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Ionic Conductivity (solid State)
Ionic conductivity (denoted by ) is a measure of a substance's tendency towards ionic conduction. Ionic conduction is the movement of ions. The phenomenon is observed in solids and solutions. Ionic conduction is one mechanism of current (electricity), current. In crystalline solids In most solids, ions rigidly occupy fixed positions, strongly embraced by neighboring atoms or ions. In some solids, selected ions are highly mobile allowing ionic conduction. The mobility increases with temperature. Materials exhibiting this property are used in batteries. A well-known ion conductive solid is Beta-alumina solid electrolyte, β''-alumina ("BASE"), a form of aluminium oxide that has channels through which sodium cations can hop. When this ceramic is complexed with a mobile ion, such as Sodium, Na+, it behaves as so-called fast ion conductor. BASE is used as a semipermeable membrane, membrane in several types of molten salt electrochemical cell. In glasses Ion conduction in disorder ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Superionic Ice Conducting
Superionic water, also called superionic ice or ice XVIII is a Phase (matter), phase of water that exists at extremely high temperatures and pressures. In superionic water, water molecules break apart and the oxygen ions crystallization, crystallize into an evenly spaced lattice while the hydrogen ions float around freely within the oxygen lattice.Weird water lurking inside giant planets New Scientist,01 September 2010, Magazine issue 2776. The freely mobile hydrogen ions make superionic water almost as electrical resistivity and conductivity, conductive as typical metals, making it a Fast ion conductor, superionic conductor. It is one of the 19 known crystalline Ice#Physical properties, phases of ice. Superionic wate ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lead(II) Fluoride
Lead(II) fluoride is the inorganic compound with the formula Pb F2. It is a white solid. It exists as both an orthorhombic and cubic forms. Uses Lead(II) fluoride is used in low melting glasses, in glass coatings to reflect infrared rays, in phosphors for television-tube screens, and as a catalyst for the manufacture of picoline. The Muon g−2 experiment uses scintillators in conjunction with silicon photomultipliers. Preparation Lead(II) fluoride can be prepared by treating lead(II) hydroxide or lead(II) carbonate with hydrofluoric acid: : Pb(OH)2 + 2 HF → PbF2 + 2 H2O Alternatively, it is precipitated by adding hydrofluoric acid to a lead(II) salt solution, or by adding potassium fluoride to a lead(II) nitrate Lead(II) nitrate is an inorganic compound with the chemical formula Pb( NO3)2. It commonly occurs as a colourless crystal or white powder and, unlike most other lead(II) salts, is soluble in water. Known since the Middle Ages by the name plumbum ... soluti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
NASICON
NASICON is an acronym for sodium (Na) Super Ionic CONductor, which usually refers to a family of solids with the chemical formula Na1+xZr2SixP3−xO12, 0 < x < 3. In a broader sense, it is also used for similar compounds where Na, Zr and/or Si are replaced by isovalent elements. NASICON compounds have high ionic conductivities, on the order of 10−3 S/cm, which rival those of liquid s. They are caused by hopping of Na ions among interstitial sites of the NASICON crystal lattice. Properties The crystal structure of NASICON compounds was characterized in 1968. It is a covalent network consisting of ZrO6 and PO4/SiO4 |
Fast Ion Conductor
In materials science, fast ion conductors are solid conductors with highly mobile ions. These materials are important in the area of solid state ionics, and are also known as solid electrolytes and superionic conductors. These materials are useful in batteries and various sensors. Fast ion conductors are used primarily in solid oxide fuel cells. As solid electrolytes they allow the movement of ions without the need for a liquid or soft membrane separating the electrodes. The phenomenon relies on the hopping of ions through an otherwise rigid crystal structure. Mechanism Fast ion conductors are intermediate in nature between crystalline solids which possess a regular structure with immobile ions, and liquid electrolytes which have no regular structure and fully mobile ions. Solid electrolytes find use in all solid-state supercapacitors, batteries, and fuel cells, and in various kinds of chemical sensors. Classification In solid electrolytes (glasses or crystals), the ionic condu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lattice Energy
In chemistry, the lattice energy is the energy change upon formation of one mole of a crystalline ionic compound from its constituent ions, which are assumed to initially be in the gaseous state. It is a measure of the cohesive forces that bind ionic solids. The size of the lattice energy is connected to many other physical properties including solubility, hardness, and volatility. Since it generally cannot be measured directly, the lattice energy is usually deduced from experimental data via the Born–Haber cycle. Lattice energy and lattice enthalpy The concept of lattice energy was originally applied to the formation of compounds with structures like rocksalt (NaCl) and sphalerite (ZnS), where the ions occupy high-symmetry crystal lattice sites. In the case of NaCl, lattice energy is the energy change of the reaction : Na+ (g) + Cl− (g) → NaCl (s) which amounts to −786 kJ/mol. Some chemistry textbooks as well as the widely used CRC Handbook of Chemistry and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium–sulfur Battery
A sodium–sulfur battery is a type of molten-salt battery constructed from liquid sodium (Na) and sulfur (S). This type of battery has a high energy density (its energy density is 5 times that of a lead-acid battery), high efficiency of charge/discharge and is fabricated from inexpensive and non-toxic materials. The operating temperatures of 300 to 350 °C and the highly corrosive nature of the sodium polysulfides, primarily make them suitable for stationary energy storage applications. The cell becomes more economical with increasing size. Commercially available cells are typically large with high capacities (up to 500Ah). This is because of the Square-cube law: large cells have less relative heat loss, so maintaining their high operating temperatures is easier. These batteries, although having a reasonably long long cycle life (>1000 on average) are prone to disastrous failures due to a reaction between molten sodium and molten sulfur , and primarily for this reasons ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electric Vehicle
