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Iridoid Glycosides
Iridoids are a type of monoterpenoids in the general form of cyclopentanopyran, found in a wide variety of plants and some animals. They are biosynthetically derived from 8-oxogeranial. Iridoids are typically found in plants as glycosides, most often bound to glucose. The chemical structure is exemplified by iridomyrmecin, a defensive chemical produced by the ant genus ''Iridomyrmex'', for which iridoids are named. Structurally, they are bicyclic ''cis''-fused cyclopentane-pyrans. Cleavage of a bond in the cyclopentane ring gives rise to a subclass known as ''secoiridoids'', such as oleuropein and amarogentin. Occurrence The iridoids produced by plants act primarily as a defense against herbivores or against infection by microorganisms. The variable checkerspot butterfly also contains iridoids obtained through its diet which act as a defense against avian predators. To humans and other mammals, iridoids are often characterized by a deterrent bitter taste. Aucubin and catal ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iridomyrmecin
Iridomyrmecin is a defensive chemical, classified as an iridoid, isolated from ants of the genus ''Iridomyrmex''. It has also evolved into a sex pheromone in wasps such as ''Leptopilina'', with host species using the smell of iridomyrmecin as a way of detecting the presence of the parasitoid wasps. Iridomyrmecin is also found in a variety of plants including ''Actinidia polygama ''Actinidia polygama'' (also known as , silver vine, , and cat powder) is a species of kiwifruit in the Actinidiaceae family. It grows in the mountainous areas of Korea, Japan and China at elevations between . Silver vine can reach up to high ...''. See also * Cat pheromone#Cat attractants for other chemicals that have behavioural effects on cats References Iridoids Lactones Cyclopentanes {{organic-compound-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rubiaceae
The Rubiaceae are a family of flowering plants, commonly known as the coffee, madder, or bedstraw family. It consists of terrestrial trees, shrubs, lianas, or herbs that are recognizable by simple, opposite leaves with interpetiolar stipules and sympetalous actinomorphic flowers. The family contains about 13,500 species in about 620 genera, which makes it the fourth-largest angiosperm family. Rubiaceae has a cosmopolitan distribution; however, the largest species diversity is concentrated in the tropics and subtropics. Economically important genera include ''Coffea'', the source of coffee, '' Cinchona'', the source of the antimalarial alkaloid quinine, ornamental cultivars (''e.g.'', '' Gardenia'', ''Ixora'', ''Pentas''), and historically some dye plants (''e.g.'', ''Rubia''). Description The Rubiaceae are morphologically easily recognizable as a coherent group by a combination of characters: opposite or whorled leaves that are simple and entire, interpetiolar stipules, tubu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reduction (chemistry)
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate (chemistry), substrate change. Oxidation is the loss of Electron, electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state. There are two classes of redox reactions: * ''Electron-transfer'' – Only one (usually) electron flows from the reducing agent to the oxidant. This type of redox reaction is often discussed in terms of redox couples and electrode potentials. * ''Atom transfer'' – An atom transfers from one substrate to another. For example, in the rusting of iron, the oxidation state of iron atoms increases as the iron converts to an oxide, and simultaneously the oxidation state of oxygen decreases as it accepts electrons released by the iron. Although oxidation reactions are commonly associated with the formation of oxides, other chemical species can serve the same function. In hydrogen ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
NADPH
Nicotinamide adenine dinucleotide phosphate, abbreviated NADP or, in older notation, TPN (triphosphopyridine nucleotide), is a cofactor used in anabolic reactions, such as the Calvin cycle and lipid and nucleic acid syntheses, which require NADPH as a reducing agent ('hydrogen source'). It is used by all forms of cellular life. NADPH is the reduced form of NADP. NADP differs from NAD by the presence of an additional phosphate group on the 2' position of the ribose ring that carries the adenine moiety. This extra phosphate is added by NAD+ kinase and removed by NADP+ phosphatase. Biosynthesis NADP In general, NADP+ is synthesized before NADPH is. Such a reaction usually starts with NAD+ from either the de-novo or the salvage pathway, with NAD+ kinase adding the extra phosphate group. ADP-ribosyl cyclase allows for synthesis from nicotinamide in the salvage pathway, and NADP+ phosphatase can convert NADPH back to NADH to maintain a balance. Some forms of the NAD+ kinas ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Monoterpene Cyclase
Monoterpenes are a class of terpenes that consist of two isoprene units and have the molecular formula C10H16. Monoterpenes may be linear (acyclic) or contain rings (monocyclic and bicyclic). Modified terpenes, such as those containing oxygen functionality or missing a methyl group, are called monoterpenoids. Monoterpenes and monoterpenoids are diverse. They have relevance to the pharmaceutical, cosmetic, agricultural, and food industries. Biosynthesis Monoterpenes are derived biosynthetically from units of isopentenyl pyrophosphate, which is formed from acetyl-CoA via the intermediacy of mevalonic acid in the HMG-CoA reductase pathway. An alternative, unrelated biosynthesis pathway of IPP is known in some bacterial groups and the plastids of plants, the so-called MEP-(2-methyl-D-erythritol-4-phosphate) pathway, which is initiated from C5 sugars. In both pathways, IPP is isomerized to DMAPP by the enzyme isopentenyl pyrophosphate isomerase. Geranyl pyrophosphate is the precurso ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iridoid Synthase
