Donnayite-(Y)
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Donnayite-(Y)
Donnayite-(Y) is a rare-earth carbonate mineral containing the rare-earth metal yttrium. It was first discovered in 1978 at Mont Saint-Hilaire, Quebec. Donnayite was subsequently identified and named after Joseph D. H. Donnay and his wife, Gabrielle Donnay. Both were prominent mineralogists and crystallographers, and J. D. H. Donnay was awarded the Roebling Award by the Mineralogical Society of America in 1971 for his emphasis on the importance of optical mineralogy and crystal morphology. Donnayite tends to occur in small quantities in the pegmatite dykes and miarolitic cavities of mountainous regions. It crystallizes in this environment with increasing alkalinity values until the alkalinity suddenly drops during the last stage of crystallization. This results in increasing amounts of Na carbonates and REE minerals. First discovered at Mont St-Hilaire, donnayite has since been found in the Southern Ural Mountains of Russia and the Narssarssuk pegmatite of South Greenland. Donnay ...
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Carbonate Minerals
Carbonate minerals are those minerals containing the carbonate ion, . Carbonate divisions Anhydrous carbonates *Calcite group: trigonal **Calcite CaCO3 **Gaspéite (Ni,Mg,Fe2+)CO3 **Magnesite MgCO3 **Otavite CdCO3 **Rhodochrosite MnCO3 **Siderite FeCO3 **Smithsonite ZnCO3 **Spherocobaltite CoCO3 *Aragonite group: orthorhombic **Aragonite CaCO3 **Cerussite PbCO3 **Strontianite SrCO3 **Witherite BaCO3 **Rutherfordine UO2CO3 **Natrite Na2CO3 Anhydrous carbonates with compound formulas *Dolomite group: trigonal **Ankerite CaFe(CO3)2 **Dolomite (mineral), Dolomite CaMg(CO3)2 **Huntite Mg3Ca(CO3)4 **Minrecordite CaZn(CO3)2 **Barytocalcite BaCa(CO3)2 Carbonates with hydroxyl or halogen *Carbonate with hydroxide: monoclinic **Azurite Cu3(CO3)2(OH)2 **Hydrocerussite Pb3(CO3)2(OH)2 **Malachite Cu2CO3(OH)2 **Rosasite (Cu,Zn)2CO3(OH)2 **Phosgenite Pb2(CO3)Cl2 **Hydrozincite Zn5(CO3)2(OH)6 **Aurichalcite (Zn,Cu)5(CO3)2(OH)6 Hydrated carbonates *Hydromagnesite Mg5(CO3)4(OH)2.4H2O *Ikaite ...
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Lustre (mineralogy)
Lustre (British English) or luster (American English; see spelling differences) is the way light interacts with the surface of a crystal, rock, or mineral. The word traces its origins back to the Latin ''lux'', meaning "light", and generally implies radiance, gloss, or brilliance. A range of terms are used to describe lustre, such as ''earthy'', ''metallic'', ''greasy'', and ''silky''. Similarly, the term ''vitreous'' (derived from the Latin for glass, ''vitrum'') refers to a glassy lustre. A list of these terms is given below. Lustre varies over a wide continuum, and so there are no rigid boundaries between the different types of lustre. (For this reason, different sources can often describe the same mineral differently. This ambiguity is further complicated by lustre's ability to vary widely within a particular mineral species). The terms are frequently combined to describe intermediate types of lustre (for example, a "vitreous greasy" lustre). Some minerals exhibit unus ...
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Syenite
Syenite is a coarse-grained intrusive igneous rock with a general composition similar to that of granite, but deficient in quartz, which, if present at all, occurs in relatively small concentrations (< 5%). Some syenites contain larger proportions of components and smaller amounts of felsic material than most granites; those are classed as being of . The equivalent of syenite is

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Nepheline
Nepheline, also called nephelite (), is a rock-forming mineral in the feldspathoid groupa silica-undersaturated aluminosilicate, Na3 K Al4 Si4 O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatites. It is used in glass and ceramic manufacturing and other industries, and has been investigated as an ore of aluminium. Description and properties Nepheline crystals are rare and belong to the hexagonal system, usually having the form of a short, six-sided prism terminated by the basal plane. The crystals appear to have more symmetry than they actually possess, but unsymmetrical etched figures produced artificially on the prism faces indicate that the crystals are hemimorphic and tetartohedral, the only element of symmetry being a polar hexad axis. Nepheline is found in compact, granular aggregates, and can be white, yellow, gray, green, or reddish. Its hardness on the Mohs scale is 5.5–6, and its specific gravity 2.60–2.65. It i ...
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Point Group
In geometry, a point group is a mathematical group of symmetry operations (isometries in a Euclidean space) that have a fixed point in common. The coordinate origin of the Euclidean space is conventionally taken to be a fixed point, and every point group in dimension ''d'' is then a subgroup of the orthogonal group O(''d''). Point groups are used to describe the symmetries of geometric figures and physical objects such as molecules. Each point group can be represented as sets of orthogonal matrices ''M'' that transform point ''x'' into point ''y'' according to Each element of a point group is either a rotation (determinant of ''M'' = 1), or it is a reflection or improper rotation (determinant of ''M'' = −1). The geometric symmetries of crystals are described by space groups, which allow translations and contain point groups as subgroups. Discrete point groups in more than one dimension come in infinite families, but from the crystallographic restriction theorem and ...
