Lorentz Oscillator Model
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Lorentz Oscillator Model
The Lorentz oscillator model describes the optical response of bound charges. The model is named after the Dutch physicist Hendrik Antoon Lorentz. It is a classical, phenomenological model for materials with characteristic resonance frequencies (or other characteristic energy scales) for optical absorption, e.g. ionic and molecular vibrations, interband transitions (semiconductors), phonons, and collective excitations. Derivation of electron motion The model is derived by modeling an electron orbiting a massive, stationary nucleus as a spring-mass-damper system. The electron is modeled to be connected to the nucleus via a hypothetical spring and its motion is damped by via a hypothetical damper. The damping force ensures that the oscillator's response is finite at its resonance frequency. For a time-harmonic driving force which originates from the electric field, Newton’s second law can be applied to the electron to obtain the motion of the electron and expressions for ...
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Lorentz Oscillator Model
The Lorentz oscillator model describes the optical response of bound charges. The model is named after the Dutch physicist Hendrik Antoon Lorentz. It is a classical, phenomenological model for materials with characteristic resonance frequencies (or other characteristic energy scales) for optical absorption, e.g. ionic and molecular vibrations, interband transitions (semiconductors), phonons, and collective excitations. Derivation of electron motion The model is derived by modeling an electron orbiting a massive, stationary nucleus as a spring-mass-damper system. The electron is modeled to be connected to the nucleus via a hypothetical spring and its motion is damped by via a hypothetical damper. The damping force ensures that the oscillator's response is finite at its resonance frequency. For a time-harmonic driving force which originates from the electric field, Newton’s second law can be applied to the electron to obtain the motion of the electron and expressions for ...
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Condensed Matter Physics
Condensed matter physics is the field of physics that deals with the macroscopic and microscopic physical properties of matter, especially the solid and liquid phases which arise from electromagnetic forces between atoms. More generally, the subject deals with "condensed" phases of matter: systems of many constituents with strong interactions between them. More exotic condensed phases include the superconducting phase exhibited by certain materials at low temperature, the ferromagnetic and antiferromagnetic phases of spins on crystal lattices of atoms, and the Bose–Einstein condensate found in ultracold atomic systems. Condensed matter physicists seek to understand the behavior of these phases by experiments to measure various material properties, and by applying the physical laws of quantum mechanics, electromagnetism, statistical mechanics, and other theories to develop mathematical models. The diversity of systems and phenomena available for study makes condensed matter phy ...
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Brendel–Bormann Oscillator Model
The Brendel–Bormann oscillator model is a mathematical formula for the frequency dependence of the complex-valued relative permittivity, sometimes referred to as the dielectric function. The model has been used to fit to the complex refractive index of materials with absorption lineshapes exhibiting Spectral_line_shape#Lorentzian, non-Lorentzian broadening, such as metals and amorphous insulators, across broad spectral ranges, typically near-ultraviolet, visible spectrum, visible, and infrared frequencies. The dispersion relation bears the names of R. Brendel and D. Bormann, who derived the model in 1992, despite first being applied to optical constants in the literature by Andrei M. Efimov and E. G. Makarova in 1983. Around that time, several other researchers also independently discovered the model. The Brendel-Bormann oscillator model is aphysical because it does not satisfy the Kramers–Kronig relations. The model is non-causal, due to a singularity at zero frequency, and Herm ...
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Tauc–Lorentz Model
The Tauc–Lorentz model is a mathematical formula for the frequency dependence of the complex-valued relative permittivity, sometimes referred to as the dielectric function. The model has been used to fit the complex refractive index of amorphous semiconductor materials at frequencies greater than their optical band gap. The dispersion relation bears the names of Jan Tauc and Hendrik Lorentz, whose previous works were combined by G. E. Jellison and F. A. Modine to create the model. The model was inspired, in part, by shortcomings of the Forouhi–Bloomer model, which is aphysical due to its incorrect asymptotic behavior and non-Hermitian character. Despite the inspiration, the Tauc–Lorentz model is itself aphysical due to being non-Hermitian and non-analytic in the upper half-plane. Further researchers have modified the model to address these shortcomings. Mathematical formulation The general form of the model is given by :\varepsilon(E) = \varepsilon_ + \chi^(E) where * \ ...
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Forouhi–Bloomer Model
The Forouhi–Bloomer model is a mathematical formula for the frequency dependence of the complex-valued refractive index. The model can be used to fit the refractive index of amorphous and crystalline semiconductor and dielectric materials at energies near and greater than their optical band gap. The dispersion relation bears the names of Rahim Forouhi and Iris Bloomer, who created the model and interpreted the physical significance of its parameters. The model is aphysical due to its incorrect asymptotic behavior and non-Hermitian character. These shortcomings inspired modified versions of the model as well as development of the Tauc–Lorentz model. Mathematical Formulation The complex refractive index is given by : \tilde(E) = n(E) + i \kappa(E) where * n is the real component of the complex refractive index, commonly called the refractive index, * \kappa is the imaginary component of the complex refractive index, commonly called the extinction coefficient, * E is the p ...
