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Fundamental Series
The fundamental series is a set of spectral lines in a set caused by transition between d and f orbitals in atoms. Originally the series was discovered in the infrared by Fowler and independently by Arno Bergmann. This resulted in the name Bergmann series used for such a set of lines in a spectrum. However the name was changed as Bergmann also discovered other series of lines. And other discoverers also established other such series. They became known as the fundamental series. Bergmann observed lithium at 5347 cm−1, sodium at 5416 cm−1 potassium at 6592 cm−1. Bergmann observed that the lines in the series in the caesium spectrum were double. His discovery was announced in ''Contributions to the Knowledge of the Infra-Red Emission Spectra of the Alkalies'', Jena 1907. Carl Runge called this series the "new series". He predicted that the lines of potassium and rubidium would be in pairs. He expressed the frequencies of the series lines by a formula and pred ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spectral Line
A spectral line is a dark or bright line in an otherwise uniform and continuous spectrum, resulting from emission or absorption of light in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to identify atoms and molecules. These "fingerprints" can be compared to the previously collected ones of atoms and molecules, and are thus used to identify the atomic and molecular components of stars and planets, which would otherwise be impossible. Types of line spectra Spectral lines are the result of interaction between a quantum system (usually atoms, but sometimes molecules or atomic nuclei) and a single photon. When a photon has about the right amount of energy (which is connected to its frequency) to allow a change in the energy state of the system (in the case of an atom this is usually an electron changing orbitals), the photon is absorbed. Then the energy will be spontaneously re-emitted, either as one photon at the same frequenc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atomic Orbital
In atomic theory and quantum mechanics, an atomic orbital is a function describing the location and wave-like behavior of an electron in an atom. This function can be used to calculate the probability of finding any electron of an atom in any specific region around the atom's nucleus. The term ''atomic orbital'' may also refer to the physical region or space where the electron can be calculated to be present, as predicted by the particular mathematical form of the orbital. Each orbital in an atom is characterized by a set of values of the three quantum numbers , , and , which respectively correspond to the electron's energy, angular momentum, and an angular momentum vector component (magnetic quantum number). Alternative to the magnetic quantum number, the orbitals are often labeled by the associated harmonic polynomials (e.g., ''xy'', ). Each such orbital can be occupied by a maximum of two electrons, each with its own projection of spin m_s. The simple names s orbital, p orb ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Arno Bergmann
The Arno is a river in the Tuscany region of Italy. It is the most important river of central Italy after the Tiber. Source and route The river originates on Monte Falterona in the Casentino area of the Apennines, and initially takes a southward curve. The river turns to the west near Arezzo passing through Florence, Empoli and Pisa, flowing into the Tyrrhenian Sea at Marina di Pisa. With a length of , it is the largest river in the region. It has many tributaries: Sieve at long, Bisenzio at , Ombrone Pistoiese at , and the Era, Elsa, Pesa, and Pescia. The drainage basin amounts to more than and drains the waters of the following subbasins: *The Casentino, in the province of Arezzo, formed by the upper course of the river until its confluence with the Maestro della Chiana channel. *The Val di Chiana, a plain drained in the 18th century, which until then had been a marshy area tributary of the Tiber. *The upper Valdarno, a long valley bordered on the east by the Pratoma ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
CRC Press
The CRC Press, LLC is an American publishing group that specializes in producing technical books. Many of their books relate to engineering, science and mathematics. Their scope also includes books on business, forensics and information technology. CRC Press is now a division of Taylor & Francis, itself a subsidiary of Informa. History The CRC Press was founded as the Chemical Rubber Company (CRC) in 1903 by brothers Arthur, Leo and Emanuel Friedman in Cleveland, Ohio, based on an earlier enterprise by Arthur, who had begun selling rubber laboratory aprons in 1900. The company gradually expanded to include sales of laboratory equipment to chemists. In 1913 the CRC offered a short (116-page) manual called the ''Rubber Handbook'' as an incentive for any purchase of a dozen aprons. Since then the ''Rubber Handbook'' has evolved into the CRC's flagship book, the '' CRC Handbook of Chemistry and Physics''. In 1964, Chemical Rubber decided to focus on its publishing ventures ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carl Runge
Carl David Tolmé Runge (; 30 August 1856 – 3 January 1927) was a German mathematician, physicist, and spectroscopist. He was co-developer and co-eponym of the Runge–Kutta method (German pronunciation: ), in the field of what is today known as numerical analysis. Life and work Runge spent the first few years of his life in Havana, where his father Julius Runge was the Danish consul. His mother was Fanny Schwartz Tolmé. The family later moved to Bremen, where his father died early (in 1864). In 1880, he received his Ph.D. in mathematics at Berlin, where he studied under Karl Weierstrass. In 1886, he became a professor at the Technische Hochschule Hannover in Hanover, Germany. His interests included mathematics, spectroscopy, geodesy, and astrophysics. In addition to pure mathematics, he did experimental work studying spectral lines of various elements (together with Heinrich Kayser), and was very interested in the application of this work to astronomical spectroscopy ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quantum Defect
