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Metaldehyde is an organic compound with the formula (C8H16O4). It is used as a pesticide against slugs, snails, and other gastropods. It is the cyclic tetramer of acetaldehyde. Production and properties Metaldehyde is flammable, toxic if ingested in large quantities, and irritating to the skin and eyes.  It has a white crystalline appearance with a menthol odor. Metaldehyde is obtained in moderate yields by treatment of acetaldehyde with various acid catalysts, such as hydrogen bromide, and cooling. The liquid trimer, paraldehyde is also obtained. The reaction is reversible; upon heating to about 80 °C, metaldehyde and paraldehyde revert to acetaldehyde. Metaldehyde exists as a mixture of four stereoisomers, molecules that differ with respect to the relative orientation of the methyl groups on the 8-membered ring. The stereoisomers have respectively the molecular symmetries C (with symmetry of order 2), C (order 4), D (order 8), and C (order 8). All have at least ...
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Organic Compound
In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The study of the properties, reactions, and syntheses of organic compounds comprise the discipline known as organic chemistry. For historical reasons, a few classes of carbon-containing compounds (e.g., carbonate salts and cyanide salts), along with a few other exceptions (e.g., carbon dioxide, hydrogen cyanide), are not classified as organic compounds and are considered inorganic. Other than those just named, little consensus exists among chemists on precisely which carbon-containing compounds are excluded, making any rigorous definition of an organic compound elusive. Although organic compounds make up only a small percentage of Earth's crust, they are of central importance because all known life is based on organic compounds. Living t ...
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Trade Name
A trade name, trading name, or business name, is a pseudonym used by companies that do not operate under their registered company name. The term for this type of alternative name is a "fictitious" business name. Registering the fictitious name with a relevant government body is often required. In a number of countries, the phrase "trading as" (abbreviated to t/a) is used to designate a trade name. In the United States, the phrase "doing business as" (abbreviated to DBA, dba, d.b.a., or d/b/a) is used, among others, such as assumed business name or fictitious business name. In Canada, "operating as" (abbreviated to o/a) and "trading as" are used, although "doing business as" is also sometimes used. A company typically uses a trade name to conduct business using a simpler name rather than using their formal and often lengthier name. Trade names are also used when a preferred name cannot be registered, often because it may already be registered or is too similar to a name that is a ...
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Molluscicides
Molluscicides () – also known as snail baits, snail pellets, or slug pellets – are pesticides against molluscs, which are usually used in agriculture or gardening, in order to control Pest (organism)#Gastropods, gastropod pests specifically slugs and snails which damage crops or other valued plants by feeding on them. A number of chemicals can be employed as a molluscicide: * Metal salt (chemistry), salts such as iron(III) phosphate, aluminium sulfate, and ferric sodium EDTA, relatively non-toxic, also used in organic gardening * Metaldehyde * Niclosamide * Acetylcholinesterase inhibitors (e.g. methiocarb), highly toxic to other animals and humans, acts also as a contact poison Accidental poisonings Metal salt-based molluscicides are not toxic to higher animals. However, metaldehyde-based and especially acetylcholinesterase inhibitor-based products are highly toxic, and have resulted in many deaths of pets and humans. Some products contain a bitter (taste), bittering agen ...
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A Wikimanual Of Gardening/Slugs
A, or a, is the first letter and the first vowel of the Latin alphabet, used in the modern English alphabet, the alphabets of other western European languages and others worldwide. Its name in English is ''a'' (pronounced ), plural ''aes''. It is similar in shape to the Ancient Greek letter alpha, from which it derives. The uppercase version consists of the two slanting sides of a triangle, crossed in the middle by a horizontal bar. The lowercase version can be written in two forms: the double-storey a and single-storey ɑ. The latter is commonly used in handwriting and fonts based on it, especially fonts intended to be read by children, and is also found in italic type. In English grammar, " a", and its variant " an", are indefinite articles. History The earliest certain ancestor of "A" is aleph (also written 'aleph), the first letter of the Phoenician alphabet, which consisted entirely of consonants (for that reason, it is also called an abjad to distinguis ...
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Paraldehyde
Paraldehyde is the cyclic trimer of acetaldehyde molecules. Formally, it is a derivative of 1,3,5-trioxane, with a methyl group substituted for a hydrogen atom at each carbon. The corresponding tetramer is metaldehyde. A colourless liquid, it is sparingly soluble in water and highly soluble in ethanol. Paraldehyde slowly oxidizes in air, turning brown and producing an odour of acetic acid. It quickly reacts with most plastics and rubber. Paraldehyde was first observed in 1835 by the German chemist Justus Liebig; its empirical formula was determined in 1838 by Liebig's student Hermann Fehling. The German chemist Valentin Hermann Weidenbusch (1821–1893), another of Liebig's students, synthesized paraldehyde in 1848 by treating acetaldehyde with acid (either sulfuric or nitric acid) and cooling to 0°C. He found it quite remarkable that when paraldehyde was ''heated'' with a trace of the same acid, the reaction went the other way, recreating acetaldehyde. Paraldehyde has uses i ...
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Methiocarb
Methiocarb is a carbamate pesticide (an acetylecholinesterase inhibitor) which is used as an insecticide, bird repellent, acaricide and molluscicide since the 1960s. Methiocarb has contact and stomach action on mites and neurotoxic effects on molluscs. Seeds treated with methiocarb also affect birds. Other names for methiocarb are mesurol and mercaptodimethur. Due to its toxicity, methiocarb approval as a plant protection product has been withdrawn by the EU effective 2020. Structure and reactivity The carbamate functional group in methiocarb can be cleaved by cholinesterase to result in the carbamate, which binds to the cholinesterase, and the aromatic alcohol. Synthesis Methiocarb (3) is synthesised by Bayer from 4-methylthio-3,5-xylenol (1) and methyl isocyanate (2). The xylenol (1) will act as the nucleophile in this reaction attacking the partially positively charged carbon in the isocyanate (2). Mechanism of action Methiocarb acts by acetylcholinesterase inhibition ...
