Karl Andreas Hofmann
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Karl Andreas Hofmann
Karl Andreas Hofmann (2 April 1870 – 15 October 1940) was a German inorganic chemist. He is best known for his discovery of a family of clathrates which consist of a 2-D metal cyanide sheet, with every second metal also bound axially to two other ligands. These materials have been named ' Hofmann clathrates' in his honour. Works * ''Lehrbuch der Anorganischen Chemie'' . Vieweg, Braunschweig 2nd ed. 191Digital editionby the University and State Library Düsseldorf The University and State Library Düsseldorf (german: Universitäts- und Landesbibliothek Düsseldorf, abbreviated ULB Düsseldorf) is a central service institution of Heinrich Heine University. Along with Bonn and Münster, it is also one of th ... References 1870 births 1940 deaths 19th-century German chemists Inorganic chemists 20th-century German chemists Ludwig Maximilian University of Munich alumni University of Tübingen faculty Technical University of Berlin faculty Solid state chemists ...
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Ansbach
Ansbach (; ; East Franconian: ''Anschba'') is a city in the German state of Bavaria. It is the capital of the administrative region of Middle Franconia. Ansbach is southwest of Nuremberg and north of Munich, on the river Fränkische Rezat, a tributary of the river Main. In 2020, its population was 41,681. Developed in the 8th century as a Benedictine monastery, it became the seat of the Hohenzollern family in 1331. In 1460, the Margraves of Brandenburg-Ansbach lived here. The city has a castle known as Margrafen–Schloss, built between 1704 and 1738. It was not badly damaged during the World Wars and hence retains its original historical baroque sheen. Ansbach is now home to a US military base and to the Ansbach University of Applied Sciences. The city has connections via autobahn A6 and highways B13 and B14. Ansbach station is on the Nürnberg–Crailsheim and Treuchtlingen–Würzburg railways and is the terminus of line S4 of the Nuremberg S-Bahn. Name origin Ans ...
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University And State Library Düsseldorf
The University and State Library Düsseldorf (german: Universitäts- und Landesbibliothek Düsseldorf, abbreviated ULB Düsseldorf) is a central service institution of Heinrich Heine University. Along with Bonn and Münster, it is also one of the three State Libraries of North Rhine-Westphalia. Tradition and Modernity From 1965 to 1969, the University and Library Düsseldorf gradually developed out of the Medical Academy in Düsseldorf. There is no real founding year of the ULB, but the foundation stone for an integrated library system was laid when the former State and City Library of Düsseldorf was taken over by the university in 1970 and merged with the Central Library of the former Medical Academy. Structure and Holdings The ULB consists of one central library and four decentralized locations. Management and media processing are organized centrally. Catalogues, databases, e-books and e-journals are accessible throughout the whole university as well as at home via the lib ...
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University Of Tübingen Faculty
A university () is an institution of higher (or tertiary) education and research which awards academic degrees in several academic disciplines. Universities typically offer both undergraduate and postgraduate programs. In the United States, the designation is reserved for colleges that have a graduate school. The word ''university'' is derived from the Latin ''universitas magistrorum et scholarium'', which roughly means "community of teachers and scholars". The first universities were created in Europe by Catholic Church monks. The University of Bologna (''Università di Bologna''), founded in 1088, is the first university in the sense of: *Being a high degree-awarding institute. *Having independence from the ecclesiastic schools, although conducted by both clergy and non-clergy. *Using the word ''universitas'' (which was coined at its foundation). *Issuing secular and non-secular degrees: grammar, rhetoric, logic, theology, canon law, notarial law.Hunt Janin: "The university ...
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Ludwig Maximilian University Of Munich Alumni
Ludwig may refer to: People and fictional characters * Ludwig (given name), including a list of people and fictional characters * Ludwig (surname), including a list of people * Ludwig Ahgren, or simply Ludwig, American YouTube live streamer and content creator Arts and entertainment * ''Ludwig'' (cartoon), a 1977 animated children's series * ''Ludwig'' (film), a 1973 film by Luchino Visconti about Ludwig II of Bavaria * '' Ludwig: Requiem for a Virgin King'', a 1972 film by Hans-Jürgen Syberberg about Ludwig II of Bavaria * "Ludwig", a 1967 song by Al Hirt Other uses * Ludwig (crater), a small lunar impact crater just beyond the eastern limb of the Moon * Ludwig, Missouri, an unincorporated community in the United States * Ludwig Canal, an abandoned canal in southern Germany * Ludwig Drums, an American manufacturer of musical instruments * ''Ludwig'' (ship), a steamer that sank in 1861 after a collision with the '' Stadt Zürich'' See also * Ludewig * Ludvig * Ludwik ...
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Inorganic Chemists
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep mantle remain active areas of investigation. Some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, etc.), carbon monoxide, carbon dioxide, carbides, and the following salts of inorganic anions: carbonates, cyanides, cyanates, and thiocyanates. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it does not occur within living things. History Friedrich Wöhler's conversion of ammonium cyanate into urea in 1828 is often cited as the starting point of modern ...
