Krytox
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Krytox
Krytox is a registered trademark of The Chemours Company. It refers to a group of colourless synthetic lubricants (oils and greases) with a variety of applications. Invented by researchers at DuPont, Krytox oils are fluorocarbon ether polymers of poly hexafluoropropylene oxide, with a chemical formula: F−(CF(CF3)−CF2−O)''n''−CF2CF3, where the degree of polymerization, n, generally lies within the range of 10 to 60. DuPont Krytox Performance Lubricants Product Overview, available onlinhere These compounds are collectively known by many names including perfluoropolyether (PFPE), perfluoroalkylether (PFAE) and perfluoropolyalkylether (PFPAE). A unique identifier is their CAS registry number, 60164-51-4. In addition to PFPE, Krytox grease also contains telomers of PTFE and in fact was designed as a liquid or grease form of PTFE. It is thermally stable, nonflammable (even in liquid oxygen), and insoluble in water, acids, bases, and most organic solvents. It is nonvolat ...
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Hexafluoropropylene Oxide
Hexafluoropropylene oxide (HFPO) is an intermediate used in industrial organofluorine chemistry; specifically it is a monomer for fluoropolymers. This colourless gas is the epoxide of hexafluoropropylene, that is fluorinated analog of propylene oxide, HFPO is produced by DuPont and 3M and as a precursor to the lubricant Krytox and related materials. It is generated by oxidation of perfluoropropylene, e.g. with oxygen as well as other oxidants. Reactivity Fluoride catalyzes the formation of the perfluorinated polyethers such as Krytox. The initial step entails nucleophilic attack at the middle carbon to give the perfluoropropoxide anion, which in turn attacks another monomer. This process generates a polymer terminated by an acyl fluoride, which is hydrolyzed to the carboxylic acid which is decarboxylated with fluorine. The net polymerization reaction can be represented as: :n+2 CF3CFCF2O → CF3CF2CF2O(CF(CF3)CF2O)nCF2CF3 + CO Upon heating above 150 °C, HFPO decom ...
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Grease (lubricant)
Grease is a solid or semisolid lubricant formed as a dispersion of thickening agents in a liquid lubricant. Grease generally consists of a soap emulsified with mineral or vegetable oil. A common feature of greases is that they possess a high initial viscosity, which upon the application of shear, drops to give the effect of an oil-lubricated bearing of approximately the same viscosity as the base oil used in the grease. This change in viscosity is called shear thinning. Grease is sometimes used to describe lubricating materials that are simply soft solids or high viscosity liquids, but these materials do not exhibit the shear-thinning properties characteristic of the classical grease. For example, petroleum jellies such as Vaseline are not generally classified as greases. Greases are applied to mechanisms that can be lubricated only infrequently and where a lubricating oil would not stay in position. They also act as sealants to prevent ingress of water and incompressible mat ...
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Perfluoropolyether
Perfluoropolyether (PFPE) is a type of liquid lubricant that has been used in the aerospace industry for over 30 years. The main properties of PFPE are being temperature resistant between and (depending on specific composites), having very low outgassing compared to other fluids (vapour pressure of ) and having a dielectric strength of around 15.7 MV/m. Perfluoropolyether consists of a polymer chain in which monomers consisting of perfluoro-alkyl groups are joined by ether linkages. The bonds between carbon and oxygen or fluorine are strong. The thermal and chemical stability of PFPE along with a vapor–liquid equilibrium of 230 °C when mixed with the right composites make it a suitable candidate for vapor phase soldering technologies. History It's been developed in early 1960s at request of USAF with a requirement to be non-reacting with liquid and gaseous oxygen (O2). Manufacture Perfluoropolyether can be synthesized from tetrafluoroethylene or hexafluoropro ...
