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Hydrazinium Nitroformate
Hydrazinium nitroformate (HNF) is a salt of hydrazine and nitroform (trinitromethane). It has the molecular formula and is soluble in most solvents. Hydrazinium nitroformate is an energetic oxidizer. Research is being conducted at the European Space Agency to investigate its use in solid rocket propellants. It tends to produce propellants which burn very rapidly and with very high combustion efficiency. Its high energy leads to high specific impulse Specific impulse (usually abbreviated ) is a measure of how efficiently a reaction mass engine (a rocket using propellant or a jet engine using fuel) creates thrust. For engines whose reaction mass is only the fuel they carry, specific impulse i ... propellants. It is currently an expensive research chemical available only in limited quantities. A disadvantage of HNF is its limited thermal stability. References {{reflist Rocket fuels Hydrazinium compounds Nitroalkanes ...
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Salt (chemistry)
In chemistry, a salt is a chemical compound consisting of an ionic assembly of positively charged cations and negatively charged anions, which results in a compound with no net electric charge. A common example is table salt, with positively charged sodium ions and negatively charged chloride ions. The component ions in a salt compound can be either inorganic, such as chloride (Cl−), or organic, such as acetate (). Each ion can be either monatomic, such as fluoride (F−), or polyatomic, such as sulfate (). Types of salt Salts can be classified in a variety of ways. Salts that produce hydroxide ions when dissolved in water are called ''alkali salts'' and salts that produce hydrogen ions when dissolved in water are called ''acid salts''. ''Neutral salts'' are those salts that are neither acidic nor basic. Zwitterions contain an anionic and a cationic centre in the same molecule, but are not considered salts. Examples of zwitterions are amino acids, many metabolites, peptid ...
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Hydrazine
Hydrazine is an inorganic compound with the chemical formula . It is a simple pnictogen hydride, and is a colourless flammable liquid with an ammonia-like odour. Hydrazine is highly toxic unless handled in solution as, for example, hydrazine hydrate (). Hydrazine is mainly used as a foaming agent in preparing polymer foams, but applications also include its uses as a precursor to polymerization catalysts, pharmaceuticals, and agrochemicals, as well as a long-term storable propellant for in-space spacecraft propulsion. Additionally, hydrazine is used in various rocket fuels and to prepare the gas precursors used in air bags. Hydrazine is used within both nuclear and conventional electrical power plant steam cycles as an oxygen scavenger to control concentrations of dissolved oxygen in an effort to reduce corrosion. the world hydrazine hydrate market amounted to $350 million. About two million tons of hydrazine hydrate were used in foam blowing agents in 2015. Hydrazines r ...
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Nitroform
Trinitromethane, also referred to as nitroform, is a nitroalkane and oxidizer with chemical formula HC(NO2)3. It was first obtained in 1857 as the ammonium salt by the Russian chemist Leon Nikolaevich Shishkov (1830–1908). In 1900, it was discovered that nitroform can be produced by the reaction of acetylene with anhydrous nitric acid. This method went on to become the industrial process of choice during the 20th century. In the laboratory, nitroform can also be produced by hydrolysis of tetranitromethane under mild basic conditions. Acidity Trinitromethane as a neutral molecule is colorless. It is highly acidic, easily forming an intensely yellow anion, (NO2)3C−. The p''K''a of trinitromethane has been measured at 0.17 ± 0.02 at 20 °C, which is remarkably acidic for a methane derivative. Trinitromethane easily dissolves in water to form an acidic yellow solution. There is some evidence that the anion, which obeys the 4''n''+2 Hückel rule, is aromatic. Nitroform sal ...
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Oxidizer
An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or " accepts"/"receives" an electron from a (called the , , or ). In other words, an oxidizer is any substance that oxidizes another substance. The oxidation state, which describes the degree of loss of electrons, of the oxidizer decreases while that of the reductant increases; this is expressed by saying that oxidizers "undergo reduction" and "are reduced" while reducers "undergo oxidation" and "are oxidized". Common oxidizing agents are oxygen, hydrogen peroxide and the halogens. In one sense, an oxidizing agent is a chemical species that undergoes a chemical reaction in which it gains one or more electrons. In that sense, it is one component in an oxidation–reduction (redox) reaction. In the second sense, an oxidizing agent is a chemical species that transfers electronegative atoms, usually oxygen, to a substrate. Combust ...