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Cleavage (crystal)
Cleavage, in mineralogy and materials science, is the tendency of crystalline materials to split along definite crystallographic structural planes. These planes of relative weakness are a result of the regular locations of atoms and ions in the crystal, which create smooth repeating surfaces that are visible both in the microscope and to the naked eye. If bonds in certain directions are weaker than others, the crystal will tend to split along the weakly bonded planes. These flat breaks are termed "cleavage."Hurlbut, Cornelius S.; Klein, Cornelis, 1985, '' Manual of Mineralogy'', 20th ed., Wiley, The classic example of cleavage is mica, which cleaves in a single direction along the basal pinacoid, making the layers seem like pages in a book. In fact, mineralogists often refer to "books of mica." Diamond and graphite provide examples of cleavage. Both are composed solely of a single element, carbon. But in diamond, each carbon atom is bonded to four others in a tetrahedral pa ...
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Mohs Scale
The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. The scale was introduced in 1812 by the German geologist and mineralogist Friedrich Mohs, in his book ''"Versuch einer Elementar-Methode zur naturhistorischen Bestimmung und Erkennung der Fossilien"''; it is one of several definitions of hardness in materials science, some of which are more quantitative. The method of comparing hardness by observing which minerals can scratch others is of great antiquity, having been mentioned by Theophrastus in his treatise ''On Stones'', , followed by Pliny the Elder in his ''Naturalis Historia'', . The Mohs scale is useful for identification of minerals in the field, but is not an accurate predictor of how well materials endure in an industrial setting – ''toughness''. Minerals The Mohs scale of mineral hardness is based on the ability ...
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Strontium
Strontium is the chemical element with the symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is exposed to air. Strontium has physical and chemical properties similar to those of its two vertical neighbors in the periodic table, calcium and barium. It occurs naturally mainly in the minerals celestine and strontianite, and is mostly mined from these. Both strontium and strontianite are named after Strontian, a village in Scotland near which the mineral was discovered in 1790 by Adair Crawford and William Cruickshank; it was identified as a new element the next year from its crimson-red flame test color. Strontium was first isolated as a metal in 1808 by Humphry Davy using the then newly discovered process of electrolysis. During the 19th century, strontium was mostly used in the production of sugar from sugar beets (see strontian p ...
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Electron Microprobe
An electron microprobe (EMP), also known as an electron probe microanalyzer (EPMA) or electron micro probe analyzer (EMPA), is an analytical tool used to non-destructively determine the chemical composition of small volumes of solid materials. It works similarly to a scanning electron microscope: the sample is bombarded with an electron beam, emitting x-rays at wavelengths characteristic to the elements being analyzed. This enables the abundances of elements present within small sample volumes (typically 10-30 cubic micrometers or less) to be determined,Wittry, David B. (1958). "Electron Probe Microanalyzer"US Patent No 2916621 Washington, DC: U.S. Patent and Trademark Office when a conventional accelerating voltage of 15-20 kV is used. The concentrations of elements from lithium to plutonium may be measured at levels as low as 100 parts per million (ppm), material dependent, although with care, levels below 10 ppm are possible. The ability to quantify lithium by EPMA became a real ...
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Metamorphism
Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of chemically active fluids, but the rock remains mostly solid during the transformation. Metamorphism is distinct from weathering or diagenesis, which are changes that take place at or just beneath Earth's surface. Various forms of metamorphism exist, including regional, contact, hydrothermal, shock, and dynamic metamorphism. These differ in the characteristic temperatures, pressures, and rate at which they take place and in the extent to which reactive fluids are involved. Metamorphism occurring at increasing pressure and temperature conditions is known as ''prograde metamorphism'', while decreasing temperature and pressure characterize ''retrograde metamorphism''. Metamorphic petrology is the study of metamorphism. Metamorphic petrologists re ...
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Mineral Hydration
In chemistry, mineral hydration is an inorganic chemical reaction which adds water to the crystal structure of a mineral, usually creating a new mineral, usually called a ''hydrate''. In geological terms, the process of mineral hydration is known as ''retrograde alteration'' and is a process occurring in retrograde metamorphism. It commonly accompanies metasomatism and is often a feature of wall rock alteration around ore bodies. Hydration of minerals occurs generally in concert with hydrothermal circulation which may be driven by tectonic or igneous activity. Processes There are two main ways in which minerals hydrate. One is conversion of an oxide to a double hydroxide, as with the hydration of calcium oxide—CaO—to calcium hydroxide—Ca(OH)2, the other is with the incorporation of water molecules directly into the crystalline structure of a new mineral. The later process is exhibited in the hydration of feldspars to clay minerals, garnet to chlorite, or kyanite to m ...
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Isomorphism
In mathematics, an isomorphism is a structure-preserving mapping between two structures of the same type that can be reversed by an inverse mapping. Two mathematical structures are isomorphic if an isomorphism exists between them. The word isomorphism is derived from the Ancient Greek: ἴσος ''isos'' "equal", and μορφή ''morphe'' "form" or "shape". The interest in isomorphisms lies in the fact that two isomorphic objects have the same properties (excluding further information such as additional structure or names of objects). Thus isomorphic structures cannot be distinguished from the point of view of structure only, and may be identified. In mathematical jargon, one says that two objects are . An automorphism is an isomorphism from a structure to itself. An isomorphism between two structures is a canonical isomorphism (a canonical map that is an isomorphism) if there is only one isomorphism between the two structures (as it is the case for solutions of a univer ...
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