Larnite
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Larnite
Larnite is a calcium silicate mineral with formula: Ca2SiO4. It is the calcium member of the olivine group of minerals. It was first described from an occurrence at Scawt Hill, Larne, Northern Ireland in 1929 by Cecil Edgar Tilley and named for the location. At the type locality it occurs with wollastonite, spurrite, perovskite, merwinite, melilite and gehlenite. It occurs in contact metamorphosed limestones and chalks adjacent to basaltic intrusives. Dicalcium silicate is chemically, β–Ca2SiO4, sometimes represented by the formula 2CaO·SiO2. When used in the cement industry, the mineral is usually referred to as belite Belite is an industrial mineral important in Portland cement manufacture. Its main constituent is dicalcium silicate, Ca2SiO4, sometimes formulated as 2 CaO · SiO2 (C2S in cement chemist notation). Etymology The name was given by Törnebohm in .... References * Nesosilicates Monoclinic minerals Minerals in space group 14 {{silicate-mine ...
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Scawt Hill
Scawt Hill is a volcanic plug in County Antrim, Northern Ireland, in the borough of Larne, 5 km from the village of Ballygally. It gets its name from the Ulster Scots "" meaning scaly, scabby or rugged. Alternatively, '' 'scawt' '' meaning scruffy and contemptible, and when applied to rocks, covered in barnacles. Discovery of minerals Scawt Hill is notable for being the type locality for several hydrated calcium silicates, that is, the place where they were first identified. These minerals were formed when the existing chalk of the area was intensely altered by the intrusion of the feeder tube of an ancient volcano, now long since cooled and eroded to its roots.Wilson, H E et al (1986) Geological Survey of Northern Ireland, HMSO Minerals that were first discovered at Scawt Hill: * Larnite (''calcium orthosilicate'') a natural form of belite discovered in 1929 and named after Larne, the nearest town * Scawtite in 1929 * Portlandite in 1933 * Hydrocalumite in 1934 * Ran ...
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Belite
Belite is an industrial mineral important in Portland cement manufacture. Its main constituent is dicalcium silicate, Ca2SiO4, sometimes formulated as 2 CaO · SiO2 (C2S in cement chemist notation). Etymology The name was given by Törnebohm in 1897 to a crystal identified in microscopic investigation of Portland cement. Belite is a name in common use in the cement industry, but is not a recognised mineral name. It occurs naturally as the mineral larnite, the name being derived from Larne, Northern Ireland, the closest town to Scawt Hill where it was discovered. Composition and structure The belite found in Portland cement differs in composition from pure dicalcium silicate. It is a solid solution and contains minor amounts of other oxides besides CaO and SiO2. A typical composition:Taylor H.F.W. (1990), ''Cement Chemistry'', Academic Press, 1990, , pp. 10-11. Based on this, the formula can be expressed as Ca1.94Mg0.02Na0.01K0.03Fe0.02Al0.07Si0.90P0.01O3.93. In practic ...
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Dicalcium Silicate
Calcium silicate is the chemical compound Ca2SiO4, also known as calcium orthosilicate and is sometimes formulated as 2CaO·SiO2. It is also referred to by the shortened trade name Cal-Sil or Calsil. It occurs naturally as the mineral larnite. Properties Calcium silicate is a white free-flowing powder. It can be derived from naturally occurring limestone and diatomaceous earth, a siliceous sedimentary rock. It is one of a group of compounds that can be produced by reacting calcium oxide and silicon dioxide, silica in various ratios e.g. 3CaO·SiO2, alite, alite (Ca3SiO5); 2CaO·SiO2, (Ca2SiO4); 3CaO·2SiO2, (Ca3SiO7); and CaO·SiO2, wollastonite, wollastonite (CaSiO3). It has a low bulk density and high physical water absorption. Use Calcium silicate is used as an anticaking agent in food preparation, including table salt
and as an ...
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Olivine Group
The mineral olivine () is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers quickly on the surface. For this reason, olivine has been proposed as a good candidate for accelerated weathering to sequester carbon dioxide from the Earth's oceans and atmosphere, as part of climate change mitigation. Olivine also has many other historical uses, such as the gemstone peridot (or chrysolite), as well as industrial applications like metalworking processes. The ratio of magnesium to iron varies between the two endmembers of the solid solution series: forsterite (Mg-endmember: ) and fayalite (Fe-endmember: ). Compositions of olivine are commonly expressed as molar percentages of forsterite (Fo) and fayalite (Fa) (''e.g.'', Fo70Fa30). Forsterite's melting temperature is unusually high at atmospheric pressure, almost , while fayal ...
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Cecil Edgar Tilley
Cecil Edgar Tilley FRS Hon FRSE PGS (14 May 1894 – 24 January 1973) was an Australian-British petrologist and geologist. Life He was born in Unley, Adelaide, the youngest child of John Thomas Edward Tilley, a civil engineer from London, and his wife South Australia-born wife, Catherine Jane Nicholas. Cecil was educated at Adelaide High School, then studied Chemistry and Geology under William Rowan Browne at the University of Adelaide, and the University of Sydney, graduating in 1915. In 1916, during the First World War, he went to South Queensferry near Edinburgh in Scotland to work as a chemist Department of Explosives Supply. He returned to Australia in December 1918. He won an Exhibition of 1851 scholarship to the University of Cambridge in 1919, where he studied petrology under Alfred Harker, and completed his PhD in 1922. From 1923 he was employed at Cambridge University, first as demonstrator in petrology, and then lecturer in petrology in 1929. In 1931, followin ...
