Einsteinium(III) Fluoride
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Einsteinium(III) Fluoride
Einsteinium fluoride is a binary inorganic chemical compound of einsteinium and fluorine with the chemical formula . Synthesis Einsteinium fluoride can be precipitated from einsteinium(III) chloride solutions upon reaction with fluoride ions. An alternative preparation procedure is to expose einsteinium(III) oxide to chlorine trifluoride (ClF3) or F2 gas at a pressure of 1–2 atmospheres and a temperature between 300 and 400 °C. The EsF3 crystal structure is hexagonal, as in californium(III) fluoride (CfF3) where the Es3+ ions are 8-fold coordinated by fluorine ions in a bicapped trigonal prism arrangement.Greenwood Green wood is unseasoned wood. Greenwood or Green wood may also refer to: People * Greenwood (surname) Settlements Australia * Greenwood, Queensland, a locality in the Toowoomba Region * Greenwood, Western Australia, a suburb of Perth C ..., p. 1270 Physical properties The compound forms crystals and is insoluble in water. Chemical properties ...
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Californium(III) Fluoride
Californium(III) fluoride is a binary inorganic compound of californium and fluorine with the formula Physical properties Californium(III) fluoride is a yellow-green solid and has two crystalline structures that are temperature dependent. At low temperatures the orthorhombic structure ( type) is found with lattice constant A lattice constant or lattice parameter is one of the physical dimensions and angles that determine the geometry of the unit cells in a crystal lattice, and is proportional to the distance between atoms in the crystal. A simple cubic crystal has o ...s ''a'' = 665.3(3) pm, ''b'' = 703.9(1) pm and ''c'' = 439.3(3) pm. At higher temperatures it forms a trigonal system ( type) with: ''a'' = 694.5(3) pm and ''c'' = 710.1(2) pm. Here, each californium atom is surrounded by nine fluorine atoms in a distorted triply-capped trigonal-prismatic structure. References Californium compounds Fluorides {{inorganic-compound-stub ...
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Californium(III) Fluoride
Californium(III) fluoride is a binary inorganic compound of californium and fluorine with the formula Physical properties Californium(III) fluoride is a yellow-green solid and has two crystalline structures that are temperature dependent. At low temperatures the orthorhombic structure ( type) is found with lattice constant A lattice constant or lattice parameter is one of the physical dimensions and angles that determine the geometry of the unit cells in a crystal lattice, and is proportional to the distance between atoms in the crystal. A simple cubic crystal has o ...s ''a'' = 665.3(3) pm, ''b'' = 703.9(1) pm and ''c'' = 439.3(3) pm. At higher temperatures it forms a trigonal system ( type) with: ''a'' = 694.5(3) pm and ''c'' = 710.1(2) pm. Here, each californium atom is surrounded by nine fluorine atoms in a distorted triply-capped trigonal-prismatic structure. References Californium compounds Fluorides {{inorganic-compound-stub ...
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Einsteinium Compounds
Einsteinium compounds are compounds that contain the element einsteinium (Es). These compounds largely have einsteinium in the +3 oxidation state, or in some cases in the +2 and +4 oxidation states. Although einsteinium is relatively stable, with half-lives ranging from 20 days upwards, these compounds have not been studied in great detail. Properties of einsteinium compounds Oxides Einsteinium(III) oxide (Es2O3) was obtained by burning einsteinium(III) nitrate. It forms colorless cubic crystals, which were first characterized from microgram samples sized about 30 nanometers.Greenwood, p. 1268 Two other phases, monoclinic and hexagonal, are known for this oxide. The formation of a certain Es2O3 phase depends on the preparation technique and sample history, and there is no clear phase diagram. Interconversions between the three phases can occur spontaneously, as a result of self-irradiation or self-heating. Haire, p. 1598 The hexagonal phase is isotypic with lanthanum oxide w ...
