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Hamaker Constant
The Hamaker constant ''A'' can be defined for a van der Waals (vdW) body–body interaction: :A=\pi^2C\rho_1\rho_2, where \rho_1 and \rho_2 are the number densities of the two interacting kinds of particles, and ''C'' is the London coefficient in the particle–particle pair interaction. It is named after H. C. Hamaker. The magnitude of this constant reflects the strength of the vdW-force between two particles, or between a particle and a substrate. The Hamaker constant provides the means to determine the interaction parameter ''C'' from the vdW-pair potential, w(r) = -C/r^6. Hamaker's method and the associated Hamaker constant ignores the influence of an intervening medium between the two particles of interaction. In 1956 Lifshitz developed a description of the vdW energy but with consideration of the dielectric properties of this intervening medium (often a continuous phase). The Van der Waals forces are effective only up to several hundred angstroms. When the interactions ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Number Density
The number density (symbol: ''n'' or ''ρ''N) is an intensive quantity used to describe the degree of concentration of countable objects (particles, molecules, phonons, cells, galaxies, etc.) in physical space: three-dimensional volumetric number density, two-dimensional areal number density, or one-dimensional linear number density. ''Population density'' is an example of areal number density. The term number concentration (symbol: lowercase ''n'', or ''C'', to avoid confusion with amount of substance indicated by uppercase '' N'') is sometimes used in chemistry for the same quantity, particularly when comparing with other concentrations. Definition Volume number density is the number of specified objects per unit volume: :n = \frac, where ''N'' is the total number of objects in a volume ''V''. Here it is assumed that ''N'' is large enough that rounding of the count to the nearest integer does not introduce much of an error, however ''V'' is chosen to be small enough t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Van Der Waals Forces
In molecular physics, the van der Waals force is a distance-dependent interaction between atoms or molecules. Unlike ionic or covalent bonds, these attractions do not result from a chemical electronic bond; they are comparatively weak and therefore more susceptible to disturbance. The van der Waals force quickly vanishes at longer distances between interacting molecules. Named after Dutch physicist Johannes Diderik van der Waals, the van der Waals force plays a fundamental role in fields as diverse as supramolecular chemistry, structural biology, polymer science, nanotechnology, surface science, and condensed matter physics. It also underlies many properties of organic compounds and molecular solids, including their solubility in polar and non-polar media. If no other force is present, the distance between atoms at which the force becomes repulsive rather than attractive as the atoms approach one another is called the van der Waals contact distance; this phenomenon result ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Angstrom
The angstromEntry "angstrom" in the Oxford online dictionary. Retrieved on 2019-03-02 from https://en.oxforddictionaries.com/definition/angstrom.Entry "angstrom" in the Merriam-Webster online dictionary. Retrieved on 2019-03-02 from https://www.merriam-webster.com/dictionary/angstrom. (, ; , ) or ångström is a metric unit of length equal to m; that is, one ten-billionth ( US) of a metre, a hundred-millionth of a centimetre,Entry "angstrom" in the Oxford English Dictionary, 2nd edition (1986). Retrieved on 2021-11-22 from https://www.oed.com/oed2/00008552. 0.1 nanometre, or 100 picometres. Its symbol is Å, a letter of the Swedish alphabet. The unit is named after the Swedish physicist Anders Jonas Ångström (1814–1874). The angstrom is often used in the natural sciences and technology to express sizes of atoms, molecules, microscopic biological structures, and lengths of chemical bonds, arrangement of atoms in crystals,Arturas Vailionis (2015):Geometry of Crystals L ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Retarded Potential
In electrodynamics, the retarded potentials are the electromagnetic potentials for the electromagnetic field generated by time-varying electric current or charge distributions in the past. The fields propagate at the speed of light ''c'', so the delay of the fields connecting cause and effect at earlier and later times is an important factor: the signal takes a finite time to propagate from a point in the charge or current distribution (the point of cause) to another point in space (where the effect is measured), see figure below. In the Lorenz gauge The starting point is Maxwell's equations in the potential formulation using the Lorenz gauge: : \Box \varphi = \dfrac \,,\quad \Box \mathbf = \mu_0\mathbf where φ(r, ''t'') is the electric potential and A(r, ''t'') is the magnetic vector potential, for an arbitrary source of charge density ρ(r, ''t'') and current density J(r, ''t''), and \Box is the D'Alembert operator. Solving these gives the retarded potentials below (al ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Casimir–Polder Force
