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Flow-accelerated Corrosion
Flow-accelerated corrosion (FAC), also known as flow-assisted corrosion, is a corrosion mechanism in which a normally protective oxide layer on a metal surface dissolves in a fast flowing water. The underlying metal corrodes to re-create the oxide, and thus the metal loss continues. By definition, the rate of FAC depends on the flow velocity. FAC often affects carbon steel piping carrying ultra-pure, deoxygenated water or wet steam. Stainless steel does not suffer from FAC. FAC of carbon steel halts in the presence of small amount of oxygen dissolved in water. FAC rates rapidly decrease with increasing water pH. FAC has to be distinguished from erosion corrosion because the fundamental mechanisms for the two corrosion modes are different. FAC does not involve impingement of particles, bubbles, or cavitation which cause the mechanical (often crater-like) wear on the surface. By contrast to mechanical erosion, FAC involves dissolution of normally poorly soluble oxide by combined ele ...
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Corrosion
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and preventing corrosion. In the most common use of the word, this means electrochemical oxidation of metal in reaction with an oxidant such as oxygen, hydrogen or hydroxide. Rusting, the formation of iron oxides, is a well-known example of electrochemical corrosion. This type of damage typically produces oxide(s) or salt(s) of the original metal and results in a distinctive orange colouration. Corrosion can also occur in materials other than metals, such as ceramics or polymers, although in this context, the term "degradation" is more common. Corrosion degrades the useful properties of materials and structures including strength, appearance and permeability to liquids and gases. Many structural ...
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Carbon Steel
Carbon steel is a steel with carbon content from about 0.05 up to 2.1 percent by weight. The definition of carbon steel from the American Iron and Steel Institute (AISI) states: * no minimum content is specified or required for chromium, cobalt, molybdenum, nickel, niobium, titanium, tungsten, vanadium, zirconium, or any other element to be added to obtain a desired alloying effect; * the specified minimum for copper does not exceed 0.40%; * or the maximum content specified for any of the following elements does not exceed the percentages noted: manganese 1.65%; silicon 0.60%; copper 0.60%. The term ''carbon steel'' may also be used in reference to steel which is not stainless steel; in this use carbon steel may include alloy steels. High carbon steel has many different uses such as milling machines, cutting tools (such as chisels) and high strength wires. These applications require a much finer microstructure, which improves the toughness. Carbon steel is a popular metal choic ...
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Stainless Steel
Stainless steel is an alloy of iron that is resistant to rusting and corrosion. It contains at least 11% chromium and may contain elements such as carbon, other nonmetals and metals to obtain other desired properties. Stainless steel's corrosion resistance, resistance to corrosion results from the chromium, which forms a Passivation (chemistry), passive film that can protect the material and self-healing material, self-heal in the presence of oxygen. The alloy's properties, such as luster and resistance to corrosion, are useful in many applications. Stainless steel can be rolled into Sheet metal, sheets, plates, bars, wire, and tubing. These can be used in cookware, cutlery, surgical instruments, major appliances, vehicles, construction material in large buildings, industrial equipment (e.g., in paper mills, chemical plants, water treatment), and storage tanks and tankers for chemicals and food products. The biological cleanability of stainless steel is superior to both alumi ...
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Erosion Corrosion
Erosion corrosion is a degradation of material surface due to mechanical action, often by impinging liquid, abrasion by a slurry, particles suspended in fast flowing liquid or gas, bubbles or droplets, cavitation, etc. The mechanism can be described as follows: * mechanical erosion of the material, or protective (or passive) oxide layer on its surface, * enhanced corrosion of the material, if the corrosion rate of the material depends on the thickness of the oxide layer. The mechanism of erosion corrosion, the materials affected by it, and the conditions when it occurs are generally different from that of flow-accelerated corrosion, although the last one is sometimes classified as a sub-type of erosion corrosion. See also * Corrosion engineering * Tribocorrosion * Tribology * Wear Wear is the damaging, gradual removal or deformation of material at solid surfaces. Causes of wear can be mechanical (e.g., erosion) or chemical (e.g., corrosion). The study of wear and related pro ...
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Cavitation
Cavitation is a phenomenon in which the static pressure of a liquid reduces to below the liquid's vapour pressure, leading to the formation of small vapor-filled cavities in the liquid. When subjected to higher pressure, these cavities, called "bubbles" or "voids", collapse and can generate shock waves that may damage machinery. These shock waves are strong when they are very close to the imploded bubble, but rapidly weaken as they propagate away from the implosion. Cavitation is a significant cause of wear in some engineering contexts. Collapsing voids that implode near to a metal surface cause cyclic stress through repeated implosion. This results in surface fatigue of the metal causing a type of wear also called "cavitation". The most common examples of this kind of wear are to pump impellers, and bends where a sudden change in the direction of liquid occurs. Cavitation is usually divided into two classes of behavior: inertial (or transient) cavitation and non-inertial c ...
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Erosion Corrosion Of Copper Water Tubes
Erosion corrosion, also known as impingement damage, is the combined effect of corrosion and erosion caused by rapid flowing turbulent water. It is probably the second most common cause of copper tube failures behind Type 1 pitting which is also known as Cold Water Pitting of Copper Tube. Copper Water Tubes Copper tubes have been used to distribute drinking water within buildings for many years, and hundreds of miles are installed throughout Europe every year. The long life of copper when exposed to natural waters is a result of its thermodynamic stability, its high resistance to reacting with the environment, and the formation of insoluble corrosion products that insulate the metal from the environment. The corrosion rate of copper in most drinkable waters is less than 2.5 µm/year, at this rate a 15 mm tube with a wall thickness of 0.7 mm would last for about 280 years. In some soft waters the general corrosion rate may increase to 12.5 µm/year, but even at t ...
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Oxygenated Treatment
Oxygenated treatment (OT) is a technique used to reduce corrosion in a boiler and its associated feedwater system in flow-through boilers. With oxygenated treatment, oxygen is injected into the feedwater to keep the oxygen level between 30-50 ppb. OT programs are most commonly used in supercritical (ie >3250psi) power boilers. The ability to change an existing sub-critical boiler over to an OT program is very limited. "Common injection points are just after the condensate polisher and again at the deaerator outlet." This forms a thicker protective layer of hematite (Fe2O3) on top of the magnetite. This is a denser, flatter film (vs. the undulation scale with OT) so that there is less resistance to water flow compared to AVT. Also, OT reduces the risk of flow-accelerated corrosion. When OT is used, conductivity after cation exchange (CACE) at the economiser inlet must be maintained below 0.15μS/cm this can be achieved by the use of a full-flow condensate polisher.Frank Gabriell ...
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