Ice XVI
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Ice XVI
Ice XVI is the least dense (0.81 g/cm) experimentally obtained crystalline form of ice. It is topologically equivalent to the empty structure of sII clathrate hydrates. It was first obtained in 2014 by removing gas molecules from a neon clathrate under vacuum at temperatures below 147 K. The resulting empty water frame, ice XVI, is thermodynamically unstable at the experimental conditions, yet it can be preserved at cryogenic temperatures. Above 145–147 K at positive pressures ice XVI transforms into the stacking-faulty ice Ic and further into ordinary ice Ih. Theoretical studies predict ice XVI to be thermodynamically stable at negative pressures (that is under tension Tension may refer to: Science * Psychological stress * Tension (physics), a force related to the stretching of an object (the opposite of compression) * Tension (geology), a stress which stretches rocks in two opposite directions * Voltage or el ...). References Water ice {{inorganic-compo ...
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Clathrate Hydrate
Clathrate hydrates, or gas hydrates, clathrates, hydrates, etc., are crystalline water-based solids physically resembling ice, in which small non-polar molecules (typically gases) or polar molecules with large hydrophobic moieties are trapped inside "cages" of hydrogen bonded, frozen water molecules. In other words, clathrate hydrates are clathrate compounds in which the host molecule is water and the guest molecule is typically a gas or liquid. Without the support of the trapped molecules, the lattice structure of hydrate clathrates would collapse into conventional ice crystal structure or liquid water. Most low molecular weight gases, including , , , , , , , , and , as well as some higher hydrocarbons and freons, will form hydrates at suitable temperatures and pressures. Clathrate hydrates are not officially chemical compounds, as the enclathrated guest molecules are never bonded to the lattice. The formation and decomposition of clathrate hydrates are first order phase t ...
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Clathrate Hydrates
Clathrate hydrates, or gas hydrates, clathrates, hydrates, etc., are crystalline water-based solids physically resembling ice, in which small non-polar molecules (typically gases) or polar molecules with large hydrophobic moieties are trapped inside "cages" of hydrogen bonded, frozen water molecules. In other words, clathrate hydrates are clathrate compounds in which the host molecule is water and the guest molecule is typically a gas or liquid. Without the support of the trapped molecules, the lattice structure of hydrate clathrates would collapse into conventional ice crystal structure or liquid water. Most low molecular weight gases, including , , , , , , , , and , as well as some higher hydrocarbons and freons, will form hydrates at suitable temperatures and pressures. Clathrate hydrates are not officially chemical compounds, as the enclathrated guest molecules are never bonded to the lattice. The formation and decomposition of clathrate hydrates are first order phase tra ...
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Neon Clathrate
Neon compounds are chemical compounds containing the chemical element, element neon (Ne) with other molecules or elements from the periodic table. Compounds of the noble gas neon were believed not to exist, but there are now known to be molecular ions containing neon, as well as temporary excited neon-containing molecules called excimers. Several neutral neon molecules have also been predicted to be stable, but are yet to be discovered in nature. Neon has been shown to crystallize with other substances and form clathrates or Van der Waals molecule, Van der Waals solids. Neon has a high first ionization potential of 21.564 eV, which is only exceeded by that of helium (24.587 eV), requiring too much energy to make stable ionic compounds. Neon's polarisability of 0.395 Å3 is the second lowest of any element (only helium's is more extreme). Low polarisability means there will be little tendency to link to other atoms. Neon has a Lewis basicity or proton affinity of 2.06  ...
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Ice Ic
Ice Ic (pronounced "ice one c" or "ice I see") is a metastable cubic crystalline variant of ice. Hans König was the first to identify and deduce the structure of ice Ic. The oxygen atoms in ice Ic are arranged in a diamond structure; it is extremely similar to ice Ih having nearly identical densities and the same lattice constant along the hexagonal puckered-planes. It forms at temperatures between upon cooling, and can exist up to upon warming, when it transforms into ice Ih. Apart from forming from supercooled water, ice Ic has also been reported to form from amorphous ice as well as from the high-pressure ices II, III and V. It can form in and is occasionally present in the upper atmosphere and is believed to be responsible for the observation of Scheiner's halo, a rare ring that occurs near 28 degrees from the Sun or the Moon. Ordinary water ice is known as ice Ih (in the Bridgman nomenclature). Different types of ice, from ice II to ice XIX, have been created in t ...
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Ice Ih
Photograph showing details of an ice cube under magnification. Ice Ih is the form of ice commonly seen on Earth. Phase space of ice Ih with respect to other ice phases. Ice Ih (hexagonal ice crystal) (pronounced: ice one h, also known as ice-phase-one) is the hexagonal crystal form of ordinary ice, or frozen water. Virtually all ice in the biosphere is ice Ih, with the exception only of a small amount of ice Ic that is occasionally present in the upper atmosphere. Ice Ih exhibits many peculiar properties that are relevant to the existence of life and regulation of global climate. For a description of these properties, see ''Ice'', which deals primarily with ice Ih. The crystal structure is characterized by the oxygen atoms forming hexagonal symmetry with near tetrahedral bonding angles. Ice Ih is stable down to , as evidenced by x-ray diffraction and extremely high resolution thermal expansion measurements. Ice Ih is also stable under applied pressures of up to about where i ...
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Tension (physics)
In physics, tension is described as the pulling force transmitted axially by the means of a string, a rope, chain, or similar object, or by each end of a rod, truss member, or similar three-dimensional object; tension might also be described as the action-reaction pair of forces acting at each end of said elements. Tension could be the opposite of compression (physics), compression. At the atomic level, when atoms or molecules are pulled apart from each other and gain potential energy with a restoring force still existing, the restoring force might create what is also called tension. Each end of a string or rod under such tension could pull on the object it is attached to, in order to restore the string/rod to its relaxed length. Tension (as a transmitted force, as an action-reaction pair of forces, or as a restoring force) is measured in newton (unit), newtons in the International System of Units (or pounds-force in Imperial units). The ends of a string or other object transmitt ...
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Water Phase Diagram Extended To Negative Pressurs
Water (chemical formula ) is an Inorganic compound, inorganic, transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a solvent). It is vital for all known forms of life, despite not providing food energy, food, energy or organic micronutrients. Its chemical formula, H2O, indicates that each of its molecules contains one oxygen and two hydrogen atoms, connected by covalent bonds. The hydrogen atoms are attached to the oxygen atom at an angle of 104.45°. "Water" is also the name of the liquid state of H2O at standard temperature and pressure. A number of natural states of water exist. It forms precipitation in the form of rain and aerosols in the form of fog. Clouds consist of suspended droplets of water and ice, its solid state. When finely divided, crystalline ice may precipitate in the form of snow. The gaseous state of ...
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