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Heavy Rydberg System
A heavy Rydberg system consists of a weakly bound positive and negative ion orbiting their common centre of mass. Such systems share many properties with the conventional Rydberg atom and consequently are sometimes referred to as heavy Rydberg atoms. While such a system is a type of ionically bound molecule, it should not be confused with a molecular Rydberg state, which is simply a molecule with one or more highly excited electrons. The peculiar properties of the Rydberg atom come from the large charge separation and the resulting hydrogenic potential. The extremely large separation between the two components of a heavy Rydberg system results in an almost perfect ''1/r'' hydrogenic potential seen by each ion. The positive ion can be viewed as analogous to the nucleus of a hydrogen atom, with the negative ion playing the role of the electron. Species The most commonly studied system to date is the H^+/H^- system, consisting of a proton bound with a H^- ion. The H^+/H^- system wa ...
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Rydberg Atom
A Rydberg atom is an excited atom with one or more electrons that have a very high principal quantum number, ''n''. The higher the value of ''n'', the farther the electron is from the nucleus, on average. Rydberg atoms have a number of peculiar properties including an exaggerated response to electric and magnetic fields, long decay periods and electron wavefunctions that approximate, under some conditions, classical orbits of electrons about the nuclei. The core electrons shield the outer electron from the electric field of the nucleus such that, from a distance, the electric potential looks identical to that experienced by the electron in a hydrogen atom. In spite of its shortcomings, the Bohr model of the atom is useful in explaining these properties. Classically, an electron in a circular orbit of radius ''r'', about a hydrogen nucleus of charge +'' e'', obeys Newton's second law: : \mathbf=m\mathbf \Rightarrow = where ''k'' = 1/(4π ε0). Orbital momentum is quantiz ...
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Diatomic
Diatomic molecules () are molecules composed of only two atoms, of the same or different chemical elements. If a diatomic molecule consists of two atoms of the same element, such as hydrogen () or oxygen (), then it is said to be homonuclear. Otherwise, if a diatomic molecule consists of two different atoms, such as carbon monoxide () or nitric oxide (), the molecule is said to be heteronuclear. The bond in a homonuclear diatomic molecule is non-polar. The only chemical elements that form stable homonuclear diatomic molecules at standard temperature and pressure (STP) (or typical laboratory conditions of 1 bar and 25 °C) are the gases hydrogen (), nitrogen (), oxygen (), fluorine (), and chlorine (). The noble gases (helium, neon, argon, krypton, xenon, and radon) are also gases at STP, but they are monatomic. The homonuclear diatomic gases and noble gases together are called "elemental gases" or "molecular gases", to distinguish them from other gases that are chemical ...
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Energy Level
A quantum mechanical system or particle that is bound—that is, confined spatially—can only take on certain discrete values of energy, called energy levels. This contrasts with classical particles, which can have any amount of energy. The term is commonly used for the energy levels of the electrons in atoms, ions, or molecules, which are bound by the electric field of the nucleus, but can also refer to energy levels of nuclei or vibrational or rotational energy levels in molecules. The energy spectrum of a system with such discrete energy levels is said to be quantized. In chemistry and atomic physics, an electron shell, or principal energy level, may be thought of as the orbit of one or more electrons around an atom's nucleus. The closest shell to the nucleus is called the " shell" (also called "K shell"), followed by the " shell" (or "L shell"), then the " shell" (or "M shell"), and so on farther and farther from the nucleus. The shells correspond with the principal quan ...
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Coulomb's Law
Coulomb's inverse-square law, or simply Coulomb's law, is an experimental law of physics that quantifies the amount of force between two stationary, electrically charged particles. The electric force between charged bodies at rest is conventionally called ''electrostatic force'' or Coulomb force. Although the law was known earlier, it was first published in 1785 by French physicist Charles-Augustin de Coulomb, hence the name. Coulomb's law was essential to the development of the theory of electromagnetism, maybe even its starting point, as it made it possible to discuss the quantity of electric charge in a meaningful way. The law states that the magnitude of the electrostatic force of attraction or repulsion between two point charges is directly proportional to the product of the magnitudes of charges and inversely proportional to the square of the distance between them. Coulomb studied the repulsive force between bodies having electrical charges of the same sign: Coulomb also ...
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Semi-major Axis
In geometry, the major axis of an ellipse is its longest diameter: a line segment that runs through the center and both foci, with ends at the two most widely separated points of the perimeter. The semi-major axis (major semiaxis) is the longest semidiameter or one half of the major axis, and thus runs from the centre, through a focus, and to the perimeter. The semi-minor axis (minor semiaxis) of an ellipse or hyperbola is a line segment that is at right angles with the semi-major axis and has one end at the center of the conic section. For the special case of a circle, the lengths of the semi-axes are both equal to the radius of the circle. The length of the semi-major axis of an ellipse is related to the semi-minor axis's length through the eccentricity and the semi-latus rectum \ell, as follows: The semi-major axis of a hyperbola is, depending on the convention, plus or minus one half of the distance between the two branches. Thus it is the distance from the center ...
