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Holger Braunschweig
Holger Braunschweig is Head and Chair of Inorganic Chemistry at the Julius-Maximilians-University of Würzburg in Würzburg, Germany. He is best known for founding the field of transition metal- boron multiple bonding (transition metal borylenes), the synthesis of the first stable compounds containing boron-boron and boron-oxygen triple bonds, the isolation of the first non-carbon/nitrogen main-group dicarbonyl, and the first fixation of dinitrogen at an element of the p-block of the periodic table. By modifying a strategy pioneered by Prof. Gregory Robinson of the University of Georgia, Braunschweig also discovered the first rational and high-yield synthesis of neutral compounds containing boron-boron double bonds ( diborenes). In 2016 Braunschweig isolated the first compounds of beryllium in the oxidation state of zero. Education and research career Braunschweig obtained his Ph.D. and Habilitation from RWTH Aachen with P. Paetzold and worked as a postdoctoral researcher wi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Germany
Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated between the Baltic and North seas to the north, and the Alps to the south; it covers an area of , with a population of almost 84 million within its 16 constituent states. Germany borders Denmark to the north, Poland and the Czech Republic to the east, Austria and Switzerland to the south, and France, Luxembourg, Belgium, and the Netherlands to the west. The nation's capital and most populous city is Berlin and its financial centre is Frankfurt; the largest urban area is the Ruhr. Various Germanic tribes have inhabited the northern parts of modern Germany since classical antiquity. A region named Germania was documented before AD 100. In 962, the Kingdom of Germany formed the bulk of the Holy Roman Empire. During the 16th ce ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Boron Dinitrogen Activation
Boron is a chemical element with the symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the ''boron group'' it has three valence electrons for forming covalent bonds, resulting in many compounds such as boric acid, the mineral sodium borate, and the ultra-hard crystals of boron carbide and boron nitride. Boron is synthesized entirely by cosmic ray spallation and supernovae and not by stellar nucleosynthesis, so it is a low-abundance element in the Solar System and in the Earth's crust. It constitutes about 0.001 percent by weight of Earth's crust. It is concentrated on Earth by the water-solubility of its more common naturally occurring compounds, the borate minerals. These are mined industrially as evaporites, such as borax and kernite. The largest known deposits are in Turkey, the largest producer of boron minerals. Elemental boron is a metalloid that ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
University Of Sussex
, mottoeng = Be Still and Know , established = , type = Public research university , endowment = £14.4 million (2020) , budget = £319.6 million (2019–20) , chancellor = Sanjeev Bhaskar , vice_chancellor = Sasha Roseneil , head_label = Visitor , head = King Charles III , students = 19,413 (2019–20) , undergrad = 14,619https://www.sussex.ac.uk/webteam/gateway/file.php?name=19-20-digest---undergraduate-student-summary.pdf&site=381 , postgrad = 4,794https://www.sussex.ac.uk/webteam/gateway/file.php?name=19-20-digest---postgraduate-student-summary.pdf&site=381 , city = Falmer, Brighton , state = East Sussex , country = England , campus = Campus , colours = White and Flint , mascot = Badger , affiliations = Universities UK, BUCS, Sepnet, SeNSS, Association of Commonwealth Universities, NCUB , website = , logo = University of Sussex Logo.svg , footnotes = , academic_staff = 2,010 (2020) , administrative_staff = 1,100 The Universit ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Michael F
Michael may refer to: People * Michael (given name), a given name * Michael (surname), including a list of people with the surname Michael Given name "Michael" * Michael (archangel), ''first'' of God's archangels in the Jewish, Christian and Islamic religions * Michael (bishop elect), English 13th-century Bishop of Hereford elect * Michael (Khoroshy) (1885–1977), cleric of the Ukrainian Orthodox Church of Canada * Michael Donnellan (1915–1985), Irish-born London fashion designer, often referred to simply as "Michael" * Michael (footballer, born 1982), Brazilian footballer * Michael (footballer, born 1983), Brazilian footballer * Michael (footballer, born 1993), Brazilian footballer * Michael (footballer, born February 1996), Brazilian footballer * Michael (footballer, born March 1996), Brazilian footballer * Michael (footballer, born 1999), Brazilian footballer Rulers =Byzantine emperors= *Michael I Rangabe (d. 844), married the daughter of Emperor Nikephoros I *Mic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Habilitation
Habilitation is the highest university degree, or the procedure by which it is achieved, in many European countries. The candidate fulfills a university's set criteria of excellence in research, teaching and further education, usually including a dissertation. The degree, abbreviated "Dr. habil." (Doctor habilitatus) or "PD" (for "Privatdozent"), is a qualification for professorship in those countries. The conferral is usually accompanied by a lecture to a colloquium as well as a public inaugural lecture. History and etymology The term ''habilitation'' is derived from the Medieval Latin , meaning "to make suitable, to fit", from Classical Latin "fit, proper, skillful". The degree developed in Germany in the seventeenth century (). Initially, habilitation was synonymous with "doctoral qualification". The term became synonymous with "post-doctoral qualification" in Germany in the 19th century "when holding a doctorate seemed no longer sufficient to guarantee a proficient transfer o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Diborene
Diborane(2) or diborene is a theoretical/hypothetical inorganic compound with the formula B2H2. Diborenes also refers to a series of molecules with a formula R:(BH)=(BH):R, where R is an organic group. B2H2 are unstable under ambient conditions. They are synthesized by pulsed laser ablation of boron in a mixed hydrogen-argon gas atmosphere. Upon cooling the mixture, the argon gas changes into a solid, thereby stabilizing the trapped diboranes. B2H2 is a linear molecule with a triplet ground state, as revealed by electron paramagnetic resonance Electron paramagnetic resonance (EPR) or electron spin resonance (ESR) spectroscopy is a method for studying materials that have unpaired electrons. The basic concepts of EPR are analogous to those of nuclear magnetic resonance (NMR), but the spi ..., and shows an antisymmetric stretching mode at 2679.9 cm–1. References Boranes {{theoretical-chem-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
