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Manganoan Calcite
Manganoan calcite or manganocalcite is a variety of calcite rich in manganese, which gives the mineral a pink color.Manganoan Calcite
at Mindat
Its chemical formula is . It was first reported from the Banská Štiavnica Mining District, Slovak Republic, but is widely distributed around the world, notably in the Cave of Swords at Naica, Chihuahua, Mexico as well as in

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Calcite
Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on Scratch hardness, scratch hardness comparison. Large calcite crystals are used in optical equipment, and limestone composed mostly of calcite has numerous uses. Other polymorphs of calcium carbonate are the minerals aragonite and vaterite. Aragonite will change to calcite over timescales of days or less at temperatures exceeding 300 °C, and vaterite is even less stable. Etymology Calcite is derived from the German ''Calcit'', a term from the 19th century that came from the Latin word for Lime (material), lime, ''calx'' (genitive calcis) with the suffix "-ite" used to name minerals. It is thus etymologically related to chalk. When applied by archaeology, archaeologists and stone trade pr ...
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Manganese
Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy uses, particularly in stainless steels. It improves strength, workability, and resistance to wear. Manganese oxide is used as an oxidising agent; as a rubber additive; and in glass making, fertilisers, and ceramics. Manganese sulfate can be used as a fungicide. Manganese is also an essential human dietary element, important in macronutrient metabolism, bone formation, and free radical defense systems. It is a critical component in dozens of proteins and enzymes. It is found mostly in the bones, but also the liver, kidneys, and brain. In the human brain, the manganese is bound to manganese metalloproteins, most notably glutamine synthetase in astrocytes. Manganese was first isolated in 1774. It is familiar in the laboratory in the form of the ...
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Banská Štiavnica
Banská Štiavnica (; german: Schemnitz; hu, Selmecbánya (Selmec), ) is a town in central Slovakia, in the middle of an immense caldera created by the collapse of an ancient volcano. For its size, the caldera is known as the Štiavnica Mountains. Banská Štiavnica has a population of more than 10,000. It is a completely preserved medieval town. Because of their historical value, the town and its surroundings were proclaimed by the UNESCO to be a World Heritage Site on December 11, 1993. History The fate of Banská Štiavnica has been closely linked to the exploitation of its abundant resources of silver ore. According to evidence from excavations, the site was settled during the Neolithic period. The first mining settlement was founded by Celts in the 3rd century BC. It was probably occupied by the Celtic Cotini tribe. Roman authors mentioned mining activities of the Cotini, who had lived in present-day central Slovakia until they were deported to Pannonia within the Marcomann ...
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Slovak Republic
Slovakia (; sk, Slovensko ), officially the Slovak Republic ( sk, Slovenská republika, links=no ), is a landlocked country in Central Europe. It is bordered by Poland to the north, Ukraine to the east, Hungary to the south, Austria to the southwest, and the Czech Republic to the northwest. Slovakia's mostly mountainous territory spans about , with a population of over 5.4 million. The capital and largest city is Bratislava, while the second largest city is Košice. The Slavs arrived in the territory of present-day Slovakia in the fifth and sixth centuries. In the seventh century, they played a significant role in the creation of Samo's Empire. In the ninth century, they established the Principality of Nitra, which was later conquered by the Principality of Moravia to establish Great Moravia. In the 10th century, after the dissolution of Great Moravia, the territory was integrated into the Principality of Hungary, which then became the Kingdom of Hungary in 1000. In 1241 and ...
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Cave Of Swords
The Naica Mine of the Mexican state of Chihuahua, is a lead, zinc and silver mine. Located in Naica in the municipality of Saucillo, the Naica Mine is owned by Industrias Peñoles, the world's largest silver producer. Caverns discovered during mining operations contain gigantic crystals of (calcium sulfate dihydrate, gypsum, also sometimes called selenite. Peñoles announced in October 2015 that it was indefinitely suspending operations due to uncontrollable flooding at the Naica Mine. The peak underground air temperature was 58° C (136° F) with 100% relative humidity, which rapidly exposed the visitors to hyperthermia hazard and caused breathing difficulties. Because of the heat, unprotected researchers could only stay up to 10 minutes inside the cave. Longer visits required the use of a special suit fitted with a cooling system (ice reserve in a backpack with cooled water recirculating in polymer tubes installed over all the body surface) and delivering fresh air for an ea ...
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Naica, Chihuahua
Naica is a town in the Mexican state of Chihuahua. It is located in the municipality of Saucillo. As of 2010, the town of Naica had a population of 4,938, up from 4,775 in the 2005 INEGI Census. It is a mining town and the location of the renowned Naica Mine. See also *Cave of the Crystals Cave of the Crystals or Giant Crystal Cave () is a cave connected to the Naica Mine at a depth of , in Naica, Chihuahua, Mexico. It takes the form of a chamber within the limestone host rock of the mine, and is about long with a volume of . ... References Populated places in Chihuahua (state) Populated places established in 1828 {{Chihuahua-geo-stub ...
