|
Extended Metal Atom Chains
In organometallic chemistry, extended metal atom chains (EMACs) are molecules that consist of a Linear chain compound, linear chain of Metal–metal bond, directly bonded metal atoms, surrounded by organic ligands. These compounds represent the smallest molecular wires. Such species are researched for the Top-down and bottom-up design, bottom-up approach to nanoelectronics, although no applications are near term. Structure An EMAC molecule contains a linear string of transition metals (typically Chromium, Cr, Cobalt, Co, Nickel, Ni, or Copper, Cu) that are bonded to each other and surrounded helically by organic ligands. The metal chains are usually end-capped by anions, usually halides. The organic ligands often pyridylamide, pyridone, 1,8-Naphthyridine, naphthyridine, or their derivatives. Each metal atom is octahedral molecular geometry, six-coordinate, bonded to two other metals along the axis of the molecule (except terminal metals, which are bonded to one metal and one capp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organometallic Chemistry
Organometallic chemistry is the study of organometallic compounds, chemical compounds containing at least one chemical bond between a carbon atom of an organic molecule and a metal, including alkali, alkaline earth, and transition metals, and sometimes broadened to include metalloids like boron, silicon, and selenium, as well. Aside from bonds to organyl fragments or molecules, bonds to 'inorganic' carbon, like carbon monoxide (metal carbonyls), cyanide, or carbide, are generally considered to be organometallic as well. Some related compounds such as transition metal hydrides and metal phosphine complexes are often included in discussions of organometallic compounds, though strictly speaking, they are not necessarily organometallic. The related but distinct term " metalorganic compound" refers to metal-containing compounds lacking direct metal-carbon bonds but which contain organic ligands. Metal β-diketonates, alkoxides, dialkylamides, and metal phosphine complexes are repres ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Shie-Ming Peng
Shie-Ming Peng (; born 2 March 1949) is a Taiwanese chemist. Peng attended National Hsinchu Senior High School and graduated from National Taiwan University prior to completing a doctorate from the University of Chicago. He returned to teach at NTU in 1976, after two years as a postdoctoral researcher at Northwestern University. Peng was granted a Humboldt Fellowship in 1983, elected a member of Academia Sinica in 1998, and became a Fellow of the Royal Society of Chemistry Fellowship of the Royal Society of Chemistry (FRSC) is an award conferred by the Royal Society of Chemistry (RSC) in the United Kingdom. FRSC award Achieving Fellow status in the chemical profession denotes to the wider community a high level of ... in 2009. References {{DEFAULTSORT:Peng, Shie-Ming 1949 births Living people Taiwanese chemists Academic staff of the National Taiwan University National Taiwan University alumni University of Chicago alumni 20th-century Taiwanese scientists 21st-century T ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Switch
In electrical engineering, a switch is an electrical component that can disconnect or connect the conducting path in an electrical circuit, interrupting the electric current or diverting it from one conductor to another. The most common type of switch is an electromechanical device consisting of one or more sets of movable electrical contacts connected to external circuits. When a pair of contacts is touching current can pass between them, while when the contacts are separated no current can flow. Switches are made in many different configurations; they may have multiple sets of contacts controlled by the same knob or actuator, and the contacts may operate simultaneously, sequentially, or alternately. A switch may be operated manually, for example, a light switch or a keyboard button, or may function as a sensing element to sense the position of a machine part, liquid level, pressure, or temperature, such as a thermostat. Many specialized forms exist, such as the toggle switch, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rheostat
A potentiometer is a three-terminal resistor with a sliding or rotating contact that forms an adjustable voltage divider. If only two terminals are used, one end and the wiper, it acts as a variable resistor or rheostat. The measuring instrument called a potentiometer is essentially a voltage divider used for measuring electric potential (voltage); the component is an implementation of the same principle, hence its name. Potentiometers are commonly used to control electrical devices such as volume controls on audio equipment. Potentiometers operated by a mechanism can be used as position transducers, for example, in a joystick. Potentiometers are rarely used to directly control significant power (more than a watt), since the power dissipated in the potentiometer would be comparable to the power in the controlled load. Nomenclature There are a number of terms in the electronics industry used to describe certain types of potentiometers: * slide pot or slider pot: a potentiomete ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Redox
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate (chemistry), substrate change. Oxidation is the loss of Electron, electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state. There are two classes of redox reactions: * ''Electron-transfer'' – Only one (usually) electron flows from the reducing agent to the oxidant. This type of redox reaction is often discussed in terms of redox couples and electrode potentials. * ''Atom transfer'' – An atom transfers from one substrate to another. For example, in the rusting of iron, the oxidation state of iron atoms increases as the iron converts to an oxide, and simultaneously the oxidation state of oxygen decreases as it accepts electrons released by the iron. Although oxidation reactions are commonly associated with the formation of oxides, other chemical species can serve the same function. In hydrogen ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nanocircuitry