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19th-century German Chemists
The 19th (nineteenth) century began on 1 January 1801 ( MDCCCI), and ended on 31 December 1900 ( MCM). The 19th century was the ninth century of the 2nd millennium. The 19th century was characterized by vast social upheaval. Slavery was abolished in much of Europe and the Americas. The First Industrial Revolution, though it began in the late 18th century, expanding beyond its British homeland for the first time during this century, particularly remaking the economies and societies of the Low Countries, the Rhineland, Northern Italy, and the Northeastern United States. A few decades later, the Second Industrial Revolution led to ever more massive urbanization and much higher levels of productivity, profit, and prosperity, a pattern that continued into the 20th century. The Gunpowder empires, Islamic gunpowder empires fell into decline and European imperialism brought much of South Asia, Southeast Asia, and almost all of Africa under Colonialism, colonial rule. It was also marked ...
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1940 Deaths
Year 194 ( CXCIV) was a common year starting on Tuesday (link will display the full calendar) of the Julian calendar. At the time, it was known as the Year of the Consulship of Septimius and Septimius (or, less frequently, year 947 ''Ab urbe condita''). The denomination 194 for this year has been used since the early medieval period, when the Anno Domini calendar era became the prevalent method in Europe for naming years. Events By place Roman Empire * Emperor Septimius Severus and Decimus Clodius Septimius Albinus Caesar become Roman Consuls. * Battle of Issus: Septimius Severus marches with his army (12 legions) to Cilicia, and defeats Pescennius Niger, Roman governor of Syria. Pescennius retreats to Antioch, and is executed by Severus' troops. * Septimius Severus besieges Byzantium (194–196); the city walls suffer extensive damage. Asia * Battle of Yan Province: Warlords Cao Cao and Lü Bu fight for control over Yan Province; the battle lasts for over 100 ...
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1870 Births
Year 187 ( CLXXXVII) was a common year starting on Sunday (link will display the full calendar) of the Julian calendar. At the time, it was known as the Year of the Consulship of Quintius and Aelianus (or, less frequently, year 940 '' Ab urbe condita''). The denomination 187 for this year has been used since the early medieval period, when the Anno Domini calendar era became the prevalent method in Europe for naming years. Events By place Roman Empire * Septimius Severus marries Julia Domna (age 17), a Syrian princess, at Lugdunum (modern-day Lyon). She is the youngest daughter of high-priest Julius Bassianus – a descendant of the Royal House of Emesa. Her elder sister is Julia Maesa. * Clodius Albinus defeats the Chatti, a highly organized German tribe that controlled the area that includes the Black Forest. By topic Religion * Olympianus succeeds Pertinax as bishop of Byzantium (until 198). Births * Cao Pi, Chinese emperor of the Cao Wei state (d. 226) * ...
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Hofmann Clathrates
In inorganic chemistry, Hofmann clathrates refers to materials with the formula Ni(CN)2(NH3)(C6H6). These materials are a type of coordination polymer. They have attracted attention because they can be used to separate xylenes. On a conceptual level, Hofmann clathrates can be viewed as forerunners to metal-organic frameworks (MOFs). Structures The empirical formula Ni(CN)2(NH3)(C6H6) reflects the presence of two types of nickel(II) centers, one of which is the square-planar tetracyanonickelate, i(CN)4sup>2-. The second kind of nickel site consists of i(NH3)2sup>2+ groups that are connected to the Ni-CN nitrogens. Thus cyanide serves as a bridging ligand. The linking of the i(CN)4sup>2- and ''trans''- i(NH3)2sup>2+ subunits results in a sheet-like polymer. Voids between these sheets, defined by the ammonia ligands, are occupied by benzene molecules. Variations Many variations of Hofmann clathrates have been reported. The ammonia ligands can be replaced by diamines. Tetra ...
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Germany
Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated between the Baltic and North seas to the north, and the Alps to the south; it covers an area of , with a population of almost 84 million within its 16 constituent states. Germany borders Denmark to the north, Poland and the Czech Republic to the east, Austria and Switzerland to the south, and France, Luxembourg, Belgium, and the Netherlands to the west. The nation's capital and most populous city is Berlin and its financial centre is Frankfurt; the largest urban area is the Ruhr. Various Germanic tribes have inhabited the northern parts of modern Germany since classical antiquity. A region named Germania was documented before AD 100. In 962, the Kingdom of Germany formed the bulk of the Holy Roman Empire. During the 16th ce ...
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Metal Cyanide
Cyanometallates or cyanometalates are a class of coordination compounds, most often consisting only of cyanide ligands. Most are anions. Cyanide is a highly basic and small ligand, hence it readily saturates the coordination sphere of metal ions. The resulting cyanometallate anions are often used as building blocks for more complex structures called coordination polymers, the best known example of which is Prussian blue, a common dyestuff.*Dunbar, K. R. and Heintz, R. A., "Chemistry of Transition Metal Cyanide Compounds: Modern Perspectives", Progress in Inorganic Chemistry, 1997, 45, 283-391. Examples Homoleptic cyanometallates ''Homoleptic'' cyanometallates are complexes where the only ligand is cyanide. For transition metals, well known homoleptic cyanometallates are the hexacyanides. Hexacyanometalates are known for Ti(III), V(III), Cr(III), Cr(II), Mn(IV), Mn(III), Mn(II), Fe(II), Fe(III), Co(III), Ru(III), Ru(II), Os(III), and Os(II). Other more labile derivatives are a ...
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