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Hooke's Atom
Hooke's atom, also known as harmonium or hookium, refers to an artificial helium-like atom where the Coulombic electron-nucleus interaction potential is replaced by a harmonic potential. This system is of significance as it is, for certain values of the force constant defining the harmonic containment, an exactly solvable ground-state many-electron problem that explicitly includes electron correlation. As such it can provide insight into quantum correlation (albeit in the presence of a non-physical nuclear potential) and can act as a test system for judging the accuracy of approximate quantum chemical methods for solving the Schrödinger equation. The name "Hooke's atom" arises because the harmonic potential used to describe the electron-nucleus interaction is a consequence of Hooke's law. Definition Employing atomic units, the Hamiltonian defining the Hooke's atom is :\hat = -\frac\nabla^_ -\frac\nabla^_ + \frack(r^_+r^_) + \frac. As written, the first two terms are the kin ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Helium
Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic table. Its boiling and melting point are the lowest among all the elements. It is the second lightest and second most abundant element in the observable universe (hydrogen is the lightest and most abundant). It is present at about 24% of the total elemental mass, which is more than 12 times the mass of all the heavier elements combined. Its abundance is similar to this in both the Sun and in Jupiter, due to the very high nuclear binding energy (per nucleon) of helium-4, with respect to the next three elements after helium. This helium-4 binding energy also accounts for why it is a product of both nuclear fusion and radioactive decay. The most common isotope of helium in the universe is helium-4, the vast majority of which was formed during t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Separation Of Variables
In mathematics, separation of variables (also known as the Fourier method) is any of several methods for solving ordinary and partial differential equations, in which algebra allows one to rewrite an equation so that each of two variables occurs on a different side of the equation. Ordinary differential equations (ODE) Suppose a differential equation can be written in the form :\frac f(x) = g(x)h(f(x)) which we can write more simply by letting y = f(x): :\frac=g(x)h(y). As long as ''h''(''y'') ≠ 0, we can rearrange terms to obtain: : = g(x) \, dx, so that the two variables ''x'' and ''y'' have been separated. ''dx'' (and ''dy'') can be viewed, at a simple level, as just a convenient notation, which provides a handy mnemonic aid for assisting with manipulations. A formal definition of ''dx'' as a differential (infinitesimal) is somewhat advanced. Alternative notation Those who dislike Leibniz's notation may prefer to write this as :\frac \frac = g(x), but that ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Physical Review A
''Physical Review A'' (also known as PRA) is a monthly peer-reviewed scientific journal published by the American Physical Society covering atomic, molecular, and optical physics and quantum information. the editor was Jan M. Rost (Max Planck Institute for the Physics of Complex Systems). History In 1893, the ''Physical Review'' was established at Cornell University. It was taken over by the American Physical Society (formed in 1899) in 1913. In 1970, ''Physical Review'' was subdivided into ''Physical Review A'', ''B'', ''C'', and ''D''. At that time section ''A'' was subtitled ''Physical Review A: General Physics''. In 1990 a process was started to split this journal into two, resulting in the creation of ''Physical Review E'' in 1993. Hence, in 1993, ''Physical Review A'' changed its statement of scope to ''Atomic, Molecular and Optical Physics.'' In January 2007, the section of ''Physical Review E'' that published papers on classical optics was merged into ''Physical Review ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
List Of Quantum-mechanical Systems With Analytical Solutions
Much insight in quantum mechanics can be gained from understanding the closed-form solutions to the time-dependent non-relativistic Schrödinger equation. It takes the form : \hat \psi\left(\mathbf, t\right) = \left - \frac \nabla^2 + V\left(\mathbf\right) \right\psi\left(\mathbf, t\right) = i\hbar \frac, where \psi is the wave function of the system, \hat is the Hamiltonian operator, and t is time. Stationary states of this equation are found by solving the time-independent Schrödinger equation, : \left - \frac \nabla^2 + V\left(\mathbf\right) \right\psi\left(\mathbf\right) = E \psi \left(\mathbf\right), which is an eigenvalue equation. Very often, only numerical solutions to the Schrödinger equation can be found for a given physical system and its associated potential energy. However, there exists a subset of physical systems for which the form of the eigenfunctions and their associated energies, or eigenvalues, can be found. These quantum-mechanical systems with analyt ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electronic Density
In quantum chemistry, electron density or electronic density is the measure of the probability of an electron being present at an infinitesimal element of space surrounding any given point. It is a scalar quantity depending upon three spatial variables and is typically denoted as either \rho(\textbf r) or n(\textbf r). The density is determined, through definition, by the normalised N-electron wavefunction which itself depends upon 4N variables (3N spatial and N spin coordinates). Conversely, the density determines the wave function modulo up to a phase factor, providing the formal foundation of density functional theory. According to quantum mechanics, due to the uncertainty principle on an atomic scale the exact location of an electron cannot be predicted, only the probability of its being at a given position; therefore electrons in atoms and molecules act as if they are "smeared out" in space. For one-electron systems, the electron density at any point is proportional to the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Normalisable Wave Function
A wave function in quantum physics is a mathematical description of the quantum state of an isolated quantum system. The wave function is a complex-valued probability amplitude, and the probabilities for the possible results of measurements made on the system can be derived from it. The most common symbols for a wave function are the Greek letters and (lower-case and capital psi, respectively). The wave function is a function of the degrees of freedom corresponding to some maximal set of commuting observables. Once such a representation is chosen, the wave function can be derived from the quantum state. For a given system, the choice of which commuting degrees of freedom to use is not unique, and correspondingly the domain of the wave function is also not unique. For instance, it may be taken to be a function of all the position coordinates of the particles over position space, or the momenta of all the particles over momentum space; the two are related by a Fouri ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Frobenius Method