Nanocircuits are electrical circuits operating on the nanometer scale. This is well into the quantum realm, where quantum mechanical effects become very important. One nanometer is equal to 10−9 meters or a row of 10 hydrogen atoms. With such progressively smaller circuits, more can be fitted on a computer chip. This allows faster and more complex functions using less power. Nanocircuits are composed of three different fundamental components. These are transistors, interconnections, and architecture, all fabricated on the nanometer scale. Various approaches to nanocircuitry A variety of proposals have been made to implement nanocircuitry in different forms. These include Nanowires, Single-Electron Transistors, Quantum dot cellular automata, and Nanoscale Crossbar Latches. However, likely nearer-term approaches will involve incorporation of nanomaterials to improve MOSFETs (metal-oxide-semiconductor field-effect transistors). These currently form the basis of most anal ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrical Conductor
In physics and electrical engineering, a conductor is an object or type of material that allows the flow of charge (electric current) in one or more directions. Materials made of metal are common electrical conductors. Electric current is generated by the flow of negatively charged electrons, positively charged holes, and positive or negative ions in some cases. In order for current to flow within a closed electrical circuit, it is not necessary for one charged particle to travel from the component producing the current (the current source) to those consuming it (the loads). Instead, the charged particle simply needs to nudge its neighbor a finite amount, who will nudge ''its'' neighbor, and on and on until a particle is nudged into the consumer, thus powering it. Essentially what is occurring is a long chain of momentum transfer between mobile charge carriers; the Drude model of conduction describes this process more rigorously. This momentum transfer model makes metal an i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Magnetism
Magnetism is the class of physical attributes that are mediated by a magnetic field, which refers to the capacity to induce attractive and repulsive phenomena in other entities. Electric currents and the magnetic moments of elementary particles give rise to a magnetic field, which acts on other currents and magnetic moments. Magnetism is one aspect of the combined phenomena of electromagnetism. The most familiar effects occur in ferromagnetic materials, which are strongly attracted by magnetic fields and can be magnetized to become permanent magnets, producing magnetic fields themselves. Demagnetizing a magnet is also possible. Only a few substances are ferromagnetic; the most common ones are iron, cobalt, and nickel and their alloys. The rare-earth metals neodymium and samarium are less common examples. The prefix ' refers to iron because permanent magnetism was first observed in lodestone, a form of natural iron ore called magnetite, Fe3O4. All substances exhibit some type of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electronic Configuration
In atomic physics and quantum chemistry, the electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. For example, the electron configuration of the neon atom is , meaning that the 1s, 2s and 2p subshells are occupied by 2, 2 and 6 electrons respectively. Electronic configurations describe each electron as moving independently in an orbital, in an average field created by all other orbitals. Mathematically, configurations are described by Slater determinants or configuration state functions. According to the laws of quantum mechanics, for systems with only one electron, a level of energy is associated with each electron configuration and in certain conditions, electrons are able to move from one configuration to another by the emission or absorption of a quantum of energy, in the form of a photon. Knowledge of the electron configuration of different atoms is useful in understanding the structu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quantum Chemistry
Quantum chemistry, also called molecular quantum mechanics, is a branch of physical chemistry focused on the application of quantum mechanics to chemical systems, particularly towards the quantum-mechanical calculation of electronic contributions to physical and chemical properties of Molecule, molecules, Material, materials, and solutions at the atomic level. These calculations include systematically applied approximations intended to make calculations computationally feasible while still capturing as much information about important contributions to the computed Wave function, wave functions as well as to observable properties such as structures, spectra, and thermodynamic properties. Quantum chemistry is also concerned with the computation of quantum effects on molecular dynamics and chemical kinetics. Chemists rely heavily on spectroscopy through which information regarding the Quantization (physics), quantization of energy on a molecular scale can be obtained. Common metho ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Isomerism
In chemistry, isomers are molecules or polyatomic ions with identical molecular formulae – that is, same number of atoms of each element – but distinct arrangements of atoms in space. Isomerism is existence or possibility of isomers. Isomers do not necessarily share similar chemical or physical properties. Two main forms of isomerism are structural or constitutional isomerism, in which ''bonds'' between the atoms differ; and stereoisomerism or spatial isomerism, in which the bonds are the same but the ''relative positions'' of the atoms differ. Isomeric relationships form a hierarchy. Two chemicals might be the same constitutional isomer, but upon deeper analysis be stereoisomers of each other. Two molecules that are the same stereoisomer as each other might be in different conformational forms or be different isotopologues. The depth of analysis depends on the field of study or the chemical and physical properties of interest. The English word "isomer" () is a back-form ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
2,2'-dipyridylamide
2,2′-Dipyridylamine is an organic compound with the formula (C5H4N)2NH. It consists of a pair of 2-pyridyl groups (C5H4N) linked to a secondary amine. The compound forms a range of coordination complexes. Its conjugate base, 2,2′-dipyridylamide, forms extended metal atom chains. Formation 2,2′-Dipyridylamine can be formed by heating pyridine with sodium amide. Alternatively, 2-aminopyridine can be heated with 2-chloropyridine over barium oxide Barium oxide, also known as baria, is a white hygroscopic non-flammable compound with the formula BaO. It has a cubic structure and is used in cathode ray tubes, crown glass, and catalysts. It is harmful to human skin and if swallowed in large q .... References {{DEFAULTSORT:Dipyridylamine, 2,2'- Aminopyridines Chelating agents ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