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Chemours
Chemours (, ) is an American chemical company that was founded in July 2015 as a spin-off from DuPont. It has its corporate headquarters in Wilmington, Delaware, United States. History In October 2013, DuPont announced that it was planning to spin off its " performance chemicals" business into a new publicly traded company in mid-2015. DuPont filed its initial Form 10 with the SEC in December 2014 and announced that the new company would be called "The Chemours Company." The name is a portmanteau of the words chemical and Nemours, a nod to DuPont's full name, E. I. du Pont de Nemours & Co. The company's CC ticker symbol, is also a play on DuPont's DD symbol. The spin-off was completed on July 1, 2015, and Chemours' stock began trading on the New York Stock Exchange on the same date. Chemours has assumed various liabilities arising from lawsuits against DuPont. Additionally, Chemours' plant in Bladen County, North Carolina, was found to be dumping vast quantities of a chemic ...
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Fluorotelomer
Fluorotelomers are fluorocarbon-based oligomers, or telomers, synthesized by telomerization. Some fluorotelomers and fluorotelomer-based compounds are a source of environmentally persistent perfluorinated carboxylic acids such as PFOA and PFNA, while others are under extended investigation. Types There are many broad categories of fluorotelomers: * Fluorotelomer alcohols (FTOH) * Fluorotelomer ethoxylates (FTEO) * Fluorotelomer fumarates * Fluorotelomer methacrylates (FTMAC) * Fluorotelomer sulphonates (FTS) Manufacture In the radical telomerization of fluorotelomer molecules, a variety of fluorinated alkenes can serve as unsaturated taxogens including tetrafluoroethylene, vinylidene fluoride, chlorotrifluoroethylene, and hexafluoropropene. However, many fluorotelomers, such as fluorotelomer alcohols, are fluorocarbon-based because they are synthesized from tetrafluoroethylene. In addition to alcohols, synthetic products include fluorotelomer iodides, olefins, and acrylate ...
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Polymer Fume Fever
__NOTOC__ Polymer fume fever or fluoropolymer fever, also informally called Teflon flu, is an inhalation fever caused by the fumes released when polytetrafluoroethylene (PTFE, known under the trade name Teflon) reaches temperatures of 300 °C (572 °F) to 450 °C (842 °F). Fever When PTFE is heated above 450 °C the pyrolysis products are different and inhalation may cause acute lung injury. Symptoms are flu-like (chills, headaches and fevers) with chest tightness and mild cough. Onset occurs about 4 to 8 hours after exposure to the pyrolysis products of PTFE. A high white blood cell count may be seen and chest x-ray findings are usually minimal. The polymer fumes are especially harmful to certain animals whose breathing, optimized for rapidity, allows toxins which are excluded by human lungs. Fumes from Teflon in very high heat are fatal to parrots, as well as some other birds (PTFE toxicosis). See also * Cooking oil#Cooking with oil * Metal fume ...
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Solvay S
Solvay may refer to: Companies and organizations * Solvay Brussels School of Economics and Management, Brussels, Belgium * Solvay Conference, founded by Ernest Solvay, deals with open questions in physics and chemistry * Solvay Indupa, an Argentine petrochemical company formerly owned by Solvay * Solvay Institute of Sociology, Brussels, Belgium, part of the Université Libre de Bruxelles * Solvay Process Company (1880–1985), a former U.S. company that employed the Solvay process * Solvay Public Library, on the National Register of Historic Places * Solvay S.A., an international chemicals and plastics company founded by Ernest Solvay Places * Solvay Castle, La Hulpe, Belgium * Solvay Hut, on the Matterhorn * Hôtel Solvay, a town house in Brussels, Belgium * Solvay, New York, a village * Solvay Mountains, Brabant Island, off the coast of Antarctica People * Ernest Solvay (1838–1922), Belgian chemist, inventor of the Solvay process * Lucien Solvay (1851–1950), Belgian journ ...
