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Indium Mediated Allylation
Organoindium chemistry is the chemistry of compounds containing In-C bonds. The main application of organoindium chemistry is in the preparation of semiconducting components for microelectronic applications. The area is also of some interest in organic synthesis. Most organoindium compounds feature the In(III) oxidation state, akin to its lighter congeners Ga(III) and B(III). 166px, Trimethylindium Organoindium(I) Monovalent In is relatively more common than Ga(I) or B(I). One example is cyclopentadienylindium(I). Organoindium(III) Trimethylindium is a colorless, volatile solid. It is the preferred source of indium for metalorganic vapour phase epitaxy (MOVPE) of indium-containing compound semiconductors, such as InP, InAs, AlInGaNP, etc. InMe3 is pyrophoric. To obtain the trialkyl derivatives, alkylation of indium trihalides with organolithium reagents is typical. OrganoIn(III) compounds are also prepared by treating In metal with alkyl halides. This reaction gives ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organic Synthesis
Organic synthesis is a special branch of chemical synthesis and is concerned with the intentional construction of organic compounds. Organic molecules are often more complex than inorganic compounds, and their synthesis has developed into one of the most important branches of organic chemistry. There are several main areas of research within the general area of organic synthesis: ''total synthesis'', ''semisynthesis'', and ''methodology''. Total synthesis A total synthesis is the complete chemical synthesis of complex organic molecules from simple, commercially available petrochemical or natural precursors. Total synthesis may be accomplished either via a linear or convergent approach. In a ''linear'' synthesis—often adequate for simple structures—several steps are performed one after another until the molecule is complete; the chemical compounds made in each step are called synthetic intermediates. Most often, each step in a synthesis refers to a separate rea ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Green Chemistry
Green chemistry, also called sustainable chemistry, is an area of chemistry and chemical engineering focused on the design of products and processes that minimize or eliminate the use and generation of hazardous substances. While environmental chemistry focuses on the effects of polluting chemicals on nature, green chemistry focuses on the environmental impact of chemistry, including lowering consumption of nonrenewable resources and technological approaches for preventing pollution. The overarching goals of green chemistry—namely, more resource-efficient and inherently safer design of molecules, materials, products, and processes—can be pursued in a wide range of contexts. History Green chemistry emerged from a variety of existing ideas and research efforts (such as atom economy and catalysis) in the period leading up to the 1990s, in the context of increasing attention to problems of chemical pollution and resource depletion. The development of green chemistry in Europe a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Another Example Of Enantioselective IMA
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Another or variant may refer to: * anOther or Another Magazine, culture and fashion magazine * ''Another'' (novel), a Japanese horror novel ** ''Another'' (film), a Japanese 2012 live-action film based on the novel * Another River, a river in the U.S. state of Alaska * A. N. Other, a pseudonym See also * Yet another * Indefinite pronoun * English determiners * Other (other) * Others (other) Others or The Others may refer to: Fictional characters * Others (''A Song of Ice and Fire''), supernatural creatures in the fictional world of George R. R. Martin's fantasy series ''A Song of Ice and Fire'' * Others (''Lost''), mysterious inh ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Explanation Of Diastereoselectivity Of IMA
An explanation is a set of statements usually constructed to describe a set of facts which clarifies the causes, context, and consequences of those facts. It may establish rules or laws, and may clarify the existing rules or laws in relation to any objects or phenomena examined. Explanation, in philosophy, is a set of statements that makes intelligible the existence or occurrence of an object, event, or state of affairs. Among its most common forms are: * Causal explanation * Deductive-nomological explanation, which involves subsuming the explanandum under a generalization from which it may be derived in a deductive argument (e.g., “All gases expand when heated; this gas was heated; therefore, this gas expanded”) * Statistical explanation, which involves subsuming the explanandum under a generalization that gives it inductive support (e.g., “Most people who use tobacco contract cancer; this person used tobacco; therefore, this person contracted cancer”). Explanations of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Example Of Ima Showing Alpha Vs Gamma