In quantum field theory, the Casimir effect is a physical force acting on the macroscopic boundaries of a confined space which arises from the quantum fluctuations of the field. It is named after the Dutch physicist Hendrik Casimir, who predicted the effect for electromagnetic systems in 1948. In the same year, Casimir together with Dirk Polder described a similar effect experienced by a neutral atom in the vicinity of a macroscopic interface which is referred to as the Casimir–Polder force. Their result is a generalization of the London–van der Waals force and includes retardation due to the finite speed of light. Since the fundamental principles leading to the London–van der Waals force, the Casimir and the Casimir–Polder force, respectively, can be formulated on the same footing, the distinction in nomenclature nowadays serves a historical purpose mostly and usually refers to the different physical setups. It was not until 1997 that a direct experiment by S. Lamore ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hamaker Theory
After the explanation of van der Waals forces by Fritz London, several scientists soon realised that his definition could be extended from the interaction of two molecules with induced dipoles to macro-scale objects by summing all of the forces between the molecule A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and b ...s in each of the bodies involved. The theory is named after H. C. Hamaker, who derived the interaction between two spheres, a sphere and a wall, and presented a general discussion in a heavily cited 1937 paper.Hamaker, H. C. (1937) The London – van der Waals attraction between spherical particles. ''Physica'' 4(''10''), 1058–1072. The interaction of two bodies is then treated as the pairwise interaction of a set of ''N'' molecules at positions: ''Ri'' . The distance b ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Intermolecular Forces
An intermolecular force (IMF) (or secondary force) is the force that mediates interaction between molecules, including the electromagnetic forces of attraction or repulsion which act between atoms and other types of neighbouring particles, e.g. atoms or ions. Intermolecular forces are weak relative to intramolecular forces – the forces which hold a molecule together. For example, the covalent bond, involving sharing electron pairs between atoms, is much stronger than the forces present between neighboring molecules. Both sets of forces are essential parts of force fields frequently used in molecular mechanics. The investigation of intermolecular forces starts from macroscopic observations which indicate the existence and action of forces at a molecular level. These observations include non-ideal-gas thermodynamic behavior reflected by virial coefficients, vapor pressure, viscosity, superficial tension, and absorption data. The first reference to the nature of microscopic fo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Van Der Waals Forces
In molecular physics, the van der Waals force is a distance-dependent interaction between atoms or molecules. Unlike ionic or covalent bonds, these attractions do not result from a chemical electronic bond; they are comparatively weak and therefore more susceptible to disturbance. The van der Waals force quickly vanishes at longer distances between interacting molecules. Named after Dutch physicist Johannes Diderik van der Waals, the van der Waals force plays a fundamental role in fields as diverse as supramolecular chemistry, structural biology, polymer science, nanotechnology, surface science, and condensed matter physics. It also underlies many properties of organic compounds and molecular solids, including their solubility in polar and non-polar media. If no other force is present, the distance between atoms at which the force becomes repulsive rather than attractive as the atoms approach one another is called the van der Waals contact distance; this phenomenon result ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Physical Chemistry
Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mechanics, analytical dynamics and chemical equilibria. Physical chemistry, in contrast to chemical physics, is predominantly (but not always) a supra-molecular science, as the majority of the principles on which it was founded relate to the bulk rather than the molecular or atomic structure alone (for example, chemical equilibrium and colloids). Some of the relationships that physical chemistry strives to resolve include the effects of: # Intermolecular forces that act upon the physical properties of materials ( plasticity, tensile strength, surface tension in liquids). # Reaction kinetics on the rate of a reaction. # The identity of ions and the electrical conductivity of materials. # Surface science and electrochemistry of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
