Fractional Crystallisation (geology)
Fractional crystallization, or crystal fractionation, is one of the most important geochemical and physical processes operating within crust and mantle of a rocky planetary body, such as the Earth. It is important in the formation of igneous rocks because it is one of the main processes of magmatic differentiation. Fractional crystallization is also important in the formation of sedimentary evaporite rocks. Igneous rocks Fractional crystallization is the removal and segregation from a melt of mineral precipitates; except in special cases, removal of the crystals changes the composition of the magma. In essence, fractional crystallization is the removal of early formed crystals from an originally homogeneous magma (for example, by gravity settling) so that these crystals are prevented from further reaction with the residual melt. The composition of the remaining melt becomes relatively depleted in some components and enriched in others, resulting in the precipitation of a sequenc ...
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Fractional Crystallization
Fractional crystallization may refer to: * Fractional crystallization (chemistry), a process to separate different solutes from a solution * Fractional crystallization (geology) Fractional crystallization, or crystal fractionation, is one of the most important geochemical and physical processes operating within crust and mantle of a rocky planetary body, such as the Earth. It is important in the formation of igneous roc ...

Incompatible Element
In petrology and geochemistry, an incompatible element is one that is unsuitable in size and/or charge to the cation sites of the minerals of which it is included. It is defined by the partition coefficient between rock-forming minerals and melt being much smaller than 1. During the fractional crystallization of magma and magma generation by the partial melting of the Earth's mantle and crust, elements that have difficulty in entering cation sites of the minerals are concentrated in the melt phase of magma (liquid phase). Two groups of incompatible elements that have difficulty entering the solid phase are known by acronyms. One group includes elements having large ionic radius, such as potassium, rubidium, caesium, strontium, barium (called LILE, or large-ion lithophile elements), and the other group includes elements of large ionic valences (or high charges), such as zirconium, niobium, hafnium, rare-earth elements (REE), thorium, uranium and tantalum Tantalum is a chemi ...
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Feldspar
Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feldspars and the ''alkali'' (potassium-sodium) feldspars. Feldspars make up about 60% of the Earth's crust, and 41% of the Earth's continental crust by weight. Feldspars crystalize from magma as both intrusive and extrusive igneous rocks and are also present in many types of metamorphic rock. Rock formed almost entirely of calcic plagioclase feldspar is known as anorthosite. Feldspars are also found in many types of sedimentary rocks. Compositions The feldspar group of minerals consists of tectosilicates, silicate minerals in which silicon ions are linked by shared oxygen ions to form a three-dimensional network. Compositions of major elements in common feldspars can be expressed in terms of three endmembers: * potassium feldspar ...
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Pyroxene
The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe II) or magnesium (Mg) and more rarely zinc, manganese or lithium, and Y represents ions of smaller size, such as chromium (Cr), aluminium (Al), magnesium (Mg), cobalt (Co), manganese (Mn), scandium (Sc), titanium (Ti), vanadium (V) or even iron (Fe II) or (Fe III). Although aluminium substitutes extensively for silicon in silicates such as feldspars and amphiboles, the substitution occurs only to a limited extent in most pyroxenes. They share a common structure consisting of single chains of silica tetrahedra. Pyroxenes that crystallize in the monoclinic system are known as clinopyroxenes and those that crystallize in the orthorhombic system are known as orthopyroxenes. The name ''pyroxene'' is derived from the Ancient Greek words for 'fire' ( ...
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Enstatite
Enstatite is a mineral; the magnesium endmember of the pyroxene silicate mineral series enstatite (MgSiO3) – ferrosilite (FeSiO3). The magnesium rich members of the solid solution series are common rock-forming minerals found in igneous and metamorphic rocks. The intermediate composition, , has historically been known as hypersthene, although this name has been formally abandoned and replaced by orthopyroxene. When determined petrographically or chemically the composition is given as relative proportions of enstatite (En) and ferrosilite (Fs) (e.g., En80Fs20). Polymorphs and varieties Most natural crystals are orthorhombic ( space group P''bca'') although three polymorphs are known. The high temperature, low pressure polymorphs are protoenstatite and protoferrosilite (also orthorhombic, space group P''bcn'') while the low temperature forms, clinoenstatite and clinoferrosilite, are monoclinic (space group P2''1/c''). Weathered enstatite with a small amount of iron ...
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Olivine
The mineral olivine () is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers quickly on the surface. For this reason, olivine has been proposed as a good candidate for accelerated weathering to sequester carbon dioxide from the Earth's oceans and atmosphere, as part of climate change mitigation. Olivine also has many other historical uses, such as the gemstone peridot (or chrysolite), as well as industrial applications like metalworking processes. The ratio of magnesium to iron varies between the two endmembers of the solid solution series: forsterite (Mg-endmember: ) and fayalite (Fe-endmember: ). Compositions of olivine are commonly expressed as molar percentages of forsterite (Fo) and fayalite (Fa) (''e.g.'', Fo70Fa30). Forsterite's melting temperature is unusually high at atmospheric pressure, almost , whi ...
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Forsterite
Forsterite (Mg2SiO4; commonly abbreviated as Fo; also known as white olivine) is the magnesium-rich end-member of the olivine solid solution series. It is isomorphous with the iron-rich end-member, fayalite. Forsterite crystallizes in the orthorhombic system ( space group ''Pbnm'') with cell parameters ''a'' 4.75 Å (0.475 nm), ''b'' 10.20 Å (1.020 nm) and ''c'' 5.98 Å (0.598 nm). Forsterite is associated with igneous and metamorphic rocks and has also been found in meteorites. In 2005 it was also found in cometary dust returned by the Stardust probe. In 2011 it was observed as tiny crystals in the dusty clouds of gas around a forming star. Two polymorphs of forsterite are known: wadsleyite (also orthorhombic) and ringwoodite (isometric, Cubic crystal system). Both are mainly known from meteorites. Peridot is the gemstone variety of forsterite olivine. Composition Pure forsterite is composed of magnesium, oxygen and silicon. The chemical formula is Mg2 ...
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Ultramafic
Ultramafic rocks (also referred to as ultrabasic rocks, although the terms are not wholly equivalent) are igneous and meta-igneous rocks with a very low silica content (less than 45%), generally >18% MgO, high FeO, low potassium, and are composed of usually greater than 90% mafic minerals (dark colored, high magnesium and iron content). The Earth's mantle is composed of ultramafic rocks. Ultrabasic is a more inclusive term that includes igneous rocks with low silica content that may not be extremely enriched in Fe and Mg, such as carbonatites and ultrapotassic igneous rocks. Intrusive ultramafic rocks Intrusive ultramafic rocks are often found in large, layered ultramafic intrusions where differentiated rock types often occur in layers. Such cumulate rock types do not represent the chemistry of the magma from which they crystallized. The ultramafic intrusives include the dunites, peridotites and pyroxenites. Other rare varieties include troctolite which has a great ...
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