List Of Refrigerants
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List Of Refrigerants
This is a list of refrigerants, sorted by their ASHRAE-designated numbers, commonly known as R numbers. Many modern refrigerants are man-made halogenated gases, especially fluorinated gases and chlorinated gases, that are frequently referred to as Freon (a registered trademark of Chemours). The R number of a chemical refrigerant is assigned systematically according to molecular structure. First ASHRAE digit is the number of carbon atoms minus 1 (C-1); the second digit is the number of hydrogen atoms plus 1 (H+1); the third digit is the number of fluorine atoms; any remaining spaces are chlorine atoms. Eg.: R-22 aka R-022, which is chlorodifluoromethane. C=1 i.e. 1-1=0; H=1 i.e. 1+1=2; F=2 i.e 2; 1 remaining space 1=Cl. A "B" number means that one of the chlorine atoms is replaced by bromine (Br). This formula does not work with zeotropic or azeotropic blends. The table is sortable by each of the following refrigerant properties (scroll right or reduce magnification to view more ...
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American Society Of Heating, Refrigerating And Air-Conditioning Engineers
The American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE ) is an American professional association seeking to advance heating, ventilation, air conditioning and refrigeration (HVAC&R) systems design and construction. ASHRAE has over 57,000 members in more than 132 countries worldwide. ASHRAE's members are composed of building services engineers, architects, mechanical contractors, building owners, equipment manufacturers' employees, and others concerned with the design and construction of HVAC&R systems in buildings. The society funds research projects, offers continuing education programs, and develops and publishes technical standards to improve building services engineering, energy efficiency, indoor air quality, and sustainable development. History ASHRAE was founded in 1894 at a meeting of engineers in New York City, formerly headquartered at 345 East 47th Street, and has held an annual meeting since 1895. Until 1954 it was known as the Ame ...
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Boiling Point
The boiling point of a substance is the temperature at which the vapor pressure of a liquid equals the pressure surrounding the liquid and the liquid changes into a vapor. The boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at low pressure has a lower boiling point than when that liquid is at atmospheric pressure. Because of this, water boils at under standard pressure at sea level, but at at altitude. For a given pressure, different liquids will boiling, boil at different temperatures. The normal boiling point (also called the atmospheric boiling point or the atmospheric pressure boiling point) of a liquid is the special case in which the vapor pressure of the liquid equals the defined atmospheric pressure at sea level, one Atmosphere (unit), atmosphere. At that temperature, the vapor pressure of the liquid becomes suffici ...
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Chloroform
Chloroform, or trichloromethane, is an organic compound with chemical formula, formula Carbon, CHydrogen, HChlorine, Cl3 and a common organic solvent. It is a colorless, strong-smelling, dense liquid produced on a large scale as a precursor to PTFE. It is also a precursor to various refrigerants. It is trihalomethane. It is a powerful anesthetic, euphoriant, anxiolytic, and sedative when inhaled or ingested. Structure The molecule adopts a tetrahedral molecular geometry with C3v symmetry group, symmetry. Natural occurrence The total global flux of chloroform through the environment is approximately tonnes per year, and about 90% of emissions are natural in origin. Many kinds of seaweed produce chloroform, and fungi are believed to produce chloroform in soil. Abiotic processes are also believed to contribute to natural chloroform productions in soils although the mechanism is still unclear. Chloroform volatilizes readily from soil and surface water and undergoes degradation in ...
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Tetrafluoromethane
Tetrafluoromethane, also known as carbon tetrafluoride or R-14, is the simplest perfluorocarbon ( C F4). As its IUPAC name indicates, tetrafluoromethane is the perfluorinated counterpart to the hydrocarbon methane. It can also be classified as a haloalkane or halomethane. Tetrafluoromethane is a useful refrigerant but also a potent greenhouse gas. It has a very high bond strength due to the nature of the carbon–fluorine bond. Bonding Because of the multiple carbon–fluorine bonds, and the high electronegativity of fluorine, the carbon in tetrafluoromethane has a significant positive partial charge which strengthens and shortens the four carbon–fluorine bonds by providing additional ionic character. Carbon–fluorine bonds are the strongest single bonds in organic chemistry. Additionally, they strengthen as more carbon–fluorine bonds are added to the same carbon. In the one carbon organofluorine compounds represented by molecules of fluoromethane, difluoromethane, trifluorom ...
