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Magnesium Perchlorate
Magnesium perchlorate is a powerful oxidizing agent, with the formula Mg(ClO4)2. The salt is also a superior drying agent for gas analysis. Magnesium perchlorate decomposes at 250 °C. The heat of formation is -568.90 kJ mol−1. The enthalpy of solution is quite high, so reactions are done in large amounts of water to dilute it. It is sold under the trade name anhydrone. Manufacture of this product on a semi-industrial scale was first performed by G. Frederick Smith in his garage in Urbana Illinois, but later at a permanent facility in Columbus, OH called GFS Chemicals Inc, G. Frederick Smith Chemical Co. He sold the magnesium perchlorate to A. H. Thomas Co., noThomas Scientific under the trade name Dehydrite. Uses It is used as desiccant to dry gas or air samples, but is no longer advised, for use as a general desiccant, due to hazards inherent in perchlorates. It is dried by heating at 220 °C under vacuum. Magnesium perchlorate and other Perchlorate, perchlorates ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Deliquescent
Hygroscopy is the phenomenon of attracting and holding water molecules via either absorption or adsorption from the surrounding environment, which is usually at normal or room temperature. If water molecules become suspended among the substance's molecules, adsorbing substances can become physically changed, e.g., changing in volume, boiling point, viscosity or some other physical characteristic or property of the substance. For example, a finely dispersed hygroscopic powder, such as a salt, may become clumpy over time due to collection of moisture from the surrounding environment. ''Deliquescent'' materials are sufficiently hygroscopic that they absorb so much water that they become liquid and form an aqueous solution. Etymology and pronunciation The word ''hygroscopy'' () uses combining forms of '' hygro-'' and '' -scopy''. Unlike any other ''-scopy'' word, it no longer refers to a viewing or imaging mode. It did begin that way, with the word ''hygroscope'' referring in th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
American Elements
American Elements is a global manufacturer and distributor of advanced materials with a more than 35,000-page online product catalog and compendium of information on the chemical elements, advanced materials, and high technology applications. The company's headquarters and educational programs are based in Los Angeles, California. Its research and production facilities are located in Salt Lake City, Utah; Monterrey, Mexico; Baotou, China; and Manchester, UK. History American Elements began as a toll chemical manufacturer and refiner serving U.S. mining companies by producing metal-based chemicals from their deposits. In 1998, its two largest customers, the Unocal/Molycorp rare-earth mine in Mountain Pass, California and the Rhodia rare-earth refinery in Freeport, Texas closed, ending domestic U.S. rare-earth production. In response, the company established mining joint ventures in Inner Mongolia, China and in 1999 became one of the first post-Cold War companies to export rare-eart ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Calcium Perchlorate
Calcium perchlorate is classified as a metal perchlorate salt with the molecular formula . It is an inorganic compound that is a yellow-white crystalline solid in appearance. As a strong oxidizing agent, it reacts with reducing agents when heated to generate heat and products that may be gaseous (which will cause pressurization in closed containers). Calcium perchlorate has been categorized as having explosive reactivity. is a common chemical on the soil of planet Mars, counting for almost 1% of the Martian dust, by weight. Properties Calcium perchlorate is a strong inorganic oxidizing agent, enhancing the combustion of other substances that can potentially lead to explosion. The perchlorate ion, , has a highly symmetrical tetrahedral structure that is strongly stabilized in solution by its low electron-donating proton-accepting power and its relatively low polarizability. Eutectic system Calcium perchlorate solution forms a simple eutectic system. The eutectic composition ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Barium Perchlorate
Barium perchlorate is a powerful oxidizing agent, with the formula Ba(ClO4)2. It is used in the pyrotechnic industry. Barium perchlorate decomposes at 505 °C. Structure of barium perchlorate trihydrate Gallucci and Gerkin (1988) analyzed the structure of the hydrate isomer barium perchlorate trihydrate (Ba(ClO4)2•3H2O) by X-ray crystallography. The barium ions are coordinated by six water oxygen atoms at 2.919Å and six perchlorate oxygens at 3.026Å in a distorted icosahedral arrangement. The perchlorate fails by a narrow margin to have regular tetrahedral geometry, and has an average Cl-O bond length of 1.433Å. The space-group assignment of the structure was resolved, with the centrosymmetric assignment of P63/m confirmed. Each axial perchlorate oxygen is hydrogen bonded to three water molecules and each trigonal oxygen is hydrogen bonded to two water molecules. This interaction is the reason that the perchlorate fails to be tetrahedral. Gallucci and Gerkin surmised ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxidizing Agent
An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or "Electron acceptor, accepts"/"receives" an electron from a (called the , , or ). In other words, an oxidizer is any substance that oxidizes another substance. The oxidation state, which describes the degree of loss of electrons, of the oxidizer decreases while that of the reductant increases; this is expressed by saying that oxidizers "undergo reduction" and "are reduced" while reducers "undergo oxidation" and "are oxidized". Common oxidizing agents are oxygen, hydrogen peroxide and the halogens. In one sense, an oxidizing agent is a chemical species that undergoes a chemical reaction in which it gains one or more electrons. In that sense, it is one component in an Redox, oxidation–reduction (redox) reaction. In the second sense, an oxidizing agent is a chemical species that transfers electronegative atoms, usually oxygen ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Enthalpy Of Solution
In thermochemistry, the enthalpy of solution ( heat of solution or enthalpy of solvation) is the enthalpy change associated with the dissolution of a substance in a solvent at constant pressure resulting in infinite dilution. The enthalpy of solution is most often expressed in kJ/ mol at constant temperature. The energy change can be regarded as being made of three parts: the endothermic breaking of bonds within the solute and within the solvent, and the formation of attractions between the solute and the solvent. An ideal solution has a null enthalpy of mixing. For a non-ideal solution it is an excess molar quantity. Energetics Dissolution by most gases is exothermic. That is, when a gas dissolves in a liquid solvent, energy is released as heat, warming both the system (i.e. the solution) and the surroundings. The temperature of the solution eventually decreases to match that of the surroundings. The equilibrium, between the gas as a separate phase and the gas in solution, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Trade Name