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Nesosilicate
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually considered a silicate mineral. Silica is found in nature as the mineral quartz, and its polymorphism (materials science), polymorphs. On Earth, a wide variety of silicate minerals occur in an even wider range of combinations as a result of the processes that have been forming and re-working the crust for billions of years. These processes include partial melting, crystallization, fractionation, metamorphism, weathering, and diagenesis. Living organisms also contribute to this carbonate–silicate cycle, geologic cycle. For example, a type of plankton known as diatoms construct their exoskeletons ("frustules") from silica extracted from seawater. The frustules of dead diatoms are a major constituent of deep ocean sediment, and of diatomaceous e ...
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Melilite
Melilite refers to a mineral of the melilite group. Minerals of the group are solid solutions of several endmembers, the most important of which are gehlenite and åkermanite. A generalized formula for common melilite is ( Ca, Na)2( Al, Mg, Fe2+) SiOxygen.html" ;"title="Silicon">Si)Silicon.html" ;"title="Silicon.html" ;"title=" Al,Silicon">Si)Silicon">SiOxygen">O7]. Discovered in 1793 near Rome, it has a yellowish, greenish-brown color. The name derives from the Greek words meli (μέλι) "honey" and lithos (λίθους) "stone".The name refers to a group of minerals (melilite group) with chemically similar composition, nearly always minerals in åkermanite-gehlenite series. Minerals of the melilite group are sorosilicates. They have the same basic structure, of general formula ''A''2''B(T''2O7). The melilite structure consist of pairs of fused ''T''O4, where ''T'' may be Si, Al, B, in bow-tie form. Sharing one corner, the formula of the pair is ''T''2O7. These bow-ties a ...
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Nesosilicates
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually considered a silicate mineral. Silica is found in nature as the mineral quartz, and its polymorphs. On Earth, a wide variety of silicate minerals occur in an even wider range of combinations as a result of the processes that have been forming and re-working the crust for billions of years. These processes include partial melting, crystallization, fractionation, metamorphism, weathering, and diagenesis. Living organisms also contribute to this geologic cycle. For example, a type of plankton known as diatoms construct their exoskeletons ("frustules") from silica extracted from seawater. The frustules of dead diatoms are a major constituent of deep ocean sediment, and of diatomaceous earth. General structure A silicate mineral is generally an ...
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Basaltic
Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90% of all volcanic rock on Earth is basalt. Rapid-cooling, fine-grained basalt is chemically equivalent to slow-cooling, coarse-grained gabbro. The eruption of basalt lava is observed by geologists at about 20 volcanoes per year. Basalt is also an important rock type on other planetary bodies in the Solar System. For example, the bulk of the plains of Venus, which cover ~80% of the surface, are basaltic; the lunar maria are plains of flood-basaltic lava flows; and basalt is a common rock on the surface of Mars. Molten basalt lava has a low viscosity due to its relatively low silica content (between 45% and 52%), resulting in rapidly moving lava flows that can spread over great areas before cooling and solidifying. Flood basalts are thick sequence ...
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Chalk
Chalk is a soft, white, porous, sedimentary carbonate rock. It is a form of limestone composed of the mineral calcite and originally formed deep under the sea by the compression of microscopic plankton that had settled to the sea floor. Chalk is common throughout Western Europe, where deposits underlie parts of France, and steep cliffs are often seen where they meet the sea in places such as the Dover cliffs on the Kent coast of the English Channel. Chalk is mined for use in industry, such as for quicklime, bricks and builder's putty, and in agriculture, for raising pH in soils with high acidity. It is also used for " blackboard chalk" for writing and drawing on various types of surfaces, although these can also be manufactured from other carbonate-based minerals, or gypsum. Description Chalk is a fine-textured, earthy type of limestone distinguished by its light color, softness, and high porosity. It is composed mostly of tiny fragments of the calcite shells or skeletons ...
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Limestone
Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms when these minerals precipitate out of water containing dissolved calcium. This can take place through both biological and nonbiological processes, though biological processes, such as the accumulation of corals and shells in the sea, have likely been more important for the last 540 million years. Limestone often contains fossils which provide scientists with information on ancient environments and on the evolution of life. About 20% to 25% of sedimentary rock is carbonate rock, and most of this is limestone. The remaining carbonate rock is mostly dolomite, a closely related rock, which contains a high percentage of the mineral dolomite, . ''Magnesian limestone'' is an obsolete and poorly-defined term used variously for dolomite, for limes ...
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Contact Metamorphism
Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of chemically active fluids, but the rock remains mostly solid during the transformation. Metamorphism is distinct from weathering or diagenesis, which are changes that take place at or just beneath Earth's surface. Various forms of metamorphism exist, including regional, contact, hydrothermal, shock, and dynamic metamorphism. These differ in the characteristic temperatures, pressures, and rate at which they take place and in the extent to which reactive fluids are involved. Metamorphism occurring at increasing pressure and temperature conditions is known as ''prograde metamorphism'', while decreasing temperature and pressure characterize ''retrograde metamorphism''. Metamorphic petrology is the study of metamorphism. Metamorphic petrologists re ...
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