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Ferroelectric Polymers
Ferroelectric polymers are a group of crystalline polar polymers that are also ferroelectric, meaning that they maintain a permanent electric polarization that can be reversed, or switched, in an external electric field. Ferroelectric polymers, such as polyvinylidene fluoride (PVDF), are used in acoustic transducers and electromechanical actuators because of their inherent piezoelectric response, and as heat sensors because of their inherent pyroelectric response. Figure 1: Structure of poly(vinylidene fluoride) Background First reported in 1971, ferroelectric polymers are polymer chains that must exhibit ferroelectric behavior, hence piezoelectric and pyroelectric behavior. A ferroelectric polymer must contain permanent electrical polarization that can be reversed repeatedly, by an opposing electric field. In the polymer, dipoles can be randomly oriented, but application of an electric field will align the dipoles, leading to ferroelectric behavior. In order for this effect to ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polymers
A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic and natural polymers play essential and ubiquitous roles in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure and function. Polymers, both natural and synthetic, are created via polymerization of many small molecules, known as monomers. Their consequently large molecular mass, relative to small molecule compounds, produces unique physical properties including toughness, high elasticity, viscoelasticity, and a tendency to form amorphous and semicrystalline structures rather than crystals. The term "polymer" derives from the Greek word πολύς (''polus'', meaning "many, much") and μέρος (''meros'', meani ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Radical Polymerization
In polymer chemistry, free-radical polymerization (FRP) is a method of polymerization by which a polymer forms by the successive addition of free-radical building blocks (repeat units). Free radicals can be formed by a number of different mechanisms, usually involving separate initiator molecules. Following its generation, the initiating free radical adds (nonradical) monomer units, thereby growing the polymer chain. Free-radical polymerization is a key synthesis route for obtaining a wide variety of different polymers and materials composites. The relatively non-specific nature of free-radical chemical interactions makes this one of the most versatile forms of polymerization available and allows facile reactions of polymeric free-radical chain ends and other chemicals or substrates. In 2001, 40 billion of the 110 billion pounds of polymers produced in the United States were produced by free-radical polymerization. Free-radical polymerization is a type of chain-growth polymeriz ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrooptic
Electro–optics is a branch of electrical engineering, electronic engineering, materials science, and material physics involving components, electronic devices such as lasers, laser diodes, LEDs, waveguides, etc. which operate by the propagation and interaction of light with various tailored materials. It is closely related to the branch of optics, involving application of generation of photons, called photonics. It is not only concerned with the "electro–optic effect", since it deals with the interaction between the electromagnetic (optical) and the electrical (electronic) states of materials. Electro-optical devices The electro-optic effect is a change in the optical properties of an optically active material due to interaction with light. This interaction usually results in a change in the birefringence, and not simply the refractive index of the medium. In a Kerr cell, the change in birefringence is proportional to the square of the optical electric field, and the mat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Journal Of Luminescence
The ''Journal of Luminescence'' is a monthly peer-reviewed scientific journal published by Elsevier. The editor-in-chief is Xueyuan Chen. According to the ''Journal Citation Reports'', the journal has a 2021 impact factor of 4.171, ranking it 26th out of 101 journals in the category "Optics". The journal covers all aspects related to the emission of light (luminescence). Editors The editors-in-chief are: *S. Tanabe (Kyoto University *D. Poelman (Universiteit Gent, Ghent, Belgium. *K.-L. Wong (Hong Kong Baptist University *M.F. Reid (Dodd-Walls Centre for Photonic and Quantum Technologies The Dodd-Walls Centre for Photonic and Quantum Technologies () is a New Zealand Centre of Research Excellence, established in 2015, hosted by the University of Otago, and composed of researchers in six New Zealand universities as well as partn ...) References External links * Elsevier academic journals Optics journals Publications established in 1968 Monthly journals English-language ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Percolation Theory
In statistical physics and mathematics, percolation theory describes the behavior of a network when nodes or links are added. This is a geometric type of phase transition, since at a critical fraction of addition the network of small, disconnected clusters merge into significantly larger connected, so-called spanning clusters. The applications of percolation theory to materials science and in many other disciplines are discussed here and in the articles network theory and percolation. Introduction A representative question (and the source of the name) is as follows. Assume that some liquid is poured on top of some porous material. Will the liquid be able to make its way from hole to hole and reach the bottom? This physical question is modelled mathematically as a three-dimensional network of vertices, usually called "sites", in which the edge or "bonds" between each two neighbors may be open (allowing the liquid through) with probability , or closed with probability , and th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dielectric Constant
The relative permittivity (in older texts, dielectric constant) is the permittivity of a material expressed as a ratio with the electric permittivity of a vacuum. A dielectric is an insulating material, and the dielectric constant of an insulator measures the ability of the insulator to store electric energy in an electrical field. Permittivity is a material's property that affects the Coulomb force between two point charges in the material. Relative permittivity is the factor by which the electric field between the charges is decreased relative to vacuum. Likewise, relative permittivity is the ratio of the capacitance of a capacitor using that material as a dielectric, compared with a similar capacitor that has vacuum as its dielectric. Relative permittivity is also commonly known as the dielectric constant, a term still used but deprecated by standards organizations in engineering as well as in chemistry. Definition Relative permittivity is typically denoted as (sometimes ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Acoustic Impedance
Acoustic impedance and specific acoustic impedance are measures of the opposition that a system presents to the acoustic flow resulting from an acoustic pressure applied to the system. The SI unit of acoustic impedance is the pascal-second per cubic metre (), or in the MKS system the rayl per square metre (), while that of specific acoustic impedance is the pascal-second per metre (), or in the MKS system the rayl. There is a close analogy with electrical impedance, which measures the opposition that a system presents to the electric current resulting from a voltage applied to the system. Mathematical definitions Acoustic impedance For a linear time-invariant system, the relationship between the acoustic pressure applied to the system and the resulting acoustic volume flow rate through a surface perpendicular to the direction of that pressure at its point of application is given by: : p(t) = * Qt), or equivalently by : Q(t) = * pt), where * ''p'' is the acoustic pressure; * ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrostatic
Electrostatics is a branch of physics that studies electric charges at rest (static electricity). Since classical times, it has been known that some materials, such as amber, attract lightweight particles after rubbing. The Greek word for amber, (), was thus the source of the word 'electricity'. Electrostatic phenomena arise from the forces that electric charges exert on each other. Such forces are described by Coulomb's law. Even though electrostatically induced forces seem to be rather weak, some electrostatic forces are relatively large. The force between an electron and a proton, which together make up a hydrogen atom, is about 36 orders of magnitude stronger than the gravitational force acting between them. There are many examples of electrostatic phenomena, from those as simple as the attraction of plastic wrap to one's hand after it is removed from a package, to the apparently spontaneous explosion of grain silos, the damage of electronic components during manufacturi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Steric
Steric effects arise from the spatial arrangement of atoms. When atoms come close together there is a rise in the energy of the molecule. Steric effects are nonbonding interactions that influence the shape ( conformation) and reactivity of ions and molecules. Steric effects complement electronic effects, which dictate the shape and reactivity of molecules. Steric repulsive forces between overlapping electron clouds result in structured groupings of molecules stabilized by the way that opposites attract and like charges repel. Steric hindrance Steric hindrance is a consequence of steric effects. Steric hindrance is the slowing of chemical reactions due to steric bulk. It is usually manifested in ''intermolecular reactions'', whereas discussion of steric effects often focus on ''intramolecular interactions''. Steric hindrance is often exploited to control selectivity, such as slowing unwanted side-reactions. Steric hindrance between adjacent groups can also affect torsional ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
