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Franck–Condon Principle
The Franck–Condon principle describes the intensities of vibronic transitions, or the absorption or emission of a photon. It states that when a molecule is undergoing an electronic transition, such as ionization, the nuclear configuration of the molecule experiences no significant change. Overview The Franck–Condon principle has a well-established semiclassical interpretation based on the original contributions of James Franck. Electronic transitions are relatively instantaneous compared with the time scale of nuclear motions, therefore if the molecule is to move to a new vibrational level during the electronic transition, this new vibrational level must be instantaneously compatible with the nuclear positions and momenta of the vibrational level of the molecule in the originating electronic state. In the semiclassical picture of vibrations (oscillations) of a simple harmonic oscillator, the necessary conditions can occur at the turning points, where the momentum is zer ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Franck Condon Diagram
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Franck can refer to: People * Franck (name) Other * Franck, Argentina, town in Santa Fe Province, Argentina * Franck (company), Croatian coffee and snacks company * Franck (crater), Lunar crater named after James Franck See also * Franc (other) * Franks * Frank (other) * Frankie (other) * Frankel, Frankl Frankl is a surname. Notable people with the surname include: * Ludwig August von Frankl (1810–1894), Austrian writer and philanthropist * Michal Frankl (born 1974), Czech historian * Nicholas Frankl (born 1971), British-Hungarian entrepreneur ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Parabola
In mathematics, a parabola is a plane curve which is Reflection symmetry, mirror-symmetrical and is approximately U-shaped. It fits several superficially different Mathematics, mathematical descriptions, which can all be proved to define exactly the same curves. One description of a parabola involves a Point (geometry), point (the Focus (geometry), focus) and a Line (geometry), line (the Directrix (conic section), directrix). The focus does not lie on the directrix. The parabola is the locus (mathematics), locus of points in that plane that are equidistant from the directrix and the focus. Another description of a parabola is as a conic section, created from the intersection of a right circular conical surface and a plane (geometry), plane Parallel (geometry), parallel to another plane that is tangential to the conical surface. The graph of a function, graph of a quadratic function y=ax^2+bx+ c (with a\neq 0 ) is a parabola with its axis parallel to the -axis. Conversely, every ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spin (physics)
Spin is an Intrinsic and extrinsic properties, intrinsic form of angular momentum carried by elementary particles, and thus by List of particles#Composite particles, composite particles such as hadrons, atomic nucleus, atomic nuclei, and atoms. Spin is quantized, and accurate models for the interaction with spin require relativistic quantum mechanics or quantum field theory. The existence of electron spin angular momentum is inferred from experiments, such as the Stern–Gerlach experiment, in which silver atoms were observed to possess two possible discrete angular momenta despite having no orbital angular momentum. The relativistic spin–statistics theorem connects electron spin quantization to the Pauli exclusion principle: observations of exclusion imply half-integer spin, and observations of half-integer spin imply exclusion. Spin is described mathematically as a vector for some particles such as photons, and as a spinor or bispinor for other particles such as electrons. Sp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Wavefunction
In quantum physics, a wave function (or wavefunction) is a mathematical description of the quantum state of an isolated quantum system. The most common symbols for a wave function are the Greek letters and (lower-case and capital psi (letter), psi, respectively). Wave functions are complex number, complex-valued. For example, a wave function might assign a complex number to each point in a region of space. The Born rule provides the means to turn these complex probability amplitudes into actual probabilities. In one common form, it says that the squared modulus of a wave function that depends upon position is the probability density function, probability density of measurement in quantum mechanics, measuring a particle as being at a given place. The integral of a wavefunction's squared modulus over all the system's degrees of freedom must be equal to 1, a condition called ''normalization''. Since the wave function is complex-valued, only its relative phase and relative magnitud ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Probability Amplitude
In quantum mechanics, a probability amplitude is a complex number used for describing the behaviour of systems. The square of the modulus of this quantity at a point in space represents a probability density at that point. Probability amplitudes provide a relationship between the quantum state vector of a system and the results of observations of that system, a link that was first proposed by Max Born, in 1926. Interpretation of values of a wave function as the probability amplitude is a pillar of the Copenhagen interpretation of quantum mechanics. In fact, the properties of the space of wave functions were being used to make physical predictions (such as emissions from atoms being at certain discrete energies) before any physical interpretation of a particular function was offered. Born was awarded half of the 1954 Nobel Prize in Physics for this understanding, and the probability thus calculated is sometimes called the "Born probability". These probabilistic concepts, namel ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrons
