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Grüneisen Parameter
The Grüneisen parameter, γ, named after Eduard Grüneisen, describes the effect that changing the volume of a crystal lattice has on its vibrational properties, and, as a consequence, the effect that changing temperature has on the size or dynamics of the crystal lattice. The term is usually reserved to describe the single thermodynamic property , which is a weighted average of the many separate parameters entering Grüneisen's original formulation in terms of the phonon nonlinearities. Thermodynamic definitions Because of the equivalences between many properties and derivatives within thermodynamics (e.g. see Maxwell Relations), there are many formulations of the Grüneisen parameter which are equally valid, leading to numerous distinct yet correct interpretations of its meaning. Some formulations for the Grüneisen parameter include: \gamma = V \left(\frac\right)_V = \frac = \frac = \frac = -\left(\frac\right)_S where is volume, C_P and C_V are the principal (i.e. per-mass) ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Eduard Grüneisen
Eduard Grüneisen (26 May 1877 – 5 April 1949) was a German physicist and the co-eponym of Mie–Grüneisen equation of state. Grüneisen was born in Giebichenstein, near Halle (Saale). The Grüneisen parameter was named after him. Since 1929 he was together with Max Planck editor of ''Annalen der Physik''. In 1933 Grüneisen signed the ''Vow of allegiance of the Professors of the German Universities and High-Schools to Adolf Hitler and the National Socialistic State''. Grüneisen died in Marburg Marburg ( or ) is a university town in the German federal state (''Bundesland'') of Hesse, capital of the Marburg-Biedenkopf district (''Landkreis''). The town area spreads along the valley of the river Lahn and has a population of approximate ..., West Germany. References 1877 births 1949 deaths 20th-century German physicists {{Germany-physicist-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Negative Thermal Expansion
Negative thermal expansion (NTE) is an unusual physicochemical process in which some materials contract upon heating, rather than expand as most other materials do. The most well-known material with NTE is water at 0~4 °C. Water's NTE is the reason why ice floats, rather than sinks, in liquid water. Materials which undergo NTE have a range of potential engineering, photonic, electronic, and structural applications. For example, if one were to mix a negative thermal expansion material with a "normal" material which expands on heating, it could be possible to use it as a thermal expansion compensator what might allow for forming composites with tailored or even close to zero thermal expansion. Origin of negative thermal expansion There are a number of physical processes which may cause contraction with increasing temperature, including transverse vibrational modes, rigid unit modes and phase transitions. In 2011, Liu et al. showed that the NTE phenomenon originates from the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mie–Grüneisen Equation Of State
The Mie–Grüneisen equation of state is an equation of state that relates the pressure and volume of a solid at a given temperature.Roberts, J. K., & Miller, A. R. (1954). Heat and thermodynamics (Vol. 4). Interscience Publishers.Burshtein, A. I. (2008). Introduction to thermodynamics and kinetic theory of matter. Wiley-VCH. It is used to determine the pressure in a shock-compressed solid. The Mie–Grüneisen relation is a special form of the Grüneisen model which describes the effect that changing the volume of a crystal lattice has on its vibrational properties. Several variations of the Mie–Grüneisen equation of state are in use. The Grüneisen model can be expressed in the form :\Gamma = V \left(\frac\right)_V where is the volume, is the pressure, is the internal energy, and is the Grüneisen parameter which represents the thermal pressure from a set of vibrating atoms. If we assume that is independent of and , we can integrate Grüneisen's model to get : p - ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Debye Model
In thermodynamics and solid-state physics, the Debye model is a method developed by Peter Debye in 1912 for estimating the phonon contribution to the specific heat (Heat capacity) in a solid. It treats the vibrations of the atomic lattice (heat) as phonons in a box, in contrast to the Einstein photoelectron model, which treats the solid as many individual, non-interacting quantum harmonic oscillators. The Debye model correctly predicts the low-temperature dependence of the heat capacity of solids, which is proportional to T^3 – the Debye ''T'' 3 law. Just like the Einstein photoelectron model, it also recovers the Dulong–Petit law at high temperatures. But due to simplifying assumptions, its accuracy suffers at intermediate temperatures. Derivation The Debye model is a solid-state equivalent of Planck's law of black body photon radiation, where one treats electromagnetic photonic radiation as a photon gas. The Debye model treats atomic vibrations as phonons in a box ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Maxwell Relations
file:Thermodynamic map.svg, 400px, Flow chart showing the paths between the Maxwell relations. P is pressure, T temperature, V volume, S entropy, \alpha coefficient of thermal expansion, \kappa compressibility, C_V heat capacity at constant volume, C_P heat capacity at constant pressure. Maxwell's relations are a set of equations in thermodynamics which are derivable from the symmetry of second derivatives and from the definitions of the thermodynamic potentials. These relations are named for the nineteenth-century physicist James Clerk Maxwell. Equations The structure of Maxwell relations is a statement of equality among the second derivatives for continuous functions. It follows directly from the fact that the order of differentiation of an analytic function of two variables is irrelevant ( Schwarz theorem). In the case of Maxwell relations the function considered is a thermodynamic potential and x_i and x_j are two different natural variables for that potential, we have ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Phonons