The term quantum defect refers to two concepts: energy loss in lasers and energy levels in alkali elements. Both deal with quantum systems where matter interacts with light. In laser science In laser science, the term "quantum defect" refers to the fact that the energy of a pump photon is generally higher than that of a ''signal photon'' (photon of the output radiation). The energy difference is lost to heat, which may carry away the excess entropy delivered by the multimode incoherent pump. The quantum defect of a laser can be defined as part of the energy of the pumping photon, which is lost (not turned into photons at the lasing wavelength) in the gain medium at the lasing. At given frequency \omega_ of pump and given frequency \omega_ of lasing, the quantum defect q = \hbar \omega_ - \hbar\omega_. Such quantum defect has dimension of energy; for the efficient operation, the temperature of the gain medium (measured in units of energy) should be small compared to the quantum def ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cambridge University Press
Cambridge University Press is the university press of the University of Cambridge. Granted letters patent by Henry VIII of England, King Henry VIII in 1534, it is the oldest university press A university press is an academic publishing house specializing in monographs and scholarly journals. Most are nonprofit organizations and an integral component of a large research university. They publish work that has been reviewed by schola ... in the world. It is also the King's Printer. Cambridge University Press is a department of the University of Cambridge and is both an academic and educational publisher. It became part of Cambridge University Press & Assessment, following a merger with Cambridge Assessment in 2021. With a global sales presence, publishing hubs, and offices in more than 40 Country, countries, it publishes over 50,000 titles by authors from over 100 countries. Its publishing includes more than 380 academic journals, monographs, reference works, school and uni ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rydberg Correction
The term quantum defect refers to two concepts: energy loss in lasers and energy levels in alkali metal, alkali elements. Both deal with quantum systems where matter interacts with light. In laser science In laser science, the term "quantum defect" refers to the fact that the energy of a pump photon is generally higher than that of a ''signal photon'' (photon of the output radiation). The energy difference is lost to heat, which may carry away the excess entropy delivered by the multimode incoherent pump. The quantum defect of a laser can be defined as part of the energy of the pumping photon, which is lost (not turned into photons at the lasing wavelength) in the gain medium at the lasing. At given frequency \omega_ of pump and given frequency \omega_ of lasing, the quantum defect q = \hbar \omega_ - \hbar\omega_. Such quantum defect has dimension of energy; for the efficient operation, the temperature of the gain medium (measured in units of energy) should be small compared to th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sharp Series
The sharp series is a series of spectral lines in the atomic emission spectrum caused when electrons descend from higher-energy s orbitals of an atom to the lowest available p orbital. The spectral lines include some in the visible light, and they extend into the ultraviolet. The lines get closer and closer together as the frequency increases never exceeding the series limit. The sharp series was important in the development of the understanding of electron shells and subshells in atoms. The sharp series has given the letter ''s'' to the s atomic orbital or subshell. The sharp series has a limit given by v=\frac-\frac \text m=2,3,4,5,6,... The series is caused by transitions to the lowest P state from higher energy S orbitals. One terminology to identify the lines is: 1P-mS But note that 1P just means the lowest P state in an atom and that the modern designation would start at 2P, and is larger for higher atomic numbered atoms. The terms can have different designations, mS for ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Diffuse Series
The diffuse series is a series of spectral lines in the atomic emission spectrum caused when electrons jump between the lowest p orbital and d orbitals of an atom. The total orbital angular momentum changes between 1 and 2. The spectral lines include some in the visible light, and may extend into ultraviolet or near infrared. The lines get closer and closer together as the frequency increases never exceeding the series limit. The diffuse series was important in the development of the understanding of electron shells and subshells in atoms. The diffuse series has given the letter ''d'' to the d atomic orbital or subshell. The diffuse series has values given by v=\frac-\frac with \ m=2,3,4,5,6,... The series is caused by transitions from the lowest P state to higher energy D orbitals. One terminology to identify the lines is: 1P-mD But note that 1P just means the lowest P state in the valence shell of an atom and that the modern designation would start at 2P, and is larger for ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Energy Levels Of Sodium Atom
In physics, energy (from Ancient Greek: ἐνέργεια, ''enérgeia'', “activity”) is the quantitative property that is transferred to a body or to a physical system, recognizable in the performance of work and in the form of heat and light. Energy is a conserved quantity—the law of conservation of energy states that energy can be converted in form, but not created or destroyed. The unit of measurement for energy in the International System of Units (SI) is the joule (J). Common forms of energy include the kinetic energy of a moving object, the potential energy stored by an object (for instance due to its position in a field), the elastic energy stored in a solid object, chemical energy associated with chemical reactions, the radiant energy carried by electromagnetic radiation, and the internal energy contained within a thermodynamic system. All living organisms constantly take in and release energy. Due to mass–energy equivalence, any object that has mass whe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium
Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable isotope is 23Na. The free metal does not occur in nature, and must be prepared from compounds. Sodium is the sixth most abundant element in the Earth's crust and exists in numerous minerals such as feldspars, sodalite, and halite (NaCl). Many salts of sodium are highly water-soluble: sodium ions have been leached by the action of water from the Earth's minerals over eons, and thus sodium and chlorine are the most common dissolved elements by weight in the oceans. Sodium was first isolated by Humphry Davy in 1807 by the electrolysis of sodium hydroxide. Among many other useful sodium compounds, sodium hydroxide (lye) is used in soap manufacture, and sodium chloride (edible salt) is a de-icing agent and a nutrient for animals including h ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