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Bromotrifluoromethane
Bromotrifluoromethane, commonly known as Halon 1301, R13B1, Halon 13B1 or BTM, is an organic halide with the chemical formula C Br F3. It is used for gaseous fire suppression as a far less toxic alternative to bromochloromethane. Table of physical properties Uses Halon 1301 was developed in a joint venture between the U.S. Army and DuPont in 1954, and introduced as an effective gaseous fire suppression fixed systems agent in the 1960s, and was used around valuable materials, such as aircraft, mainframe computers, and telecommunication switching centers, usually in total flooding systems . It was also widely used in the maritime industry to add a third level of protection should the main and emergency fire pumps become inoperable or ineffective. Halon 1301 was never widely used in portables outside military and spacecraft applications, due to its limited range, and invisible discharge. It does not produce the characteristic white cloud like CO2 and is difficult to direct ...
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Chlorotrifluoromethane
Chlorotrifluoromethane, R-13, CFC-13, or Freon 13, is a non-flammable, non-corrosive chlorofluorocarbon (CFC) and also a mixed halomethane. It is a man-made substance used primarily as a refrigerant. When released into the environment, CFC-13 has a high ozone depletion potential, high global warming potential, and long atmospheric lifetime. Preparation It can be prepared by reacting carbon tetrachloride with hydrogen fluoride in the presence of a catalytic amount of antimony pentachloride: CCl4 + 3HF → CClF3 + 3HCl This reaction can also produce trichlorofluoromethane (CCl3F), dichlorodifluoromethane (CCl2F2) and tetrafluoromethane (CF4). Production phaseout Per the international Montreal Protocol, CFC-13 began a phase out and replacement with alternative substances starting in the early 1990s that will culminate in a global ban on its production. The atmospheric abundance of CFC-13 rose from 3.0 parts per trillion (ppt) in year 2010 to 3.3 ppt in year 2020 based ...
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Dibromodifluoromethane
Dibromodifluoromethane is a mixed halomethane. It is a colorless non-flammable liquid. Along with Halons 1211, 2402, and 1301, it is one of the most effective fire extinguishers A fire extinguisher is a handheld active fire protection device usually filled with a dry or wet chemical used to extinguish or control small fires, often in emergencies. It is not intended for use on an out-of-control fire, such as one which ha ..., however, it is also very toxic. It is a class I ozone depleting substance (ODS). Table of physical properties References External links * * Photolysis of dibromodifluoromethane at 265 nmRaman and infrared spectra of solid dibromodifluoromethane {{fluorine compounds Halomethanes Fire suppression agents Ozone depletion Organobromides Organofluorides ...
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Bromochlorodifluoromethane
Bromochlorodifluoromethane (BCF), also referred to by the code numbers Halon 1211 and Freon 12B1, is a haloalkane with the chemical formula C F2 Cl Br. It is used for fire suppression, especially for expensive equipment or items that could be damaged by the residue from other types of extinguishers. Use as a fire extinguishing agent Brominated haloalkanes were first used during World War II in fire extinguishers for aircraft and tanks. BCF was introduced as an effective gaseous fire suppression agent in the mid-1960s for use around highly valuable materials in places such as museums, mainframe rooms, and telecommunication switching centers. BCFs were also widely used in the maritime industries in the engine rooms of ships and also in the transport industry in vehicles. Its efficiency as a fire extinguishing agent has also led it to be the predominant choice of fire extinguishing agent on commercial aircraft and is typically found in cylindrical hand-held canisters. Its advanta ...
