Ludwig Wilhelmy
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Ludwig Wilhelmy
Ludwig Ferdinand Wilhelmy (25 December 1812, Stargard in Pommern – 18 February 1864, Berlin) was a German scientist who is usually credited with publishing the first quantitative study in chemical kinetics. Scientific work Wilhelmy studied at Heidelberg, earning a doctorate in 1846. He worked as a Privatdozent from 1849 to 1854 before moving to Berlin. Wilhelmy's work in chemical kinetics concerned the acid-catalyzed conversion of a sucrose solution into a 1:1 mixture of fructose and glucose, a reaction that he followed with a polarimeter. He wrote a differential equation to describe the reaction, integrated it, and used it to interpret his experimental results. Wilhelmy found that the reaction's rate was proportional to the concentrations of sucrose and of acid present. He also examined the influence of temperature on the reaction. According to Moore, Wilhelmy received little credit from his contemporaries for his early investigations in the field of chemical ki ...
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Stargard
Stargard (; 1945: ''Starogród'', 1950–2016: ''Stargard Szczeciński''; formerly German language, German: ''Stargard in Pommern'', or ''Stargard an der Ihna''; csb, Stôrgard) is a city in northwestern Poland, located in the West Pomeranian Voivodeship. In 2021 it was inhabited by 67,293 people. It is situated on the Ina River. The city is the seat of the Stargard County, and, extraterritorially, of the municipality of Gmina Stargard, Stargard. It is the second biggest city of Szczecin agglomeration. Stargard is a major railroad junction, where the southwards connection from Szczecin splits into two directions: towards Poznań and Gdańsk. Etymology The city's name is of Pomeranian language, Pomeranian (Kashubian language, Kashubian) origin and stands for ''old'' (''stari'') ''town/city'' (''gard'' or ''gôrd''). In this meaning, the term ''gard'' is still being used by the only surviving Pomeranian language speakers, the Kashubs. However, some experts say that the name is ...
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Svante Arrhenius
Svante August Arrhenius ( , ; 19 February 1859 – 2 October 1927) was a Swedes, Swedish scientist. Originally a physicist, but often referred to as a chemist, Arrhenius was one of the founders of the science of physical chemistry. He received the Nobel Prize for Chemistry in 1903, becoming the first Sweden, Swedish Nobel laureate. In 1905, he became director of the Nobel Institute, where he remained until his death."Arrhenius, Svante August" in ''Chambers's Encyclopædia''. London: George Newnes Ltd, George Newnes, 1961, Vol. 1, p. 635. Arrhenius was the first to use principles of physical chemistry to estimate the extent to which increases in atmospheric carbon dioxide are responsible for the Earth's increasing surface temperature. His work played an important role in the emergence of modern climate science. In the 1960s, Charles David Keeling demonstrated that the quantity of human-caused carbon dioxide emissions into the air is enough to cause global warming. The Arrhenius ...
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Heidelberg University Alumni
Heidelberg (; Palatine German language, Palatine German: ''Heidlberg'') is a city in the States of Germany, German state of Baden-Württemberg, situated on the river Neckar in south-west Germany. As of the 2016 census, its population was 159,914, of which roughly a quarter consisted of students. Located about south of Frankfurt, Heidelberg is the List of cities in Baden-Württemberg by population, fifth-largest city in Baden-Württemberg. Heidelberg is part of the densely populated Rhine-Neckar, Rhine-Neckar Metropolitan Region. Heidelberg University, founded in 1386, is Germany's oldest and one of Europe's most reputable universities. Heidelberg is a Science, scientific hub in Germany and home to several internationally renowned #Research, research facilities adjacent to its university, including the European Molecular Biology Laboratory and four Max Planck Society, Max Planck Institutes. The city has also been a hub for the arts, especially literature, throughout the centurie ...
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1864 Deaths
Events January–March * January 13 – American songwriter Stephen Foster ("Oh! Susanna", "Old Folks at Home") dies aged 37 in New York City, leaving a scrap of paper reading "Dear friends and gentle hearts". His parlor song " Beautiful Dreamer" is published in March. * January 16 – Denmark rejects an Austrian-Prussian ultimatum to repeal the Danish Constitution, which says that Schleswig-Holstein is part of Denmark. * January 21 – New Zealand Wars: The Tauranga campaign begins. * February – John Wisden publishes '' The Cricketer's Almanack for the year 1864'' in England; it will go on to become the major annual cricket reference publication. * February 1 – Danish-Prussian War (Second Schleswig War): 57,000 Austrian and Prussian troops cross the Eider River into Denmark. * February 15 – Heineken brewery founded in Netherlands. * February 17 – American Civil War: The tiny Confederate hand-propelled submarine ''H. L. Hunley'' s ...
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1812 Births
Year 181 ( CLXXXI) was a common year starting on Sunday (link will display the full calendar) of the Julian calendar. At the time, it was known as the Year of the Consulship of Aurelius and Burrus (or, less frequently, year 934 ''Ab urbe condita''). The denomination 181 for this year has been used since the early medieval period, when the Anno Domini calendar era became the prevalent method in Europe for naming years. Events By place Roman Empire * Imperator Lucius Aurelius Commodus and Lucius Antistius Burrus become Roman Consuls. * The Antonine Wall is overrun by the Picts in Britannia (approximate date). Oceania * The volcano associated with Lake Taupō in New Zealand erupts, one of the largest on Earth in the last 5,000 years. The effects of this eruption are seen as far away as Rome and China. Births * April 2 – Xian of Han, Chinese emperor (d. 234) * Zhuge Liang, Chinese chancellor and regent (d. 234) Deaths * Aelius Aristides, Greek orator and w ...
