Forouhi–Bloomer Model
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Forouhi–Bloomer Model
The Forouhi–Bloomer model is a mathematical formula for the frequency dependence of the complex-valued refractive index. The model can be used to fit the refractive index of amorphous and crystalline semiconductor and dielectric materials at energies near and greater than their optical band gap. The dispersion relation bears the names of Rahim Forouhi and Iris Bloomer, who created the model and interpreted the physical significance of its parameters. The model is aphysical due to its incorrect asymptotic behavior and non-Hermitian character. These shortcomings inspired modified versions of the model as well as development of the Tauc–Lorentz model. Mathematical Formulation The complex refractive index is given by : \tilde(E) = n(E) + i \kappa(E) where * n is the real component of the complex refractive index, commonly called the refractive index, * \kappa is the imaginary component of the complex refractive index, commonly called the extinction coefficient, * E is the p ...
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Refractive Index
In optics, the refractive index (or refraction index) of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium. The refractive index determines how much the path of light is bent, or refracted, when entering a material. This is described by Snell's law of refraction, , where ''θ''1 and ''θ''2 are the angle of incidence and angle of refraction, respectively, of a ray crossing the interface between two media with refractive indices ''n''1 and ''n''2. The refractive indices also determine the amount of light that is reflected when reaching the interface, as well as the critical angle for total internal reflection, their intensity ( Fresnel's equations) and Brewster's angle. The refractive index can be seen as the factor by which the speed and the wavelength of the radiation are reduced with respect to their vacuum values: the speed of light in a medium is , and similarly the wavelength in that medium is , where ''Π...
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Band Gap
In solid-state physics, a band gap, also called an energy gap, is an energy range in a solid where no electronic states can exist. In graphs of the electronic band structure of solids, the band gap generally refers to the energy difference (in electron volts) between the top of the valence band and the bottom of the conduction band in insulators and semiconductors. It is the energy required to promote a valence electron bound to an atom to become a conduction electron, which is free to move within the crystal lattice and serve as a charge carrier to conduct electric current. It is closely related to the HOMO/LUMO gap in chemistry. If the valence band is completely full and the conduction band is completely empty, then electrons cannot move within the solid because there are no available states. If the electrons are not free to move within the crystal lattice, then there is no generated current due to no net charge carrier mobility. However, if some electrons transfer fr ...
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Dispersion Relation
In the physical sciences and electrical engineering, dispersion relations describe the effect of dispersion on the properties of waves in a medium. A dispersion relation relates the wavelength or wavenumber of a wave to its frequency. Given the dispersion relation, one can calculate the phase velocity and group velocity of waves in the medium, as a function of frequency. In addition to the geometry-dependent and material-dependent dispersion relations, the overarching Kramers–Kronig relations describe the frequency dependence of wave propagation and attenuation. Dispersion may be caused either by geometric boundary conditions ( waveguides, shallow water) or by interaction of the waves with the transmitting medium. Elementary particles, considered as matter waves, have a nontrivial dispersion relation even in the absence of geometric constraints and other media. In the presence of dispersion, wave velocity is no longer uniquely defined, giving rise to the distinction o ...
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Hermitian Function
In mathematical analysis, a Hermitian function is a complex function with the property that its complex conjugate is equal to the original function with the variable changed in sign: :f^*(x) = f(-x) (where the ^* indicates the complex conjugate) for all x in the domain of f. In physics, this property is referred to as PT symmetry. This definition extends also to functions of two or more variables, e.g., in the case that f is a function of two variables it is Hermitian if :f^*(x_1, x_2) = f(-x_1, -x_2) for all pairs (x_1, x_2) in the domain of f. From this definition it follows immediately that: f is a Hermitian function if and only if * the real part of f is an even function, * the imaginary part of f is an odd function. Motivation Hermitian functions appear frequently in mathematics, physics, and signal processing. For example, the following two statements follow from basic properties of the Fourier transform: * The function f is real-valued if and only if the Fourie ...
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Tauc–Lorentz Model
The Tauc–Lorentz model is a mathematical formula for the frequency dependence of the complex-valued relative permittivity, sometimes referred to as the dielectric function. The model has been used to fit the complex refractive index of amorphous semiconductor materials at frequencies greater than their optical band gap. The dispersion relation bears the names of Jan Tauc and Hendrik Lorentz, whose previous works were combined by G. E. Jellison and F. A. Modine to create the model. The model was inspired, in part, by shortcomings of the Forouhi–Bloomer model, which is aphysical due to its incorrect asymptotic behavior and non-Hermitian character. Despite the inspiration, the Tauc–Lorentz model is itself aphysical due to being non-Hermitian and non-analytic in the upper half-plane. Further researchers have modified the model to address these shortcomings. Mathematical formulation The general form of the model is given by :\varepsilon(E) = \varepsilon_ + \chi^(E) where * \ ...