A trade name, trading name, or business name, is a pseudonym used by companies that do not operate under their registered company name. The term for this type of alternative name is a "fictitious" business name. Registering the fictitious name with a relevant government body is often required. In a number of countries, the phrase "trading as" (abbreviated to t/a) is used to designate a trade name. In the United States, the phrase "doing business as" (abbreviated to DBA, dba, d.b.a., or d/b/a) is used, among others, such as assumed business name or fictitious business name. In Canada, "operating as" (abbreviated to o/a) and "trading as" are used, although "doing business as" is also sometimes used. A company typically uses a trade name to conduct business using a simpler name rather than using their formal and often lengthier name. Trade names are also used when a preferred name cannot be registered, often because it may already be registered or is too similar to a name that is a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
GFS Chemicals Inc
GFS Chemicals Inc, formerly known as G. Frederick Smith Chemical Company, is a privately owned fine and specialty chemical company with headquarters in Powell, Ohio and manufacturing facilities in Columbus, Ohio. It was founded by G. Frederick Smith in Urbana, Illinois in 1924, and moved to Columbus, Ohio in 1928. GFS Chemicals currently serves over seventy countries and a variety of industries, including: Alternative energy, energy storage, pharmaceuticals, biotechnology, electronics, etching, and environmental and research analytics. The company has approximately 100 employees. Its various divisions are managed by three separate units: Organic Specialty Materials, Inorganic Specialty Materials, and Analytical Reagents & Research Chemicals Catalog Division. History 1920s The Smith Chemical Company was started in G. Frederick Smith's garage in Urbana, Illinois as a result of his use of magnesium perchlorate as a super drying agent. Smith enlisted the help of his brothers Allyn ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Desiccant
A desiccant is a hygroscopic substance that is used to induce or sustain a state of dryness (desiccation) in its vicinity; it is the opposite of a humectant. Commonly encountered pre-packaged desiccants are solids that absorb water. Desiccants for specialized purposes may be in forms other than solid, and may work through other principles, such as chemical bonding of water molecules. They are commonly encountered in foods to retain crispness. Industrially, desiccants are widely used to control the level of water in gas streams. Types of desiccants Although some desiccants are chemically inert, others are extremely reactive and require specialized handling techniques. The most common desiccant is silica gel, an otherwise inert, nontoxic, water-insoluble white solid. Tens of thousands of tons are produced annually for this purpose. Other common desiccants include activated charcoal, calcium sulfate, calcium chloride, and molecular sieves (typically, zeolites). Desiccants ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Journal Of The American Chemical Society
The ''Journal of the American Chemical Society'' is a weekly peer-reviewed scientific journal that was established in 1879 by the American Chemical Society. The journal has absorbed two other publications in its history, the ''Journal of Analytical and Applied Chemistry'' (July 1893) and the ''American Chemical Journal'' (January 1914). It covers all fields of chemistry. Since 2021, the editor-in-chief is Erick M. Carreira (ETH Zurich). In 2014, the journal moved to a hybrid open access publishing model. Abstracting and indexing The journal is abstracted and indexed in Chemical Abstracts Service, Scopus, EBSCO databases, ProQuest databases, Index Medicus/MEDLINE/PubMed, and the Science Citation Index Expanded. According to the ''Journal Citation Reports'', the journal has a 2021 impact factor of 16.383. Editors-in-chief The following people are or have been editor-in-chief: * 1879–1880 – Hermann Endemann * 1880–1881 – Gideon E. Moore * 1881–1882 – Hermann Endemann ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Perchlorate
A perchlorate is a chemical compound containing the perchlorate ion, . The majority of perchlorates are commercially produced salts. They are mainly used as oxidizers for pyrotechnic devices and to control static electricity in food packaging. Perchlorate contamination in food, water, and other parts of the environment has been studied in the U.S. because of harmful effects on human health. Perchlorate ions are somewhat toxic to the thyroid gland. Most perchlorates are colorless solids that are soluble in water. Four perchlorates are of primary commercial interest: ammonium perchlorate , perchloric acid , potassium perchlorate and sodium perchlorate . Perchlorate is the anion resulting from the dissociation of perchloric acid and its salts upon their dissolution in water. Many perchlorate salts are soluble in non-aqueous solutions. Production Perchlorate salts are produced industrially by the oxidation of aqueous solutions of sodium chlorate by electrolysis. This method is used ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mars
Mars is the fourth planet from the Sun and the second-smallest planet in the Solar System, only being larger than Mercury (planet), Mercury. In the English language, Mars is named for the Mars (mythology), Roman god of war. Mars is a terrestrial planet with a thin atmosphere (less than 1% that of Earth's), and has a crust primarily composed of elements similar to Earth's crust, as well as a core made of iron and nickel. Mars has surface features such as impact craters, valleys, dunes and polar ice caps. It has two small and irregularly shaped moons, Phobos (moon), Phobos and Deimos (moon), Deimos. Some of the most notable surface features on Mars include Olympus Mons, the largest volcano and List of tallest mountains in the Solar System, highest known mountain in the Solar System and Valles Marineris, one of the largest canyons in the Solar System. The North Polar Basin (Mars), Borealis basin in the Northern Hemisphere covers approximately 40% of the planet and may be a la ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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