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Springer Science & Business Media
Springer Science+Business Media, commonly known as Springer, is a German multinational publishing company of books, e-books and peer-reviewed journals in science, humanities, technical and medical (STM) publishing. Originally founded in 1842 in Berlin, it expanded internationally in the 1960s, and through mergers in the 1990s and a sale to venture capitalists it fused with Wolters Kluwer and eventually became part of Springer Nature in 2015. Springer has major offices in Berlin, Heidelberg, Dordrecht, and New York City. History Julius Springer founded Springer-Verlag in Berlin in 1842 and his son Ferdinand Springer grew it from a small firm of 4 employees into Germany's then second largest academic publisher with 65 staff in 1872.Chronology
". Springer Science+Business Media.
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CRC Press
The CRC Press, LLC is an American publishing group that specializes in producing technical books. Many of their books relate to engineering, science and mathematics. Their scope also includes books on business, forensics and information technology. CRC Press is now a division of Taylor & Francis, itself a subsidiary of Informa. History The CRC Press was founded as the Chemical Rubber Company (CRC) in 1903 by brothers Arthur, Leo and Emanuel Friedman in Cleveland, Ohio, based on an earlier enterprise by Arthur, who had begun selling rubber laboratory aprons in 1900. The company gradually expanded to include sales of laboratory equipment to chemists. In 1913 the CRC offered a short (116-page) manual called the ''Rubber Handbook'' as an incentive for any purchase of a dozen aprons. Since then the ''Rubber Handbook'' has evolved into the CRC's flagship book, the '' CRC Handbook of Chemistry and Physics''. In 1964, Chemical Rubber decided to focus on its publishing ventures ...
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Greenwood
Green wood is unseasoned wood. Greenwood or Green wood may also refer to: People * Greenwood (surname) Settlements Australia * Greenwood, Queensland, a locality in the Toowoomba Region * Greenwood, Western Australia, a suburb of Perth Canada * Greenwood, Calgary, Alberta, a neighbourhood * Greenwood, British Columbia, a city * Greenwood, Nova Scotia, a village * Greenwood, Halifax County, Nova Scotia, a community in the Halifax Regional Municipality * Greenwood, Durham Regional Municipality, Ontario * Greenwood, Renfrew County, Ontario United States * Greenwood, Arizona * Greenwood, Arkansas * Greenwood, El Dorado County, California * Greenwood, Glenn County, California * Greenwood, former name of Elk, Mendocino County, California * Greenwood Village, Colorado, a city * Greenwood, Delaware * Greenwood, Florida * Greenwood, Georgia * Greenwood, Idaho * Greenwood, Illinois * Mount Greenwood, Chicago, Illinois * Greenwood, Indiana * Greenwood, Wayne County, Indiana * Gr ...
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Journal Of Inorganic And Nuclear Chemistry
''Polyhedron'' is a peer-reviewed scientific journal covering the field of inorganic chemistry. It was established in 1955 as the ''Journal of Inorganic and Nuclear Chemistry'' and is published by Elsevier. Abstracting and indexing ''Polyhedron'' is abstracted and indexed in: According to the ''Journal Citation Reports'', the journal has a 2020 impact factor The impact factor (IF) or journal impact factor (JIF) of an academic journal is a scientometric index calculated by Clarivate that reflects the yearly mean number of citations of articles published in the last two years in a given journal, as i ... of 3.052. References External links * {{Official Website, http://www.journals.elsevier.com/polyhedron/ Inorganic chemistry journals Elsevier academic journals Publications established in 1955 English-language journals ...
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Octahedral Molecular Geometry
In chemistry, octahedral molecular geometry, also called square bipyramidal, describes the shape of compounds with six atoms or groups of atoms or ligands symmetrically arranged around a central atom, defining the vertices of an octahedron. The octahedron has eight faces, hence the prefix ''octa''. The octahedron is one of the Platonic solids, although octahedral molecules typically have an atom in their centre and no bonds between the ligand atoms. A perfect octahedron belongs to the point group Oh. Examples of octahedral compounds are sulfur hexafluoride SF6 and molybdenum hexacarbonyl Mo(CO)6. The term "octahedral" is used somewhat loosely by chemists, focusing on the geometry of the bonds to the central atom and not considering differences among the ligands themselves. For example, , which is not octahedral in the mathematical sense due to the orientation of the bonds, is referred to as octahedral. The concept of octahedral coordination geometry was developed by Alfred Wern ...