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Sellmeier Equation
The Sellmeier equation is an empirical relationship between refractive index and wavelength for a particular transparent medium. The equation is used to determine the dispersion of light in the medium. It was first proposed in 1872 by Wolfgang Sellmeier and was a development of the work of Augustin Cauchy on Cauchy's equation for modelling dispersion. The equation In its original and the most general form, the Sellmeier equation is given as : n^2(\lambda) = 1 + \sum_i \frac , where ''n'' is the refractive index, ''λ'' is the wavelength, and ''B''i and ''C''i are experimentally determined ''Sellmeier coefficients''. These coefficients are usually quoted for λ in micrometres. Note that this λ is the vacuum wavelength, not that in the material itself, which is λ/n. A different form of the equation is sometimes used for certain types of materials, e.g. crystals. Each term of the sum representing an absorption resonance of strength ''B''i at a wavelength . For example, the coe ...
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Cauchy's Equation
In optics, Cauchy's transmission equation is an empirical relationship between the refractive index and wavelength of light for a particular transparent material. It is named for the mathematician Augustin-Louis Cauchy, who defined it in 1837. The equation The most general form of Cauchy's equation is : n(\lambda) = A + \frac + \frac + \cdots, where ''n'' is the refractive index, λ is the wavelength, ''A'', ''B'', ''C'', etc., are coefficients that can be determined for a material by fitting the equation to measured refractive indices at known wavelengths. The coefficients are usually quoted for λ as the vacuum wavelength in micrometres. Usually, it is sufficient to use a two-term form of the equation: : n(\lambda) = A + \frac, where the coefficients ''A'' and ''B'' are determined specifically for this form of the equation. A table of coefficients for common optical materials is shown below: The theory of light-matter interaction on which Cauchy based this equation ...
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Optical Conductivity
Optical conductivity is the property of a material which gives the relationship between the induced current density in the material and the magnitude of the inducing electric field for arbitrary frequencies. This linear response function is a generalization of the electrical conductivity, which is usually considered in the static limit, i.e., for time-independent or slowly varying electric fields. While the static electrical conductivity is vanishingly small in insulators (such as diamond or porcelain), the optical conductivity always remains finite in some frequency intervals (above the optical gap in the case of insulators). The total optical weight can be inferred from sum rules. The optical conductivity is closely related to the dielectric function, the generalization of the dielectric constant to arbitrary frequencies. High Frequency Limit In the simplest cases, this property can be considered as a complex valued scalar function of frequency only. This formulation app ...
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Plasma Frequency
Plasma oscillations, also known as Langmuir waves (after Irving Langmuir), are rapid oscillations of the electron density in conducting media such as plasmas or metals in the ultraviolet region. The oscillations can be described as an instability in the dielectric function of a free electron gas. The frequency only depends weakly on the wavelength of the oscillation. The quasiparticle resulting from the quantization of these oscillations is the plasmon. Langmuir waves were discovered by American physicists Irving Langmuir and Lewi Tonks in the 1920s. They are parallel in form to Jeans instability waves, which are caused by gravitational instabilities in a static medium. Mechanism Consider an electrically neutral plasma in equilibrium, consisting of a gas of positively charged ions and negatively charged electrons. If one displaces by a tiny amount an electron or a group of electrons with respect to the ions, the Coulomb force pulls the electrons back, acting as a restoring fo ...
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Complex Number
In mathematics, a complex number is an element of a number system that extends the real numbers with a specific element denoted , called the imaginary unit and satisfying the equation i^= -1; every complex number can be expressed in the form a + bi, where and are real numbers. Because no real number satisfies the above equation, was called an imaginary number by René Descartes. For the complex number a+bi, is called the , and is called the . The set of complex numbers is denoted by either of the symbols \mathbb C or . Despite the historical nomenclature "imaginary", complex numbers are regarded in the mathematical sciences as just as "real" as the real numbers and are fundamental in many aspects of the scientific description of the natural world. Complex numbers allow solutions to all polynomial equations, even those that have no solutions in real numbers. More precisely, the fundamental theorem of algebra asserts that every non-constant polynomial equation with real or ...
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Hendrik Antoon Lorentz
Hendrik Antoon Lorentz (; 18 July 1853 – 4 February 1928) was a Dutch physicist who shared the 1902 Nobel Prize in Physics with Pieter Zeeman for the discovery and theoretical explanation of the Zeeman effect. He also derived the Lorentz transformation underpinning Albert Einstein's special theory of relativity, as well as the Lorentz force, which describes the combined electric and magnetic forces acting on a charged particle in an electromagnetic field. Lorentz was also responsible for the Lorentz oscillator model, a classical model used to describe the anomalous dispersion observed in dielectric materials when the driving frequency of the electric field was near the resonant frequency, resulting in abnormal refractive indices. According to the biography published by the Nobel Foundation, "It may well be said that Lorentz was regarded by all theoretical physicists as the world's leading spirit, who completed what was left unfinished by his predecessors and prepared the g ...
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