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Bulgaria
Bulgaria (; bg, България, Bǎlgariya), officially the Republic of Bulgaria,, ) is a country in Southeast Europe. It is situated on the eastern flank of the Balkans, and is bordered by Romania to the north, Serbia and North Macedonia to the west, Greece and Turkey to the south, and the Black Sea to the east. Bulgaria covers a territory of , and is the sixteenth-largest country in Europe. Sofia is the nation's capital and largest city; other major cities are Plovdiv, Varna and Burgas. One of the earliest societies in the lands of modern-day Bulgaria was the Neolithic Karanovo culture, which dates back to 6,500 BC. In the 6th to 3rd century BC the region was a battleground for ancient Thracians, Persians, Celts and Macedonians; stability came when the Roman Empire conquered the region in AD 45. After the Roman state splintered, tribal invasions in the region resumed. Around the 6th century, these territories were settled by the early Slavs. The Bulgars, led by Asp ...
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Rhodochrosite
Rhodochrosite is a manganese carbonate mineral with chemical composition MnCO3. In its (rare) pure form, it is typically a rose-red color, but impure specimens can be shades of pink to pale brown. It streaks white, and its Mohs hardness varies between 3.5 and 4. Its specific gravity is between 3.5 and 3.7. It crystallizes in the trigonal system, and cleaves with rhombohedral carbonate cleavage in three directions. Crystal twinning often is present. It is transparent to translucent with refractive indices of ''nω''=1.814 to 1.816, ''nε''=1.596 to 1.598. It is often confused with the manganese silicate, rhodonite, but is distinctly softer. It is officially listed as one of the National symbols of Argentina. Rhodochrosite forms a complete solid solution series with iron carbonate (siderite). Calcium, (as well as magnesium and zinc, to a limited extent) frequently substitutes for manganese in the structure, leading to lighter shades of red and pink, depending on the degree of substit ...
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Solid Solution
A solid solution, a term popularly used for metals, is a homogenous mixture of two different kinds of atoms in solid state and have a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The word "solution" is used to describe the intimate mixing of components at the atomic level and distinguishes these homogeneous materials from physical mixtures of components. Two terms are mainly associated with solid solutions - ''solvents'' and ''solutes,'' depending on the relative abundance of the atomic species. In general if two compounds are isostructural then a solid solution will exist between the end members (also known as parents). For example sodium chloride and potassium chloride have the same cubic crystal structure so it is possible to make a pure compound with any ratio of sodium to potassium (Na1-xKx)Cl by dissolving that ratio of NaCl and KCl in water and then evaporating the solution. A member of this family is sold under t ...
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University Of Delaware
The University of Delaware (colloquially UD or Delaware) is a public land-grant research university located in Newark, Delaware. UD is the largest university in Delaware. It offers three associate's programs, 148 bachelor's programs, 121 master's programs (with 13 joint degrees), and 55 doctoral programs across its eight colleges. The main campus is in Newark, with satellite campuses in Dover, Wilmington, Lewes, and Georgetown. It is considered a large institution with approximately 18,200 undergraduate and 4,200 graduate students. It is a privately governed university which receives public funding for being a land-grant, sea-grant, and space-grant state-supported research institution. UDel is ranked among the top 150 universities in the U.S. UD is classified among "R1: Doctoral Universities – Very high research activity". According to the National Science Foundation, UD spent $186 million on research and development in 2018, ranking it 119th in the nation. It is rec ...
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Carbonate Minerals
Carbonate minerals are those minerals containing the carbonate ion, . Carbonate divisions Anhydrous carbonates *Calcite group: trigonal **Calcite CaCO3 **Gaspéite (Ni,Mg,Fe2+)CO3 **Magnesite MgCO3 **Otavite CdCO3 **Rhodochrosite MnCO3 **Siderite FeCO3 **Smithsonite ZnCO3 **Spherocobaltite CoCO3 *Aragonite group: orthorhombic **Aragonite CaCO3 **Cerussite PbCO3 **Strontianite SrCO3 **Witherite BaCO3 **Rutherfordine UO2CO3 **Natrite Na2CO3 Anhydrous carbonates with compound formulas *Dolomite group: trigonal **Ankerite CaFe(CO3)2 **Dolomite (mineral), Dolomite CaMg(CO3)2 **Huntite Mg3Ca(CO3)4 **Minrecordite CaZn(CO3)2 **Barytocalcite BaCa(CO3)2 Carbonates with hydroxyl or halogen *Carbonate with hydroxide: monoclinic **Azurite Cu3(CO3)2(OH)2 **Hydrocerussite Pb3(CO3)2(OH)2 **Malachite Cu2CO3(OH)2 **Rosasite (Cu,Zn)2CO3(OH)2 **Phosgenite Pb2(CO3)Cl2 **Hydrozincite Zn5(CO3)2(OH)6 **Aurichalcite (Zn,Cu)5(CO3)2(OH)6 Hydrated carbonates *Hydromagnesite Mg5(CO3)4(OH)2.4H2O *Ikaite ...
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