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Bittering Agent
A bittering agent is a flavoring agent added to a food or beverage to impart a bitter taste, possibly in addition to other effects. While many substances are bitter to a greater or lesser degree, a few substances are used specifically for their bitterness, especially to balance other flavors, such as sweetness. Notable beverage examples include caffeine, found naturally in tea and coffee and added to many soft drinks, hops in beer, and quinine in tonic water. Food examples include bitter melon, which may be mixed into a stir fry or soup for its bitter flavor. Potent bittering agents may also be added to dangerous products as aversive agents to make them foul tasting, so as to prevent accidental poisoning. Examples including anti-freeze, household cleaning products and pesticides such as slug pellets. In general dangerous products with bright colours, which may be appealing to children, often contain agents such as denatonium. However, the efficacy of using bittering agents for thi ...
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Interwar Period
In the history of the 20th century, the interwar period lasted from 11 November 1918 to 1 September 1939 (20 years, 9 months, 21 days), the end of the World War I, First World War to the beginning of the World War II, Second World War. The interwar period was relatively short, yet featured many significant social, political, and economic changes throughout the world. Petroleum-based energy production and associated mechanisation led to the prosperous Roaring Twenties, a time of both social mobility and economic mobility for the middle class. Automobiles, electric lighting, radio, and more became common among populations in the developed world. The indulgences of the era subsequently were followed by the Great Depression, an unprecedented worldwide economic downturn that severely damaged many of the world's largest economies. Politically, the era coincided with the rise of communism, starting in Russia with the October Revolution and Russian Civil War, at the end of World War I ...
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Candy
Candy, also called sweets (British English) or lollies (Australian English Australian English (AusE, AusEng, AuE, AuEng, en-AU) is the set of varieties of the English language native to Australia. It is the country's common language and ''de facto'' national language; while Australia has no official language, Engli ..., New Zealand English), is a Confectionery, confection that features sugar as a principal ingredient. The category, called ''sugar confectionery'', encompasses any sweet confection, including chocolate, chewing gum, and sugar candy. Vegetable, Vegetables, fruit, or Nut (fruit), nuts which have been glaze (cooking technique), glazed and coated with sugar are said to be ''Candied fruit, candied''. Physically, candy is characterized by the use of a significant amount of sugar or sugar substitutes. Unlike a cake or loaf of bread that would be shared among many people, candies are usually made in smaller pieces. However, the definition of candy also depends ...
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Iron(III) Phosphate
Iron(III) phosphate, also ferric phosphate, is the inorganic compound with the formula Fe PO4. Several related materials are known, including four polymorphs of FePO4 and two polymorphs of the dihydrate FePO4·(H2O)2. These materials find few technical applications as well as occurring in the mineral kingdom. Structure The most common form of FePO4 adopts the structure of α-quartz. As such the material consists of tetrahedral Fe(III) and phosphate sites. As such the P and Fe have tetrahedral molecular geometry. At high pressures, a phase change occurs to a more dense structure with octahedral Fe centres. Two orthorhombic structures and a monoclinic phase are also known. In the two polymorphs of the dihydrate, the Fe centre is octahedral with two mutually cis water ligands. Uses Iron(III) phosphate can be used in steel and metal manufacturing processes. When bonded to a metal surface, iron phosphate prevents further oxidation of the metal. Its presence is partially r ...
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Ferric Sodium EDTA
Ferric sodium EDTA, also known as sodium ferric ethylenediaminetetraacetate, is a broad spectrum molluscicide used to kill snails and slugs and protect agricultural crops and garden plants, and in particular to eliminate infestations of ''Cornu aspersum'', the common garden snail. Chemically, it is a salt of ethylenediaminetetraacetic acid. Mechanism of action and environmental impacts Ferric sodium EDTA works by interacting with and destroying hemocyanin, a copper based compound found in the blood of molluscs and arthropods which is used to carry oxygen, similar to hemoglobin found in vertebrates, and typically kills snails and slugs in a matter of days following exposure. The compound is much safer than Metaldehyde Metaldehyde is an organic compound with the chemical formula, formula (C8H16O4). It is used as a pesticide against slugs, snails, and other gastropods. It is the cyclic tetramer of acetaldehyde. Production and properties Metaldehyde is flammable, ... and does n ...
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University Of California, Davis
The University of California, Davis (UC Davis, UCD, or Davis) is a public land-grant research university near Davis, California. Named a Public Ivy, it is the northernmost of the ten campuses of the University of California system. The institution was first founded as an agricultural branch of the system in 1905 and became the seventh campus of the University of California in 1959. The university is classified among "R1: Doctoral Universities – Very high research activity". The UC Davis faculty includes 23 members of the National Academy of Sciences, 30 members of the American Academy of Arts and Sciences, 17 members of the American Law Institute, 14 members of the Institute of Medicine, and 14 members of the National Academy of Engineering. Among other honors that university faculty, alumni, and researchers have won are two Nobel Prizes, one Fields Medal, a Presidential Medal of Freedom, three Pulitzer Prizes, three MacArthur Fellowships, and a National Medal of Scien ...
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