Example may refer to: * '' exempli gratia'' (e.g.), usually read out in English as "for example" * .example, reserved as a domain name that may not be installed as a top-level domain of the Internet ** example.com, example.net, example.org, example.edu, second-level domain names reserved for use in documentation as examples * HMS ''Example'' (P165), an Archer-class patrol and training vessel of the Royal Navy Arts * ''The Example'', a 1634 play by James Shirley * ''The Example'' (comics), a 2009 graphic novel by Tom Taylor and Colin Wilson * Example (musician), the British dance musician Elliot John Gleave (born 1982) * ''Example'' (album), a 1995 album by American rock band For Squirrels See also * * Exemplar (other), a prototype or model which others can use to understand a topic better * Exemplum, medieval collections of short stories to be told in sermons * Eixample The Eixample (; ) is a district of Barcelona between the old city (Ciutat Vella) and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Steric Effects
Steric effects arise from the spatial arrangement of atoms. When atoms come close together there is a rise in the energy of the molecule. Steric effects are nonbonding interactions that influence the shape ( conformation) and reactivity of ions and molecules. Steric effects complement electronic effects, which dictate the shape and reactivity of molecules. Steric repulsive forces between overlapping electron clouds result in structured groupings of molecules stabilized by the way that opposites attract and like charges repel. Steric hindrance Steric hindrance is a consequence of steric effects. Steric hindrance is the slowing of chemical reactions due to steric bulk. It is usually manifested in ''intermolecular reactions'', whereas discussion of steric effects often focus on ''intramolecular interactions''. Steric hindrance is often exploited to control selectivity, such as slowing unwanted side-reactions. Steric hindrance between adjacent groups can also affect torsional ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Updated Chemoselective Propargylation Of Aldehyde
Update(s) or Updated may refer to: Music * Update (Anouk album), ''Update'' (Anouk album), 2004 * Update (Berlin Jazz Orchestra album), ''Update'' (Berlin Jazz Orchestra album), 2004 * Update (Jane Zhang album), ''Update'' (Jane Zhang album), 2007 * Update (Mal Waldron album), ''Update'' (Mal Waldron album), 1987 * Update (Yandel album), ''Update'' (Yandel album), 2017 * Updated (M. Pokora album), ''Updated'' (M. Pokora album), an English-language version of ''Mise à jour'', 2011 Other uses * Update (SQL), a statement for changing database records * ''Updates'', a List of programs broadcast by CNN Philippines, program broadcast by CNN Philippines See also * Patch (computing), also known as a software update {{disambiguation ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carbonyl
In organic chemistry, a carbonyl group is a functional group composed of a carbon atom double-bonded to an oxygen atom: C=O. It is common to several classes of organic compounds, as part of many larger functional groups. A compound containing a carbonyl group is often referred to as a carbonyl compound. The term carbonyl can also refer to carbon monoxide as a ligand in an inorganic or organometallic complex (a metal carbonyl, e.g. nickel carbonyl). The remainder of this article concerns itself with the organic chemistry definition of carbonyl, where carbon and oxygen share a double bond. Carbonyl compounds In organic chemistry, a carbonyl group characterizes the following types of compounds: Other organic carbonyls are urea and the carbamates, the derivatives of acyl chlorides chloroformates and phosgene, carbonate esters, thioesters, lactones, lactams, hydroxamates, and isocyanates. Examples of inorganic carbonyl compounds are carbon dioxide and carbonyl sulfide. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
A Wide Variety Of IMA Reactions
A, or a, is the first letter and the first vowel of the Latin alphabet, used in the modern English alphabet, the alphabets of other western European languages and others worldwide. Its name in English is ''a'' (pronounced ), plural ''aes''. It is similar in shape to the Ancient Greek letter alpha, from which it derives. The uppercase version consists of the two slanting sides of a triangle, crossed in the middle by a horizontal bar. The lowercase version can be written in two forms: the double-storey a and single-storey ɑ. The latter is commonly used in handwriting and fonts based on it, especially fonts intended to be read by children, and is also found in italic type. In English grammar, " a", and its variant " an", are indefinite articles. History The earliest certain ancestor of "A" is aleph (also written 'aleph), the first letter of the Phoenician alphabet, which consisted entirely of consonants (for that reason, it is also called an abjad to distinguish it fro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