The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up quark, up and down quark, down quarks. Electrons are extremely lightweight particles that orbit the positively charged atomic nucleus, nucleus of atoms. Their negative charge is balanced by the positive charge of protons in the nucleus, giving atoms their overall electric charge#Charge neutrality, neutral charge. Ordinary matter is composed of atoms, each consisting of a positively charged nucleus surrounded by a number of orbiting electrons equal to the number of protons. The configuration and energy levels of these orbiting electrons determine the chemical properties of an atom. Electrons are bound to the nucleus to different degrees. The outermost or valence electron, valence electrons are the least tightly bound and are responsible for th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bra–ket Notation
Bra–ket notation, also called Dirac notation, is a notation for linear algebra and linear operators on complex vector spaces together with their dual space both in the finite-dimensional and infinite-dimensional case. It is specifically designed to ease the types of calculations that frequently come up in quantum mechanics. Its use in quantum mechanics is quite widespread. Bra–ket notation was created by Paul Dirac in his 1939 publication ''A New Notation for Quantum Mechanics''. The notation was introduced as an easier way to write quantum mechanical expressions. The name comes from the English word "bracket". Quantum mechanics In quantum mechanics and quantum computing, bra–ket notation is used ubiquitously to denote quantum states. The notation uses angle brackets, and , and a vertical bar , to construct "bras" and "kets". A ket is of the form , v \rangle. Mathematically it denotes a vector, \boldsymbol v, in an abstract (complex) vector space V, and physicall ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dipole
In physics, a dipole () is an electromagnetic phenomenon which occurs in two ways: * An electric dipole moment, electric dipole deals with the separation of the positive and negative electric charges found in any electromagnetic system. A simple example of this system is a pair of charges of equal magnitude but opposite sign separated by some typically small distance. (A permanent electric dipole is called an electret.) * A magnetic dipole is the closed circulation of an electric current system. A simple example is a single loop of wire with constant current through it. A bar magnet is an example of a magnet with a permanent magnetic dipole moment. Dipoles, whether electric or magnetic, can be characterized by their dipole moment, a vector quantity. For the simple electric dipole, the electric dipole moment points from the negative charge towards the positive charge, and has a magnitude equal to the strength of each charge times the separation between the charges. (To be precis ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Condon Fig1 1926b
Condon may refer to: Places Australia * Condon, Queensland * Condon, Western Australia, a.k.a. Shellborough United States * Condon, Montana * Condon, Oregon and the nearby ** summit of Condon Butte Other places * Condon (crater) on the Moon Other uses * Condon (surname), an Irish surname * Condon Committee See also * Codon (nucleotides for genetic code) * Condom (other) * Condong () is a Balinese dance which is often performed as a preface to legong and accompanied by the Gamelan semar pegulingan, semar pangulingan style of gamelan. The term also refers to a stock character, a quintessential representation of the maids ... (Balinese dance) * Condong, New South Wales * Conlon * Kondon (other) {{disambig, geo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Raymond Thayer Birge
Raymond Thayer Birge (March 13, 1887 – March 22, 1980) was an American physicist. Career Born in Brooklyn, New York, into a family of academic scientists, Birge obtained his doctorate from the University of Wisconsin in 1913. In the same year he married Irene A. Walsh. The Birges had two children, Carolyn Elizabeth (Mrs. E. D. Yocky) and Robert Walsh, Associate Director of the Lawrence Berkeley National Laboratory in 1973-1981. After five years as an instructor at Syracuse University, he became a member of the physics department at University of California, Berkeley, where he remained until he retired, as chairman, in 1955. On his arrival at Berkeley, Birge sought collaboration with the Berkeley College of Chemistry, then under the leadership of Gilbert N. Lewis. However, Birge's championing of the Bohr atom led him into conflict with the chemists who defended Lewis' earlier theory of the cubical atom. Birge was unafraid of scientific controversy and persevered with his cou ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carbon Monoxide
Carbon monoxide (chemical formula CO) is a poisonous, flammable gas that is colorless, odorless, tasteless, and slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simplest oxocarbon, carbon oxide. In coordination complexes, the carbon monoxide ligand is called ''metal carbonyl, carbonyl''. It is a key ingredient in many processes in industrial chemistry. The most common source of carbon monoxide is the partial combustion of carbon-containing compounds. Numerous environmental and biological sources generate carbon monoxide. In industry, carbon monoxide is important in the production of many compounds, including drugs, fragrances, and fuels. Indoors CO is one of the most acutely toxic contaminants affecting indoor air quality. CO may be emitted from tobacco smoke and generated from malfunctioning fuel-burning stoves (wood, kerosene, natural gas, propane) and fuel-burning heating systems (wood, oil, n ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Physical Review
''Physical Review'' is a peer-reviewed scientific journal. The journal was established in 1893 by Edward Nichols. It publishes original research as well as scientific and literature reviews on all aspects of physics. It is published by the American Physical Society (APS). The journal is in its third series, and is split in several sub-journals each covering a particular field of physics. It has a sister journal, '' Physical Review Letters'', which publishes shorter articles of broader interest. History ''Physical Review'' commenced publication in July 1893, organized by Cornell University professor Edward Nichols and helped by the new president of Cornell, J. Gould Schurman. The journal was managed and edited at Cornell in upstate New York from 1893 to 1913 by Nichols, Ernest Merritt, and Frederick Bedell. The 33 volumes published during this time constitute ''Physical Review Series I''. The American Physical Society (APS), founded in 1899, took over its publicati ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