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Kepler's Laws Of Planetary Motion
In astronomy, Kepler's laws of planetary motion, published by Johannes Kepler between 1609 and 1619, describe the orbits of planets around the Sun. The laws modified the heliocentric theory of Nicolaus Copernicus, replacing its circular orbits and epicycles with elliptical trajectories, and explaining how planetary velocities vary. The three laws state that: # The orbit of a planet is an ellipse with the Sun at one of the two foci. # A line segment joining a planet and the Sun sweeps out equal areas during equal intervals of time. # The square of a planet's orbital period is proportional to the cube of the length of the semi-major axis of its orbit. The elliptical orbits of planets were indicated by calculations of the orbit of Mars. From this, Kepler inferred that other bodies in the Solar System, including those farther away from the Sun, also have elliptical orbits. The second law helps to establish that when a planet is closer to the Sun, it travels faster. The third law ex ...
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Binding Energy
In physics and chemistry, binding energy is the smallest amount of energy required to remove a particle from a system of particles or to disassemble a system of particles into individual parts. In the former meaning the term is predominantly used in condensed matter physics, atomic physics, and chemistry, whereas in nuclear physics the term ''separation energy'' is used. A bound system is typically at a lower energy level than its unbound constituents. According to relativity theory, a decrease in the total energy of a system is accompanied by a decrease in the total mass, where . Types of binding energy There are several types of binding energy, each operating over a different distance and energy scale. The smaller the size of a bound system, the higher its associated binding energy. Mass–energy relation A bound system is typically at a lower energy level than its unbound constituents because its mass must be less than the total mass of its unbound constituents. For sys ...
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Reduced Mass
In physics, the reduced mass is the "effective" Mass#Inertial mass, inertial mass appearing in the two-body problem of Newtonian mechanics. It is a quantity which allows the two-body problem to be solved as if it were a one-body problem. Note, however, that the mass determining the gravitational force is ''not'' reduced. In the computation, one mass ''can'' be replaced with the reduced mass, if this is compensated by replacing the other mass with the sum of both masses. The reduced mass is frequently denoted by \mu (Mu (letter), mu), although the standard gravitational parameter is also denoted by \mu (as are Mu (letter)#Physics and engineering, a number of other physical quantities). It has the dimensional analysis, dimensions of mass, and SI unit kg. Equation Given two bodies, one with mass ''m''1 and the other with mass ''m''2, the equivalent one-body problem, with the position of one body with respect to the other as the unknown, is that of a single body of mass :\mu = \c ...
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Magnetic Field
A magnetic field is a vector field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to the magnetic field. A permanent magnet's magnetic field pulls on ferromagnetic materials such as iron, and attracts or repels other magnets. In addition, a nonuniform magnetic field exerts minuscule forces on "nonmagnetic" materials by three other magnetic effects: paramagnetism, diamagnetism, and antiferromagnetism, although these forces are usually so small they can only be detected by laboratory equipment. Magnetic fields surround magnetized materials, and are created by electric currents such as those used in electromagnets, and by electric fields varying in time. Since both strength and direction of a magnetic field may vary with location, it is described mathematically by a function assigning a vector to each point of space, cal ...
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Electric Field
An electric field (sometimes E-field) is the physical field that surrounds electrically charged particles and exerts force on all other charged particles in the field, either attracting or repelling them. It also refers to the physical field for a system of charged particles. Electric fields originate from electric charges and time-varying electric currents. Electric fields and magnetic fields are both manifestations of the electromagnetic field, one of the four fundamental interactions (also called forces) of nature. Electric fields are important in many areas of physics, and are exploited in electrical technology. In atomic physics and chemistry, for instance, the electric field is the attractive force holding the atomic nucleus and electrons together in atoms. It is also the force responsible for chemical bonding between atoms that result in molecules. The electric field is defined as a vector field that associates to each point in space the electrostatic ( Coulomb) for ...
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Bond Length
In molecular geometry, bond length or bond distance is defined as the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types, relatively independent of the rest of the molecule. Explanation Bond length is related to bond order: when more electrons participate in bond formation the bond is shorter. Bond length is also inversely related to bond strength and the bond dissociation energy: all other factors being equal, a stronger bond will be shorter. In a bond between two identical atoms, half the bond distance is equal to the covalent radius. Bond lengths are measured in the solid phase by means of X-ray diffraction, or approximated in the gas phase by microwave spectroscopy. A bond between a given pair of atoms may vary between different molecules. For example, the carbon to hydrogen bonds in methane are different from those in methyl chloride. It is however possible to make generalizations when ...
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Hydrogen-like Atom
A hydrogen-like atom (or hydrogenic atom) is any atom or ion with a single valence electron. These atoms are isoelectronic with hydrogen. Examples of hydrogen-like atoms include, but are not limited to, hydrogen itself, all alkali metals such as Rb and Cs, singly ionized alkaline earth metals such as Ca+ and Sr+ and other ions such as He+, Li2+, and Be3+ and isotopes of any of the above. A hydrogen-like atom includes a positively charged core consisting of the atomic nucleus and any core electrons as well as a single valence electron. Because helium is common in the universe, the spectroscopy of singly ionized helium is important in EUV astronomy, for example, of DO white dwarf stars. The non-relativistic Schrödinger equation and relativistic Dirac equation for the hydrogen atom can be solved analytically, owing to the simplicity of the two-particle physical system. The one-electron wave function solutions are referred to as ''hydrogen-like atomic orbitals''. Hydrogen-li ...
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