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Dichlorodifluoromethane
Dichlorodifluoromethane (R-12) is a colorless gas usually sold under the brand name Freon-12, and a chlorofluorocarbon halomethane (CFC) used as a refrigerant and aerosol spray propellant. Complying with the Montreal Protocol, its manufacture was banned in developed countries (non-article 5 countries) in 1996, and developing countries (article 5 countries) in 2010 out of concerns about its damaging effect on the ozone layer. Its only allowed usage is as fire retardant in submarines and aircraft. It is soluble in many organic solvents. R-12 cylinders are colored white. Preparation It can be prepared by reacting carbon tetrachloride with hydrogen fluoride in the presence of a catalytic amount of antimony pentachloride: :CCl4 + 2HF → CCl2F2 + 2HCl This reaction can also produce trichlorofluoromethane (CCl3F), chlorotrifluoromethane (CClF3) and tetrafluoromethane (CF4). History Charles (Boss) Kettering, vice president of General Motors Research Corporation, was seeking a refriger ...
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Trichlorofluoromethane
Trichlorofluoromethane, also called freon-11, CFC-11, or R-11, is a chlorofluorocarbon (CFC). It is a colorless, faintly ethereal, and sweetish-smelling liquid that boils around room temperature. CFC-11 is a Class 1 ozone-depleting substance which damages Earth's protective stratospheric ozone layer. Historical use Trichlorofluoromethane was first widely used as a refrigerant. Because of its high boiling point (compared to most refrigerants), it can be used in systems with a low operating pressure, making the mechanical design of such systems less demanding than that of higher-pressure refrigerants R-12 or R-22. Trichlorofluoromethane is used as a reference compound for fluorine-19 NMR studies. Trichlorofluoromethane was formerly used in the drinking bird novelty, largely because it has a boiling point of . The replacement, dichloromethane, boiling point , requires a higher ambient temperature to work. Prior to the knowledge of the ozone depletion potential of chlorin ...
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Carbon Tetrachloride
Carbon tetrachloride, also known by many other names (such as tetrachloromethane, also IUPAC nomenclature of inorganic chemistry, recognised by the IUPAC, carbon tet in the cleaning industry, Halon-104 in firefighting, and Refrigerant-10 in HVACR) is an organic compound with the chemical formula CCl4. It is a colourless liquid with a "sweet" smell that can be detected at low levels. It is practically incombustible at lower temperatures. It was formerly widely used in fire extinguishers, as a precursor to refrigerants and as a cleaning agent, but has since been phased out because of environmental and safety concerns. Exposure to high concentrations of carbon tetrachloride (including vapor) can affect the central nervous system and degenerate the liver and kidneys. Prolonged exposure can be fatal. Properties In the carbon tetrachloride molecule, four chlorine atoms are positioned symmetrically as corners in a tetrahedron, tetrahedral configuration joined to a central carbon atom by ...
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Global Warming Potential
Global warming potential (GWP) is the heat absorbed by any greenhouse gas in the atmosphere, as a multiple of the heat that would be absorbed by the same mass of carbon dioxide (). GWP is 1 for . For other gases it depends on the gas and the time frame. Carbon dioxide equivalent (e or eq or -e) is calculated from GWP. For any gas, it is the mass of that would warm the earth as much as the mass of that gas. Thus it provides a common scale for measuring the climate effects of different gases. It is calculated as GWP times mass of the other gas. Methane has GWP (over 100 years) of 27.9 meaning that, for example, a leak of a tonne of methane is equivalent to emitting 27.9 tonnes of carbon dioxide. Similarly a tonne of nitrous oxide, from manure for example, is equivalent to 273 tonnes of carbon dioxide. Values Carbon dioxide is the reference. It has a GWP of 1 regardless of the time period used. emissions cause increases in atmospheric concentrations of that will last thousands ...
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