In physics, a phonon is a collective excitation in a periodic, elastic arrangement of atoms or molecules in condensed matter, specifically in solids and some liquids. A type of quasiparticle, a phonon is an excited state in the quantum mechanical quantization of the modes of vibrations for elastic structures of interacting particles. Phonons can be thought of as quantized sound waves, similar to photons as quantized light waves. The study of phonons is an important part of condensed matter physics. They play a major role in many of the physical properties of condensed matter systems, such as thermal conductivity and electrical conductivity, as well as in models of neutron scattering and related effects. The concept of phonons was introduced in 1932 by Soviet physicist Igor Tamm. The name ''phonon'' comes from the Greek word (), which translates to ''sound'' or ''voice'', because long-wavelength phonons give rise to sound. The name is analogous to the word ''photon''. Definiti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quasi-harmonic Approximation
The quasi-harmonic approximation is a phonon-based model of solid-state physics used to describe volume-dependent thermal effects, such as the thermal expansion. It is based on the assumption that the harmonic approximation holds for every value of the lattice constant, which is to be viewed as an adjustable parameter. Overview The quasi-harmonic approximation expands upon the harmonic phonon model of lattice dynamics. The harmonic phonon model states that all interatomic forces are purely harmonic, but such a model is inadequate to explain thermal expansion, as the equilibrium distance between atoms in such a model is independent of temperature. Thus in the quasi-harmonic model, from a phonon point of view, phonon frequencies become volume-dependent in the quasi-harmonic approximation, such that for each volume, the harmonic approximation holds. Thermodynamics For a lattice, the Helmholtz free energy ''F'' in the quasi-harmonic approximation is F(T,V) = E_(V) + U_(T,V) - T S ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Proportionality (mathematics)
In mathematics, two sequences of numbers, often experimental data, are proportional or directly proportional if their corresponding elements have a constant ratio, which is called the coefficient of proportionality or proportionality constant. Two sequences are inversely proportional if corresponding elements have a constant product, also called the coefficient of proportionality. This definition is commonly extended to related varying quantities, which are often called ''variables''. This meaning of ''variable'' is not the common meaning of the term in mathematics (see variable (mathematics)); these two different concepts share the same name for historical reasons. Two functions f(x) and g(x) are ''proportional'' if their ratio \frac is a constant function. If several pairs of variables share the same direct proportionality constant, the equation expressing the equality of these ratios is called a proportion, e.g., (for details see Ratio). Proportionality is closely rela ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Morse Potential
The Morse potential, named after physicist Philip M. Morse, is a convenient interatomic interaction model for the potential energy of a diatomic molecule. It is a better approximation for the vibrational structure of the molecule than the quantum harmonic oscillator because it explicitly includes the effects of bond breaking, such as the existence of unbound states. It also accounts for the anharmonicity of real bonds and the non-zero transition probability for overtone and combination bands. The Morse potential can also be used to model other interactions such as the interaction between an atom and a surface. Due to its simplicity (only three fitting parameters), it is not used in modern spectroscopy. However, its mathematical form inspired the MLR ( Morse/Long-range) potential, which is the most popular potential energy function used for fitting spectroscopic data. Potential energy function The Morse potential energy function is of the form :V(r) = D_e ( 1-e^ )^2 Here r is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Crystal Lattice
In geometry and crystallography, a Bravais lattice, named after , is an infinite array of discrete points generated by a set of discrete translation operations described in three dimensional space by : \mathbf = n_1 \mathbf_1 + n_2 \mathbf_2 + n_3 \mathbf_3, where the ''ni'' are any integers, and a''i'' are ''primitive translation vectors'', or ''primitive vectors'', which lie in different directions (not necessarily mutually perpendicular) and span the lattice. The choice of primitive vectors for a given Bravais lattice is not unique. A fundamental aspect of any Bravais lattice is that, for any choice of direction, the lattice appears exactly the same from each of the discrete lattice points when looking in that chosen direction. The Bravais lattice concept is used to formally define a ''crystalline arrangement'' and its (finite) frontiers. A crystal is made up of one or more atoms, called the ''basis'' or ''motif'', at each lattice point. The ''basis'' may consist of atoms, mo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lennard-Jones Potential
The Lennard-Jones potential (also termed the LJ potential or 12-6 potential) is an intermolecular pair potential. Out of all the intermolecular potentials, the Lennard-Jones potential is probably the one that has been the most extensively studied. It is considered an archetype model for simple yet realistic intermolecular interactions. The Lennard-Jones potential models soft repulsive and attractive ( van der Waals) interactions. Hence, the Lennard-Jones potential describes electronically neutral atoms or molecules. It is named after John Lennard-Jones. The commonly used expression for the Lennard-Jones potential is V_\text(r) = 4\varepsilon \left \left(\frac\right)^ - \left(\frac\right)^6 \right, where r is the distance between two interacting particles, \varepsilon is the depth of the potential well (usually referred to as 'dispersion energy'), and \sigma is the distance at which the particle-particle potential energy V is zero (often referred to as 'size of the particle'). The ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