University Of Georgia
, mottoeng = "To teach, to serve, and to inquire into the nature of things.""To serve" was later added to the motto without changing the seal; the Latin motto directly translates as "To teach and to inquire into the nature of things." , established = , endowment = $1.8 billion (2021)As of June 30, 2021. , type = Public flagship land-grant research university , parent = University System of Georgia , accreditation = SACS , academic_affiliation = , president = Jere W. Morehead , provost = S. Jack Hu , city = Athens , state=Georgia , country = United States , coordinates = , faculty = 3,119 , students = 40,118 (fall 2021) , undergrad = 30,166 (fall 2021) , postgrad = 9,952 (fall 2021) , free_label2 = Newspaper , free2 = '' The Red & Black'' , campus = Midsize city / College town , campus_size = (main campus) (total) , colors = , sports_nickname = Bulldogs , sporting_affiliations = NCAA Division I FBS – SEC , mascot = Uga X (live English Bulldo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Periodic Table
The periodic table, also known as the periodic table of the (chemical) elements, is a rows and columns arrangement of the chemical elements. It is widely used in chemistry, physics, and other sciences, and is generally seen as an icon of chemistry. It is a graphic formulation of the periodic law, which states that the properties of the chemical elements exhibit an approximate periodic dependence on their atomic numbers. The table is divided into four roughly rectangular areas called blocks. The rows of the table are called periods, and the columns are called groups. Elements from the same group of the periodic table show similar chemical characteristics. Trends run through the periodic table, with nonmetallic character (keeping their own electrons) increasing from left to right across a period, and from down to up across a group, and metallic character (surrendering electrons to other atoms) increasing in the opposite direction. The underlying reason for these trends is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
P-block
A block of the periodic table is a set of elements unified by the atomic orbitals their valence electrons or vacancies lie in. The term appears to have been first used by Charles Janet. Each block is named after its characteristic orbital: s-block, p-block, d-block, and f-block. The block names (s, p, d, and f) are derived from the spectroscopic notation for the value of an electron's azimuthal quantum number: sharp (0), principal (1), diffuse (2), or fundamental (3). Succeeding notations proceed in alphabetical order, as g, h, etc., though elements that would belong in such blocks have not yet been found. Characteristics There is an ''approximate'' correspondence between this nomenclature of blocks, based on electronic configuration, and sets of elements based on chemical properties. The s-block and p-block together are usually considered main-group elements, the d-block corresponds to the transition metals, and the f-block corresponds to the inner transiti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitrogen Fixation
Nitrogen fixation is a chemical process by which molecular nitrogen (), with a strong triple covalent bond, in the air is converted into ammonia () or related nitrogenous compounds, typically in soil or aquatic systems but also in industry. Atmospheric nitrogen is molecular dinitrogen, a relatively nonreactive molecule that is metabolically useless to all but a few microorganisms. Biological nitrogen fixation or ''diazotrophy'' is an important microbials mediated process that converts dinitrogen (N2) gas to ammonia (NH3) using the nitrogenase protein complex (Nif). Nitrogen fixation is essential to life because fixed inorganic nitrogen compounds are required for the biosynthesis of all nitrogen-containing organic compounds, such as amino acids and proteins, nucleoside triphosphates and nucleic acids. As part of the nitrogen cycle, it is essential for agriculture and the manufacture of fertilizer. It is also, indirectly, relevant to the manufacture of all nitrogen chemical c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxoborane
In chemistry, an oxoborane is any chemical compound containing a boron atom with a terminal oxygen atom (a functional group). The compound class is of some relevance to academic research. The parent compound, HBO, itself called "oxoborane", together with derivatives , , , and have been detected in matrix isolation or in the gaseous phase at high temperature. In these compounds the boron and oxygen form a triple bond prone to cyclotrimerization to boroxines. Derivatives Although monomeric oxoboranes have not been isolated, derivatives have been described. A Lewis acid-stabilized adduct of an oxoborane is ( NacNacB=O.AlCl3. In this compound the oxygen atom is coordinated to aluminium chloride. The BO bond length is 130 pm (compare to 136 pm in regular boronic acids). Related systems are known. In ''trans''- Cy3P)2PtBr(BO) platinum is coordinated to the BO unit.''Oxoboryl Complexes: Boron−Oxygen Triple Bonds Stabilized in the Coordination Sphere of Platinum'' Holger Braunschwe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Borylene
A borylene is the boron analogue of a carbene. The general structure is R-B: with R an organic residue and B a boron atom with two unshared electrons. Borylenes are of academic interest in organoboron chemistry. A singlet ground state is predominant with boron having two vacant sp2 orbitals and one doubly occupied one. With just one additional substituent the boron is more electron deficient than the carbon atom in a carbene. For this reason stable borylenes are more uncommon than stable carbenes. Some borylenes such as boron monofluoride (BF) and boron monohydride (BH) the parent compound also known simply as borylene, have been detected in microwave spectroscopy and may exist in stars. Other borylenes exist as reactive intermediates and can only be inferred by chemical trapping. The first stable terminal borylene complex OC)5WBN(SiMe3)2was reported by Holger Braunschweig et al. in 1998. In this compound a borylene is coordinated to a transition metal. Borylenes are also s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