In mathematics, the method of Frobenius, named after Ferdinand Georg Frobenius, is a way to find an infinite series solution for a second-order ordinary differential equation of the form z^2 u'' + p(z)z u'+ q(z) u = 0 with u' \equiv \frac and u'' \equiv \frac. in the vicinity of the regular singular point z=0. One can divide by z^2 to obtain a differential equation of the form u'' + \fracu' + \fracu = 0 which will not be solvable with regular power series methods if either or are not analytic at . The Frobenius method enables one to create a power series solution to such a differential equation, provided that ''p''(''z'') and ''q''(''z'') are themselves analytic at 0 or, being analytic elsewhere, both their limits at 0 exist (and are finite). Explanation The method of Frobenius is to seek a power series solution of the form u(z)=z^r \sum_^\infty A_k z^k, \qquad (A_0 \neq 0) Differentiating: u'(z)=\sum_^\infty (k+r)A_kz^ u''(z)=\sum_^\infty (k+r-1)(k+r)A_kz^ Substit ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spherical Coordinates
In mathematics, a spherical coordinate system is a coordinate system for three-dimensional space where the position of a point is specified by three numbers: the ''radial distance'' of that point from a fixed origin, its ''polar angle'' measured from a fixed zenith direction, and the ''azimuthal angle'' of its orthogonal projection on a reference plane that passes through the origin and is orthogonal to the zenith, measured from a fixed reference direction on that plane. It can be seen as the three-dimensional version of the polar coordinate system. The radial distance is also called the ''radius'' or ''radial coordinate''. The polar angle may be called '' colatitude'', ''zenith angle'', '' normal angle'', or ''inclination angle''. When radius is fixed, the two angular coordinates make a coordinate system on the sphere sometimes called spherical polar coordinates. The use of symbols and the order of the coordinates differs among sources and disciplines. This article will us ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Laplacian
In mathematics, the Laplace operator or Laplacian is a differential operator given by the divergence of the gradient of a scalar function on Euclidean space. It is usually denoted by the symbols \nabla\cdot\nabla, \nabla^2 (where \nabla is the nabla operator), or \Delta. In a Cartesian coordinate system, the Laplacian is given by the sum of second partial derivatives of the function with respect to each independent variable. In other coordinate systems, such as cylindrical and spherical coordinates, the Laplacian also has a useful form. Informally, the Laplacian of a function at a point measures by how much the average value of over small spheres or balls centered at deviates from . The Laplace operator is named after the French mathematician Pierre-Simon de Laplace (1749–1827), who first applied the operator to the study of celestial mechanics: the Laplacian of the gravitational potential due to a given mass density distribution is a constant multiple of that densit ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
3D Isotropic Harmonic Oscillator
3-D, 3D, or 3d may refer to: Science, technology, and mathematics Relating to three-dimensionality * Three-dimensional space ** 3D computer graphics, computer graphics that use a three-dimensional representation of geometric data ** 3D film, a motion picture that gives the illusion of three-dimensional perception ** 3D modeling, developing a representation of any three-dimensional surface or object ** 3D printing, making a three-dimensional solid object of a shape from a digital model ** 3D display, a type of information display that conveys depth to the viewer ** 3D television, television that conveys depth perception to the viewer ** Stereoscopy, any technique capable of recording three-dimensional visual information or creating the illusion of depth in an image Other uses in science and technology or commercial products * 3D projection * 3D rendering * 3D scanning, making a digital representation of three-dimensional objects * 3D video game (other) * 3-D Secure, a s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Countable Set
In mathematics, a set is countable if either it is finite or it can be made in one to one correspondence with the set of natural numbers. Equivalently, a set is ''countable'' if there exists an injective function from it into the natural numbers; this means that each element in the set may be associated to a unique natural number, or that the elements of the set can be counted one at a time, although the counting may never finish due to an infinite number of elements. In more technical terms, assuming the axiom of countable choice, a set is ''countable'' if its cardinality (its number of elements) is not greater than that of the natural numbers. A countable set that is not finite is said countably infinite. The concept is attributed to Georg Cantor, who proved the existence of uncountable sets, that is, sets that are not countable; for example the set of the real numbers. A note on terminology Although the terms "countable" and "countably infinite" as defined here are quite co ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Coulomb's Law
Coulomb's inverse-square law, or simply Coulomb's law, is an experimental law of physics that quantifies the amount of force between two stationary, electrically charged particles. The electric force between charged bodies at rest is conventionally called ''electrostatic force'' or Coulomb force. Although the law was known earlier, it was first published in 1785 by French physicist Charles-Augustin de Coulomb, hence the name. Coulomb's law was essential to the development of the theory of electromagnetism, maybe even its starting point, as it made it possible to discuss the quantity of electric charge in a meaningful way. The law states that the magnitude of the electrostatic force of attraction or repulsion between two point charges is directly proportional to the product of the magnitudes of charges and inversely proportional to the square of the distance between them. Coulomb studied the repulsive force between bodies having electrical charges of the same sign: Coulomb also ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
