Homoisoflavonoids
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Homoisoflavonoids
Homoisoflavonoids (3-benzylidenechroman-4-ones) are a type of phenolic compounds occurring naturally in plants. Chemically, they have the general structure of a 16-carbon skeleton, which consists of two phenyl rings (A and B) and heterocyclic ring (C). Synthesis Homoisoflavones can be synthetized from 2'-hydroxydihydrochalcones. Homoisoflavanones can be synthetized from 3,5-methoxy phenols via chroman-4-one in three steps or from phloroglucinol. ;Conversion Homoisoflavanes can be obtained from the conversion of homoisoflavonoids. Natural occurrences The homoisoflavonoids portulacanones A, B, C and D can be found in '' Portulaca oleracea'' (common purslane, Caryophyllales, Portulacaceae). The 3,4-dihydroxyhomoisoflavans sappanol, episappanol, 3'-deoxysappanol, 3'-O-methylsappanol and 3'-O-methylepisappanol can be found in ''Caesalpinia sappan''. The homoisoflavones scillavones A and B can be isolated from the bulbs of ''Scilla scilloides'' ('' Barnardia japonica'') ...
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Sappanol
Sappanol is a 3,4-dihydroxyhomoisoflavan, a type of homoisoflavonoid, that can be found in ''Caesalpinia sappan ''Biancaea sappan'' is a species of flowering tree in the legume family, Fabaceae, that is native to tropical Asia. Common names in English include sappanwood and Indian redwood. Sappanwood is related to brazilwood (''Paubrasilia echinata''), ...''.Homoisoflavonoids and related compounds. II. Isolation and absolute configurations of 3,4-dihydroxylated homoisoflavans and brazilins from Caesalpinia sappan L. Michio Namikoshi, Hiroyuki Nakata, Hiroyuki Yamada, Minako Nagai and Tamotsu Saitoh, Chemical & Pharmaceutical Bulletin, 1987, volume 35, number 7, pages 2761-2773abstract References Homoisoflavonoids {{aromatic-stub ...
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Sappanol
Sappanol is a 3,4-dihydroxyhomoisoflavan, a type of homoisoflavonoid, that can be found in ''Caesalpinia sappan ''Biancaea sappan'' is a species of flowering tree in the legume family, Fabaceae, that is native to tropical Asia. Common names in English include sappanwood and Indian redwood. Sappanwood is related to brazilwood (''Paubrasilia echinata''), ...''.Homoisoflavonoids and related compounds. II. Isolation and absolute configurations of 3,4-dihydroxylated homoisoflavans and brazilins from Caesalpinia sappan L. Michio Namikoshi, Hiroyuki Nakata, Hiroyuki Yamada, Minako Nagai and Tamotsu Saitoh, Chemical & Pharmaceutical Bulletin, 1987, volume 35, number 7, pages 2761-2773abstract References Homoisoflavonoids {{aromatic-stub ...
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Sappanone A
Sappanone A is a homoisoflavanone that can be found in ''Caesalpinia sappan ''Biancaea sappan'' is a species of flowering tree in the legume family, Fabaceae, that is native to tropical Asia. Common names in English include sappanwood and Indian redwood. Sappanwood is related to brazilwood (''Paubrasilia echinata''), ...''. References Homoisoflavonoids {{aromatic-stub ...
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Scillavone B
Scillavone B is a homoisoflavone that can be isolated from the bulbs of ''Scilla scilloides'' ('' Barnardia japonica''). References External links Scillavone B at kanaya.naist.jp/knapsack_jspScillavone B at ctdbase.org Homoisoflavonoids O-methylated natural phenols {{aromatic-stub ...
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Scillavone A
Scillavone A is a homoisoflavone that can be isolated from the bulbs of ''Scilla scilloides'' ('' Barnardia japonica''). References External links Scillavone A at kanaya.naist.jp/knapsack_jsp Homoisoflavonoids O-methylated natural phenols {{aromatic-stub ...
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Cremastra Appendiculata
''Cremastra appendiculata'' is an orchid species in the genus '' Cremastra''. It is the type species of its genus. There two subspecies: * ''Cremastra appendiculata ''var''. appendiculata'' - Taiwan, Tibet, Yunnan, Bhutan, Assam, Nepal, Japan, Korea, Thailand, Vietnam * ''Cremastra appendiculata ''var''. variabilis'' (Blume) I.D.Lund - Kuril, Sakhalin, Japan, Korea, Thailand, Vietnam, Anhui, Chongqing, Gansu, Guangdong, Guangxi, Guizhou, Henan, Hubei, Hunan, Jiangsu, Jiangxi, Shaanxi, Shanxi, Sichuan, Zhejiang 5,7-Dihydroxy-3-(3-hydroxy-4-methoxybenzyl)-chroman-4-one, a homoisoflavanone Homoisoflavonoids (3-benzylidenechroman-4-ones) are a type of phenolic compounds occurring naturally in plants. Chemically, they have the general structure of a 16-carbon skeleton, which consists of two phenyl rings (A and B) and heterocyclic rin ... extracted from ''C. appendiculata'', has anti-angiogenic activities and inhibits UVB-induced skin inflammation through reduced cyclooxygenase-2 e ...
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Chlorophytum Inornatum
''Chlorophytum inornatum'' is a flowering plant species in the genus ''Chlorophytum''. It is the type species of its genus. It is related to the commonly known plant Chlorophytum also referred to as a "spider plant". 3-(4'-Methoxybenzyl)-7,8-methylenedioxy-chroman-4-one, a homoisoflavanone Homoisoflavonoids (3-benzylidenechroman-4-ones) are a type of phenolic compounds occurring naturally in plants. Chemically, they have the general structure of a 16-carbon skeleton, which consists of two phenyl rings (A and B) and heterocyclic rin ... with antimycobacterial activity, can be isolated from ''C. inornatum''.Synthesis of (+/-) homoisoflavanone and corresponding homoisoflavane. Zhang L, Zhang WG, Kang J, Bao K, Dai Y and Yao XS, Journal of Asian natural products research, volume 10, issues 9-10, pages 909-13, Phytochemistry and antimycobacterial activity of Chlorophytum inornatum. Gemma O’Donnell, Franz Bucar and Simon Gibbons, Phytochemistry, January 2006, Volume 67, Issue 2, Pa ...
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