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Chlorine Trifluoride
Chlorine trifluoride is an interhalogen compound with the formula ClF3. This colorless, poisonous, corrosive, and extremely reactive gas condenses to a pale-greenish yellow liquid, the form in which it is most often sold (pressurized at room temperature). The compound is primarily of interest in plasmaless cleaning and etching operations in the semiconductor industry, in nuclear reactor fuel processing, as a component in rocket fuels, and other industrial operations. Preparation, structure, and properties It was first reported in 1930 by Ruff and Krug who prepared it by fluorination of chlorine; this also produced ClF (chlorine monofluoride) and the mixture was separated by distillation. :3 F2 + Cl2 → 2 ClF3 The molecular geometry of ClF3 is approximately T-shaped, with one short bond (1.598  Å) and two long bonds (1.698 Å). This structure agrees with the prediction of VSEPR theory, which predicts lone pairs of electrons as occupying two equatorial positions o ...
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Berkelium(III) Fluoride
Berkelium(III) fluoride is a binary inorganic compound of berkelium and fluorine with the chemical formula . Synthesis The compound can be prepared by treating with a gaseous mixture of and HF at 600 °C. Physical properties Berkelium trifluoride forms a yellow-green solid with two structures. At low temperature, it is orthorhombic ( structure), with lattice parameters a = 670 pm, b = 709 pm, and c = 441 pm. At high temperature, it is trigonal ( structure), with lattice parameters a = 697 pm and c = 714 pm. The transition temperature of is between 350 and 600 °C. Chemical properties Berkelium trifluoride is reduced by lithium Lithium (from el, λίθος, lithos, lit=stone) is a chemical element with the symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense solid el ... to obtain metallic berkelium: :: References {{Actinide halides Fluorides Berkeli ...
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Einsteinium(III) Oxide
Einsteinium(III) oxide is an oxide of the synthetic actinide einsteinium which has the molecular formula Es2O3. It is a colourless solid. Three modifications are known. The body-centered cubic form has lattice parameter ''a'' = 1076.6 ± 0.6  pm; this allows the ionic radius of the Es3+ ion to be calculated as 92.8 pm. The other two forms are monoclinic and hexagonal: the hexagonal form has the lanthanum(III) oxide structure.R. G. Haire, L. Eyring, in: ''Handbook on the Physics and Chemistry of Rare Earths'', Vol. 18 ''Lanthanoids and Actinides Chemistry'' (hrsg. von K. A. Gscheidner, Jr., L. Eyring, G. R. Choppin, G. H. Lander), North-Holland, New York 1994, S. 414–505. Einsteinium(III) oxide can be obtained by annealing einsteinium(III) nitrate Einsteinium is a synthetic element with the symbol Es and atomic number 99. Einsteinium is a member of the actinide series and it is the seventh transuranium element. It was named in honor of Albert Ein ...
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Fluoride
Fluoride (). According to this source, is a possible pronunciation in British English. is an inorganic, monatomic anion of fluorine, with the chemical formula (also written ), whose salts are typically white or colorless. Fluoride salts typically have distinctive bitter tastes, and are odorless. Its salts and minerals are important chemical reagents and industrial chemicals, mainly used in the production of hydrogen fluoride for fluorocarbons. Fluoride is classified as a weak base since it only partially associates in solution, but concentrated fluoride is corrosive and can attack the skin. Fluoride is the simplest fluorine anion. In terms of charge and size, the fluoride ion resembles the hydroxide ion. Fluoride ions occur on Earth in several minerals, particularly fluorite, but are present only in trace quantities in bodies of water in nature. Nomenclature Fluorides include compounds that contain ionic fluoride and those in which fluoride does not dissociate. The nom ...
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