials, impurities, and structural or isotopic abnormalities in the crystals. It commonly occurs with other evaporite deposit minerals such as several of the sulfates, halides, and borates. The name ''halite'' is derived from the Ancient Greek word for "salt", ἅλς (''háls''). Occurrence Halite dominantly occurs within sedimentary rocks where it has formed from the evaporation of seawater or salty lake water. Vast beds of sedimentary evaporite minerals, including halite, can result from the drying up of enclosed lakes and restricted seas. Such salt beds may be hundreds of meters thick and underlie broad areas. Halite occurs at the surface today in playas in regio ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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