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European Space Agency
, owners = , headquarters = Paris, Île-de-France, France , coordinates = , spaceport = Guiana Space Centre , seal = File:ESA emblem seal.png , seal_size = 130px , image = Views in the Main Control Room (12052189474).jpg , size = , caption = , acronym = , established = , employees = 2,200 , administrator = Director General Josef Aschbacher , budget = €7.2 billion (2022) , language = English and French (working languages) , website = , logo = European Space Agency logo.svg , logo_caption = Logo , image_caption = European Space Operations Centre (ESOC) Main Control Room The European Space Agency (ESA; french: Agence spatiale européenne , it, Agenzia Spaziale Europea, es, Agencia Espacial Europea ASE; german: Europäische Weltraumorganisation) is an intergovernmental organisation of 22 member states dedicated to the exploration of space. Established in 1975 and headquartered i ...
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Rocket Propellant
Rocket propellant is the reaction mass of a rocket. This reaction mass is ejected at the highest achievable velocity from a rocket engine A rocket engine uses stored rocket propellants as the reaction mass for forming a high-speed propulsive jet of fluid, usually high-temperature gas. Rocket engines are reaction engines, producing thrust by ejecting mass rearward, in accordanc ... to produce thrust. The energy required can either come from the propellants themselves, as with a chemical rocket, or from an external source, as with ion engines. Overview Rockets create thrust by expelling mass rear-ward, at high velocity. The thrust produced can be calculated by multiplying the mass flow rate of the propellants by their exhaust velocity relative to the rocket (specific impulse). A rocket can be thought of as being accelerated by the pressure of the combusting gases against the combustion chamber and Rocket engine nozzle, nozzle, not by "pushing" against the air behind or belo ...
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The Aerospace Corporation
The Aerospace Corporation is an American nonprofit corporation that operates a federally funded research and development center (FFRDC) in El Segundo, California. The corporation provides technical guidance and advice on all aspects of space missions to military, civil, and commercial customers. As the FFRDC for national-security space, Aerospace works closely with organizations such as the United States Space Force and the National Reconnaissance Office (NRO) to provide "objective technical analyses and assessments for space programs that serve the national interest". Although the USSF and NRO are the primary customers, Aerospace also performs work for civil agencies such as NASA and NOAA as well as international organizations and governments in the national interest. History On July 1, 1954, the Western Development Division (WDD) of the United States Air Force was established, under the command of Brig Gen Bernard A. Schriever. WDD was responsible for the development of the ...
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Specific Impulse
Specific impulse (usually abbreviated ) is a measure of how efficiently a reaction mass engine (a rocket using propellant or a jet engine using fuel) creates thrust. For engines whose reaction mass is only the fuel they carry, specific impulse is exactly proportional to the effective exhaust gas velocity. A propulsion system with a higher specific impulse uses the mass of the propellant more efficiently. In the case of a rocket, this means less propellant needed for a given delta-v, so that the vehicle attached to the engine can more efficiently gain altitude and velocity. In an atmospheric context, specific impulse can include the contribution to impulse provided by the mass of external air that is accelerated by the engine in some way, such as by an internal turbofan or heating by fuel combustion participation then thrust expansion or by external propeller. Jet engines breathe external air for both combustion and by-pass, and therefore have a much higher specific impulse than ...
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Rocket Fuels
Rocket propellant is the reaction mass of a rocket. This reaction mass is ejected at the highest achievable velocity from a rocket engine to produce thrust. The energy required can either come from the propellants themselves, as with a chemical rocket, or from an external source, as with ion engines. Overview Rockets create thrust by expelling mass rear-ward, at high velocity. The thrust produced can be calculated by multiplying the mass flow rate of the propellants by their exhaust velocity relative to the rocket (specific impulse). A rocket can be thought of as being accelerated by the pressure of the combusting gases against the combustion chamber and nozzle, not by "pushing" against the air behind or below it. Rocket engines perform best in outer space because of the lack of air pressure on the outside of the engine. In space it is also possible to fit a longer nozzle without suffering from flow separation. Most chemical propellants release energy through redox chemistry, m ...
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Hydrazinium Compounds
Hydrazinium is the cation with the formula . This cation has a methylamine-like structure (). It can be derived from hydrazine by protonation (treatment with a strong acid). Hydrazinium is a weak acid with p''K''a = 8.1. Salts of hydrazinium are common reagents in chemistry and are often used in certain industrial processes.Jean-Pierre Schirmann, Paul Bourdauducq "Hydrazine" in ''Ullmann's Encyclopedia of Industrial Chemistry'', Wiley-VCH, Weinheim, 2002. . Notable examples are hydrazinium hydrogensulfate, or , and hydrazinium azide, or . In the common names of such salts, the cation is often called "hydrazine", as in "hydrazine sulfate" for hydrazinium hydrogensulfate. The terms "hydrazinium" and "hydrazine" may also be used for the doubly protonated cation , more properly called hydrazinediium or hydrazinium(2+). This cation has an ethane-like structure (). Salts of this cation include hydrazinediium sulfate and hydrazinediium bis(6-carboxypyridazine-3-carboxylate) ...
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