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Photon Energy
Photon energy is the energy carried by a single photon. The amount of energy is directly proportional to the photon's electromagnetic frequency and thus, equivalently, is inversely proportional to the wavelength. The higher the photon's frequency, the higher its energy. Equivalently, the longer the photon's wavelength, the lower its energy. Photon energy can be expressed using any unit of energy. Among the units commonly used to denote photon energy are the electronvolt (eV) and the joule (as well as its multiples, such as the microjoule). As one joule equals 6.24 × 1018 eV, the larger units may be more useful in denoting the energy of photons with higher frequency and higher energy, such as gamma rays, as opposed to lower energy photons as in the optical and radio frequency regions of the electromagnetic spectrum. Formulas Physics Photon energy is directly proportional to frequency. E = hf where *E is energy *h is the Planck constant * f is frequency This equation is kno ...
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Angular Frequency
In physics, angular frequency "''ω''" (also referred to by the terms angular speed, circular frequency, orbital frequency, radian frequency, and pulsatance) is a scalar measure of rotation rate. It refers to the angular displacement per unit time (for example, in rotation) or the rate of change of the phase of a sinusoidal waveform (for example, in oscillations and waves), or as the rate of change of the argument of the sine function. Angular frequency (or angular speed) is the magnitude of the pseudovector quantity angular velocity.(UP1) One turn is equal to 2''Ï€'' radians, hence \omega = \frac = , where: *''ω'' is the angular frequency (unit: radians per second), *''T'' is the period (unit: seconds), *''f'' is the ordinary frequency (unit: hertz) (sometimes ''ν''). Units In SI units, angular frequency is normally presented in radians per second, even when it does not express a rotational value. The unit hertz (Hz) is dimensionally equivalent, but by conventi ...
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Cauchy Principal Value
In mathematics, the Cauchy principal value, named after Augustin Louis Cauchy, is a method for assigning values to certain improper integrals which would otherwise be undefined. Formulation Depending on the type of singularity in the integrand , the Cauchy principal value is defined according to the following rules: In some cases it is necessary to deal simultaneously with singularities both at a finite number and at infinity. This is usually done by a limit of the form \lim_\, \lim_ \,\left ,\int_^ f(x)\,\mathrmx \,~ + ~ \int_^ f(x)\,\mathrmx \,\right In those cases where the integral may be split into two independent, finite limits, \lim_ \, \left, \,\int_a^ f(x)\,\mathrmx \,\\; < \;\infty and \lim_\;\left, \,\int_^c f(x)\,\mathrmx \,\ \; < \; \infty , then the function is integrable in the ordinary sense. The result of the procedure for principal value is the same as the ordinary integral; since it no longer matches the definition, ...
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Cauchy's Equation
In optics, Cauchy's transmission equation is an empirical relationship between the refractive index and wavelength of light for a particular transparent material. It is named for the mathematician Augustin-Louis Cauchy, who defined it in 1837. The equation The most general form of Cauchy's equation is : n(\lambda) = A + \frac + \frac + \cdots, where ''n'' is the refractive index, λ is the wavelength, ''A'', ''B'', ''C'', etc., are coefficients that can be determined for a material by fitting the equation to measured refractive indices at known wavelengths. The coefficients are usually quoted for λ as the vacuum wavelength in micrometres. Usually, it is sufficient to use a two-term form of the equation: : n(\lambda) = A + \frac, where the coefficients ''A'' and ''B'' are determined specifically for this form of the equation. A table of coefficients for common optical materials is shown below: The theory of light-matter interaction on which Cauchy based this equati ...
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Sellmeier Equation
The Sellmeier equation is an empirical relationship between refractive index and wavelength for a particular transparent medium. The equation is used to determine the dispersion of light in the medium. It was first proposed in 1872 by Wolfgang Sellmeier and was a development of the work of Augustin Cauchy on Cauchy's equation for modelling dispersion. The equation In its original and the most general form, the Sellmeier equation is given as : n^2(\lambda) = 1 + \sum_i \frac , where ''n'' is the refractive index, ''λ'' is the wavelength, and ''B''i and ''C''i are experimentally determined ''Sellmeier coefficients''. These coefficients are usually quoted for λ in micrometres. Note that this λ is the vacuum wavelength, not that in the material itself, which is λ/n. A different form of the equation is sometimes used for certain types of materials, e.g. crystals. Each term of the sum representing an absorption resonance of strength ''B''i at a wavelength . For example, the ...
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