Hopkinson Effect
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Hopkinson Effect
The Hopkinson effect is a feature of ferromagnetic or ferrimagnetic materials, in which an increase in magnetic susceptibility is observed at temperatures between the blocking temperature and the Curie temperature of the material. The Hopkinson effect can be observed as a peak in thermomagnetic curves that immediately precedes the susceptibility drop associated with the Curie temperature. It was first observed by John Hopkinson in 1889 in a study on iron.Hopkinson, John. “Magnetic and Other Physical Properties of Iron at a High Temperature”. Philosophical Transactions of the Royal Society of London. A 180 (1889): 443–465. In single domain particles, a large Hopkinson peak results from a transient superparamagnetic Superparamagnetism is a form of magnetism which appears in small ferromagnetic or ferrimagnetic nanoparticles. In sufficiently small nanoparticles, magnetization can randomly flip direction under the influence of temperature. The typical time be ... particle ...
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Magnetite Hopkinson Peak
Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With the exception of extremely rare native iron deposits, it is the most magnetic of all the naturally occurring minerals on Earth. Naturally magnetized pieces of magnetite, called lodestone, will attract small pieces of iron, which is how ancient peoples first discovered the property of magnetism. Magnetite is black or brownish-black with a metallic luster, has a Mohs hardness of 5–6 and leaves a black streak. Small grains of magnetite are very common in igneous and metamorphic rocks. The chemical IUPAC name is iron(II,III) oxide and the common chemical name is ''ferrous-ferric oxide''. Properties In addition to igneous rocks, magnetite also occurs in sedimentary rocks, including banded iron formations and in lake and marine sediments as ...
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Ferromagnetism
Ferromagnetism is a property of certain materials (such as iron) which results in a large observed magnetic permeability, and in many cases a large magnetic coercivity allowing the material to form a permanent magnet. Ferromagnetic materials are the familiar metals noticeably attracted to a magnet, a consequence of their large magnetic permeability. Magnetic permeability describes the induced magnetization of a material due to the presence of an ''external'' magnetic field, and it is this temporarily induced magnetization inside a steel plate, for instance, which accounts for its attraction to the permanent magnet. Whether or not that steel plate acquires a permanent magnetization itself, depends not only on the strength of the applied field, but on the so-called coercivity of that material, which varies greatly among ferromagnetic materials. In physics, several different types of material magnetism are distinguished. Ferromagnetism (along with the similar effect ferrimagnetis ...
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Ferrimagnetism
A ferrimagnetic material is a material that has populations of atoms with opposing magnetic moments, as in antiferromagnetism, but these moments are unequal in magnitude so a spontaneous magnetization remains. This can for example occur when the populations consist of different atoms or ions (such as Fe2+ and Fe3+). Ferrimagnetism has often been confused with ferromagnetism. The oldest known magnetic substance, magnetite (Fe3O4), was classified as a ferromagnet before Louis Néel discovered ferrimagnetism in 1948. Since the discovery, numerous uses have been found for ferrimagnetic materials, such as hard drive platters and biomedical applications. History Until the twentieth century, all naturally occurring magnetic substances were called ferromagnets. In 1936, Louis Néel published a paper proposing the existence of a new form of cooperative magnetism he called antiferromagnetism. While working with Mn2Sb, French physicist Charles Guillaud discovered that the current t ...
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Magnetic Susceptibility
In electromagnetism, the magnetic susceptibility (Latin: , "receptive"; denoted ) is a measure of how much a material will become magnetized in an applied magnetic field. It is the ratio of magnetization (magnetic moment per unit volume) to the applied magnetizing field intensity . This allows a simple classification, into two categories, of most materials' responses to an applied magnetic field: an alignment with the magnetic field, , called paramagnetism, or an alignment against the field, , called diamagnetism. Magnetic susceptibility indicates whether a material is attracted into or repelled out of a magnetic field. Paramagnetic materials align with the applied field and are attracted to regions of greater magnetic field. Diamagnetic materials are anti-aligned and are pushed away, toward regions of lower magnetic fields. On top of the applied field, the magnetization of the material adds its own magnetic field, causing the field lines to concentrate in paramagnetism, or be excl ...
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Superparamagnetism
Superparamagnetism is a form of magnetism which appears in small ferromagnetic or ferrimagnetic nanoparticles. In sufficiently small nanoparticles, magnetization can randomly flip direction under the influence of temperature. The typical time between two flips is called the Néel relaxation time. In the absence of an external magnetic field, when the time used to measure the magnetization of the nanoparticles is much longer than the Néel relaxation time, their magnetization appears to be in average zero; they are said to be in the superparamagnetic state. In this state, an external magnetic field is able to magnetize the nanoparticles, similarly to a paramagnet. However, their magnetic susceptibility is much larger than that of paramagnets. The Néel relaxation in the absence of magnetic field Normally, any ferromagnetic or ferrimagnetic material undergoes a transition to a paramagnetic state above its Curie temperature. Superparamagnetism is different from this standard transi ...
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Curie Temperature
In physics and materials science, the Curie temperature (''T''C), or Curie point, is the temperature above which certain materials lose their permanent magnetic properties, which can (in most cases) be replaced by induced magnetism. The Curie temperature is named after Pierre Curie, who showed that magnetism was lost at a critical temperature. The force of magnetism is determined by the magnetic moment, a dipole moment within an atom which originates from the angular momentum and spin of electrons. Materials have different structures of intrinsic magnetic moments that depend on temperature; the Curie temperature is the critical point at which a material's intrinsic magnetic moments change direction. Permanent magnetism is caused by the alignment of magnetic moments and induced magnetism is created when disordered magnetic moments are forced to align in an applied magnetic field. For example, the ordered magnetic moments (ferromagnetic, Figure 1) change and become disorder ...
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John Hopkinson
John Hopkinson, FRS, (27 July 1849 – 27 August 1898) was a British physicist, electrical engineer, Fellow of the Royal Society and President of the IEE (now the IET) twice in 1890 and 1896. He invented the three-wire (three-phase) system for the distribution of electrical power, for which he was granted a patent in 1882. He also worked in many areas of electromagnetism and electrostatics, and in 1890 was appointed professor of electrical engineering at King's College London, where he was also director of the Siemens Laboratory. Hopkinson's law, the magnetic counterpart to Ohm's law, is named after him. Life and career John Hopkinson was born in Manchester, the eldest of 5 children. His father, also called John, was a mechanical engineer. He was educated at Queenwood School in Hampshire and Owens College in Manchester. He won a scholarship to Trinity College, Cambridge in 1867 and graduated in 1871 as Senior Wrangler, having placed first in the demanding Cambridge Mathemati ...
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Rock Magnetism
Rock magnetism is the study of the magnetic properties of rocks, sediments and soils. The field arose out of the need in paleomagnetism to understand how rocks record the Earth's magnetic field. This remanence is carried by minerals, particularly certain strongly magnetic minerals like magnetite (the main source of magnetism in lodestone). An understanding of remanence helps paleomagnetists to develop methods for measuring the ancient magnetic field and correct for effects like sediment compaction and metamorphism. Rock magnetic methods are used to get a more detailed picture of the source of the distinctive striped pattern in marine magnetic anomalies that provides important information on plate tectonics. They are also used to interpret terrestrial magnetic anomalies in magnetic surveys as well as the strong crustal magnetism on Mars. Strongly magnetic minerals have properties that depend on the size, shape, defect structure and concentration of the minerals in a rock. Rock ma ...
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