Iridoids are a type of monoterpenoids in the general form of cyclopentanopyran, found in a wide variety of plants and some animals. They are biosynthesis, biosynthetically derived from 8-oxogeranial. Iridoids are typically found in plants as glycosides, most often bound to glucose. The chemical structure is exemplified by iridomyrmecin, a defensive chemical produced by the ant genus ''Iridomyrmex'', for which iridoids are named. Structurally, they are bicyclic ''cis''-fused cyclopentane-pyrans. Cleavage of a bond in the cyclopentane ring gives rise to a subclass known as ''secoiridoids'', such as oleuropein and amarogentin. Occurrence The iridoids produced by plants act primarily as a defense against herbivores or against infection by microorganisms. The variable checkerspot butterfly also contains iridoids obtained through its diet which act as a defense against avian predators. To humans and other mammals, iridoids are often characterized by a deterrent bitter taste. Aucub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Menyanthaceae
Menyanthaceae is a family of aquatic and wetland plants in the order Asterales. There are approximately 60-70 species in six genera distributed worldwide. The simple or compound leaves arise alternately from a creeping rhizome. In the submersed aquatic genus ''Nymphoides'', leaves are floating and support a lax, umbellate or racemose inflorescence. In other genera the inflorescence is erect and consists of one (e.g., '' Liparophyllum'') to many flowers. The sympetalous, insect-pollinated flowers are five-parted and either yellow or white. The petals are ciliate or adorned with lateral wings. Fruit type is a capsule. Species of Menyanthaceae are found worldwide. The genera ''Menyanthes'' and ''Nephrophyllidium'' grow only in the northern hemisphere, while '' Liparophyllum'' and '' Villarsia'' occur only in the southern hemisphere. ''Nymphoides'' species have a cosmopolitan distribution. Menyanthaceae species are of economic importance as ornamental water garden plants, with ' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Valerianaceae
The Valerianaceae Batsch, the valerian family, was a family of flowering plants that is now considered part of the Caprifoliaceae. Plants are generally herbaceous, and their foliage often has a strong, disagreeable odor. They are found native in most regions of the world except for Australia. Some species are cultivated as ornamentals or used in herbal medicine for inducing relaxation and sleep. The genera that were placed in this family, along with some species, include: * ''Centranthus'' : ''C. ruber'' (red valerian, spur valerian or red spur valerian) * ''Fedia'' : ''F. cornucopiae'' (African valerian, horn of plenty) * ''Nardostachys'' : '' N. jatamansi'' (Spikenard) : '' N. chinensis'' * ''Patrinia'' * ''Plectritis'' * ''Valeriana'' : ''V. dioica'' (marsh valerian) : ''V. officinalis'' (garden valerian) * '' Valerianella'' : ''V. locusta'' (corn salad ''Valerianella locusta'', called mâche or mache; common cornsalad; or lamb's lettuce, is a small, herbaceous plan ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Scrophulariaceae
The Scrophulariaceae are a family of flowering plants, commonly known as the figwort family. The plants are annual and perennial herbs, as well as shrubs. Flowers have bilateral (zygomorphic) or rarely radial (actinomorphic) symmetry. The Scrophulariaceae have a cosmopolitan distribution, with the majority found in temperate areas, including tropical mountains. The family name is based on the name of the included genus ''Scrophularia'' L. Taxonomy In the past, it was treated as including about 275 genera and over 5,000 species, but its circumscription has been radically altered since numerous molecular phylogenies have shown the traditional broad circumscription to be grossly polyphyletic. Many genera have recently been transferred to other families within the Lamiales, notably Plantaginaceae and Orobanchaceae, but also several new families. - on linhere/ref> Several families of the Lamiales have had their circumscriptions enlarged to accommodate genera transferred from t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Plantaginaceae
Plantaginaceae, the plantain family, is a large, diverse family of flowering plants in the order Lamiales that includes common flowers such as snapdragon and foxglove. It is unrelated to the banana-like fruit also called "plantain." In older classifications, Plantaginaceae was the only family of the order Plantaginales, but numerous phylogenetic studies, summarized by the Angiosperm Phylogeny Group, have demonstrated that this taxon should be included within Lamiales. Overview The plantain family as traditionally circumscribed consisted of only three genera: ''Bougueria'', ''Littorella'', and ''Plantago''. However phylogenetic research has indicated that Plantaginaceae ''sensu stricto'' (in the strict sense) were nested within Scrophulariaceae (but forming a group that did not include the type genus of that family, ''Scrophularia''). Although Veronicaceae (1782) is the oldest family name for this group, Plantaginaceae (1789) is a conserved name under the International Code of B ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