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19th-century German Chemists
The 19th (nineteenth) century began on 1 January 1801 ( MDCCCI), and ended on 31 December 1900 ( MCM). The 19th century was the ninth century of the 2nd millennium. The 19th century was characterized by vast social upheaval. Slavery was abolished in much of Europe and the Americas. The First Industrial Revolution, though it began in the late 18th century, expanding beyond its British homeland for the first time during this century, particularly remaking the economies and societies of the Low Countries, the Rhineland, Northern Italy, and the Northeastern United States. A few decades later, the Second Industrial Revolution led to ever more massive urbanization and much higher levels of productivity, profit, and prosperity, a pattern that continued into the 20th century. The Gunpowder empires, Islamic gunpowder empires fell into decline and European imperialism brought much of South Asia, Southeast Asia, and almost all of Africa under Colonialism, colonial rule. It was also marked ...
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Chemical Kinetics
Chemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is to be contrasted with chemical thermodynamics, which deals with the direction in which a reaction occurs but in itself tells nothing about its rate. Chemical kinetics includes investigations of how experimental conditions influence the speed of a chemical reaction and yield information about the reaction's mechanism and transition states, as well as the construction of mathematical models that also can describe the characteristics of a chemical reaction. History In 1864, Peter Waage and Cato Guldberg pioneered the development of chemical kinetics by formulating the law of mass action, which states that the speed of a chemical reaction is proportional to the quantity of the reacting substances.C.M. Guldberg and P. Waage,"Studies Concerning Affinity" ''Forhandlinger i Videnskabs-Selskabet i Christiania'' (1864), 35P. W ...
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Surface Tension
Surface tension is the tendency of liquid surfaces at rest to shrink into the minimum surface area possible. Surface tension is what allows objects with a higher density than water such as razor blades and insects (e.g. water striders) to float on a water surface without becoming even partly submerged. At liquid–air interfaces, surface tension results from the greater attraction of liquid molecules to each other (due to cohesion) than to the molecules in the air (due to adhesion). There are two primary mechanisms in play. One is an inward force on the surface molecules causing the liquid to contract. Second is a tangential force parallel to the surface of the liquid. This ''tangential'' force is generally referred to as the surface tension. The net effect is the liquid behaves as if its surface were covered with a stretched elastic membrane. But this analogy must not be taken too far as the tension in an elastic membrane is dependent on the amount of deformation of the m ...
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Wilhelmy Plate
A Wilhelmy plate is a thin plate that is used to measure equilibrium surface or interfacial tension at an air–liquid or liquid–liquid interface. In this method, the plate is oriented perpendicular to the interface, and the force exerted on it is measured. Based on the work of Ludwig Wilhelmy, this method finds wide use in the preparation and monitoring of Langmuir films. Detailed description The Wilhelmy plate consists of a thin plate usually on the order of a few square centimeters in area. The plate is often made from filter paper, glass or platinum which may be roughened to ensure complete wetting. In fact, the results of the experiment do not depend on the material used, as long as the material is wetted by the liquid. The plate is cleaned thoroughly and attached to a balance with a thin metal wire. The force on the plate due to wetting is measured using a tensiometer or microbalance and used to calculate the surface tension (\gamma) using the Wilhelmy equation: :\ga ...
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Chemical Kinetics
Chemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is to be contrasted with chemical thermodynamics, which deals with the direction in which a reaction occurs but in itself tells nothing about its rate. Chemical kinetics includes investigations of how experimental conditions influence the speed of a chemical reaction and yield information about the reaction's mechanism and transition states, as well as the construction of mathematical models that also can describe the characteristics of a chemical reaction. History In 1864, Peter Waage and Cato Guldberg pioneered the development of chemical kinetics by formulating the law of mass action, which states that the speed of a chemical reaction is proportional to the quantity of the reacting substances.C.M. Guldberg and P. Waage,"Studies Concerning Affinity" ''Forhandlinger i Videnskabs-Selskabet i Christiania'' (1864), 35P. W ...
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Polarimetry
Polarimetry is the measurement and interpretation of the polarization of transverse waves, most notably electromagnetic waves, such as radio or light waves. Typically polarimetry is done on electromagnetic waves that have traveled through or have been reflected, refracted or diffracted by some material in order to characterize that object. Plane polarized light: According to the wave theory of light, an ordinary ray of light is considered to be vibrating in all planes of right angles to the direction of its propagation. If this ordinary ray of light is passed through a nicol prism, the emergent ray has its vibration only in one plane. Applications Polarimetry of thin films and surfaces is commonly known as ellipsometry. Polarimetry is used in remote sensing applications, such as planetary science, astronomy, and weather radar. Polarimetry can also be included in computational analysis of waves. For example, radars often consider wave polarization in post-processing to imp ...
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