An electric vehicle (EV) is a vehicle that uses one or more electric motors for propulsion. It can be powered by a collector system, with electricity from extravehicular sources, or it can be powered autonomously by a battery (sometimes charged by solar panels, or by converting fuel to electricity using fuel cells or a generator). EVs include, but are not limited to, road and rail vehicles, surface and underwater vessels, electric aircraft and electric spacecraft. For road vehicles, together with other emerging automotive technologies such as autonomous driving, connected vehicles and shared mobility, EVs form a future mobility vision called Connected, Autonomous, Shared and Electric (CASE) Mobility. EVs first came into existence in the late 19th century, when electricity was among the preferred methods for motor vehicle propulsion, providing a level of comfort and ease of operation that could not be achieved by the gasoline cars of the time. Internal combustion en ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ford Motor Company
Ford Motor Company (commonly known as Ford) is an American multinational automobile manufacturer headquartered in Dearborn, Michigan, United States. It was founded by Henry Ford and incorporated on June 16, 1903. The company sells automobiles and commercial vehicles under the Ford brand, and luxury cars under its Lincoln luxury brand. Ford also owns Brazilian SUV manufacturer Troller, an 8% stake in Aston Martin of the United Kingdom and a 32% stake in China's Jiangling Motors. It also has joint ventures in China ( Changan Ford), Taiwan ( Ford Lio Ho), Thailand (AutoAlliance Thailand), and Turkey (Ford Otosan). The company is listed on the New York Stock Exchange and is controlled by the Ford family; they have minority ownership but the majority of the voting power. Ford introduced methods for large-scale manufacturing of cars and large-scale management of an industrial workforce using elaborately engineered manufacturing sequences typified by moving assembly lines ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Superionic Conductor
In materials science, fast ion conductors are solid conductors with highly mobile ions. These materials are important in the area of solid state ionics, and are also known as solid electrolytes and superionic conductors. These materials are useful in batteries and various sensors. Fast ion conductors are used primarily in solid oxide fuel cells. As solid electrolytes they allow the movement of ions without the need for a liquid or soft membrane separating the electrodes. The phenomenon relies on the hopping of ions through an otherwise rigid crystal structure. Mechanism Fast ion conductors are intermediate in nature between crystalline solids which possess a regular structure with immobile ions, and liquid electrolytes which have no regular structure and fully mobile ions. Solid electrolytes find use in all solid-state supercapacitors, batteries, and fuel cells, and in various kinds of chemical sensors. Classification In solid electrolytes (glasses or crystals), the ionic cond ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Silver Iodide
Silver iodide is an inorganic compound with the formula Ag I. The compound is a bright yellow solid, but samples almost always contain impurities of metallic silver that give a gray coloration. The silver contamination arises because AgI is highly photosensitive. This property is exploited in silver-based photography. Silver iodide is also used as an antiseptic and in cloud seeding. Structure The structure adopted by silver iodide is temperature dependent: *Below 420 K, the β phase of AgI, with the wurtzite structure, is most stable. This phase is encountered in nature as the mineral iodargyrite. *Above 420 K, the α phase becomes more stable. This motif is a body-centered cubic structure which has the silver centers distributed randomly between 6 octahedral, 12 tetrahedral and 24 trigonal sites. At this temperature, Ag+ ions can move rapidly through the solid, allowing fast ion conduction. The transition between the β and α forms represents the melting ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Silver Sulfide
Silver sulfide is an inorganic compound with the formula . A dense black solid, it is the only sulfide of silver. It is useful as a photosensitizer in photography. It constitutes the tarnish that forms over time on silverware and other silver objects. Silver sulfide is insoluble in most solvents, but is degraded by strong acids. Silver sulfide is a network solid made up of silver (electronegativity of 1.98) and sulfur (electronegativity of 2.58) where the bonds have low ionic character (approximately 10%). Formation Silver sulfide naturally occurs as the tarnish on silverware. When combined with silver, hydrogen sulfide gas creates a layer of black silver sulfide patina on the silver, protecting the inner silver from further conversion to silver sulfide. Silver whiskers can form when silver sulfide forms on the surface of silver electrical contacts operating in an atmosphere rich in hydrogen sulfide and high humidity. Such atmospheres can exist in sewage treatment and paper ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrolysis
In chemistry and manufacturing, electrolysis is a technique that uses direct electric current (DC) to drive an otherwise non-spontaneous chemical reaction. Electrolysis is commercially important as a stage in the separation of elements from naturally occurring sources such as ores using an electrolytic cell. The voltage that is needed for electrolysis to occur is called the decomposition potential. The word "lysis" means to separate or break, so in terms, electrolysis would mean "breakdown via electricity". Etymology The word "electrolysis" was introduced by Michael Faraday in 1834, using the Greek words "amber", which since the 17th century was associated with electrical phenomena, and ' meaning "dissolution". Nevertheless, electrolysis, as a tool to study chemical reactions and obtain pure elements, precedes the coinage of the term and formal description by Faraday. History In the early nineteenth century, William Nicholson and Anthony Carlisle sought to further ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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