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Ionizing Radiation
Ionizing radiation (or ionising radiation), including nuclear radiation, consists of subatomic particles or electromagnetic waves that have sufficient energy to ionize atoms or molecules by detaching electrons from them. Some particles can travel up to 99% of the speed of light, and the electromagnetic waves are on the high-energy portion of the electromagnetic spectrum. Gamma rays, X-rays, and the higher energy ultraviolet part of the electromagnetic spectrum are ionizing radiation, whereas the lower energy ultraviolet, visible light, nearly all types of laser light, infrared, microwaves, and radio waves are non-ionizing radiation. The boundary between ionizing and non-ionizing radiation in the ultraviolet area is not sharply defined, as different molecules and atoms ionize at different energies. The energy of ionizing radiation starts between 10 electronvolts (eV) and 33 eV. Typical ionizing subatomic particles include alpha particles, beta particles, and neutrons. ...
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Solvent
A solvent (s) (from the Latin '' solvō'', "loosen, untie, solve") is a substance that dissolves a solute, resulting in a solution. A solvent is usually a liquid but can also be a solid, a gas, or a supercritical fluid. Water is a solvent for polar molecules and the most common solvent used by living things; all the ions and proteins in a cell are dissolved in water within the cell. The quantity of solute that can dissolve in a specific volume of solvent varies with temperature. Major uses of solvents are in paints, paint removers, inks, and dry cleaning. Specific uses for organic solvents are in dry cleaning (e.g. tetrachloroethylene); as paint thinners ( toluene, turpentine); as nail polish removers and solvents of glue (acetone, methyl acetate, ethyl acetate); in spot removers ( hexane, petrol ether); in detergents ( citrus terpenes); and in perfumes (ethanol). Solvents find various applications in chemical, pharmaceutical, oil, and gas industries, including in chemic ...
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Liquid Oxygen
Liquid oxygen—abbreviated LOx, LOX or Lox in the aerospace, submarine and gas industries—is the liquid form of molecular oxygen. It was used as the oxidizer in the first liquid-fueled rocket invented in 1926 by Robert H. Goddard, an application which has continued to the present. Physical properties Liquid oxygen has a pale blue color and is strongly paramagnetic: it can be suspended between the poles of a powerful horseshoe magnet. Liquid oxygen has a density of , slightly denser than liquid water, and is cryogenic with a freezing point of and a boiling point of at . Liquid oxygen has an expansion ratio of 1:861 under and , and because of this, it is used in some commercial and military aircraft as a transportable source of breathing oxygen. Because of its cryogenic nature, liquid oxygen can cause the materials it touches to become extremely brittle. Liquid oxygen is also a very powerful oxidizing agent: organic materials will burn rapidly and energetically in l ...
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PTFE
Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene that has numerous applications. It is one of the best-known and widely applied PFAS. The commonly known brand name of PTFE-based composition is Teflon by Chemours, a spin-off from DuPont, which originally discovered the compound in 1938. Polytetrafluoroethylene is a fluorocarbon solid, as it is a high- molecular-weight polymer consisting wholly of carbon and fluorine. PTFE is hydrophobic: neither water nor water-containing substances wet PTFE, as fluorocarbons exhibit only small London dispersion forces due to the low electric polarizability of fluorine. PTFE has one of the lowest coefficients of friction of any solid. Polytetrafluoroethylene is used as a non-stick coating for pans and other cookware. It is non-reactive, partly because of the strength of carbon–fluorine bonds, so it is often used in containers and pipework for reactive and corrosive chemicals. Where used as a lubrican ...
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Laboratory Grease 1
A laboratory (; ; colloquially lab) is a facility that provides controlled conditions in which scientific or technological research, experiments, and measurement may be performed. Laboratory services are provided in a variety of settings: physicians' offices, clinics, hospitals, and regional and national referral centers. Overview The organisation and contents of laboratories are determined by the differing requirements of the specialists working within. A physics laboratory might contain a particle accelerator or vacuum chamber, while a metallurgy laboratory could have apparatus for casting or refining metals or for testing their strength. A chemist or biologist might use a wet laboratory, while a psychologist's laboratory might be a room with one-way mirrors and hidden cameras in which to observe behavior. In some laboratories, such as those commonly used by computer scientists, computers (sometimes supercomputers) are used for either simulations or the analysis of data. S ...
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