Derek Harold Richard Barton
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Derek Harold Richard Barton
Sir Derek Harold Richard Barton (8 September 1918 – 16 March 1998) was an English organic chemist and Nobel Prize laureate for 1969. Education and early life Barton was born in Gravesend, Kent, to William Thomas and Maude Henrietta Barton (''née'' Lukes). He attended Gravesend Grammar School (1926–29), The King's School, Rochester (1929–32), Tonbridge School (1932–35) and Medway Technical College (1937–39). In 1938 he entered Imperial College London, where he graduated in 1940 and obtained his Doctor of Philosophy, PhD degree in Organic Chemistry in 1942. Career and research From 1942 to 1944 Barton was a government research chemist, then from 1944 to 1945 he worked for Albright and Wilson in Birmingham. He then became Assistant Lecturer in the Department of Chemistry of Imperial College, and from 1946 to 1949 he was Imperial Chemical Industries, ICI Research Fellow. During 1949 and 1950 he was visiting lecturer in natural products chemistry at Harvard University, ...
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Gravesend
Gravesend is a town in northwest Kent, England, situated 21 miles (35 km) east-southeast of Charing Cross (central London) on the Bank (geography), south bank of the River Thames and opposite Tilbury in Essex. Located in the diocese of Rochester, it is the administrative centre of the Gravesham, Borough of Gravesham. Its geographical situation has given Gravesend strategic importance throughout the maritime history, maritime and History of communication, communications history of South East England. A Thames Gateway commuter town, it retains strong links with the River Thames, not least through the Port of London Authority Pilot Station and has witnessed rejuvenation since the advent of High Speed 1 rail services via Gravesend railway station. The station was recently refurbished and now has a new bridge. Toponymy Recorded as Gravesham in the Domesday Book of 1086 when it belonged to Odo, Earl of Kent and Roman Catholic Diocese of Bayeux, Bishop of Bayeux, the half-broth ...
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Barton–McCombie Deoxygenation
The Barton–McCombie deoxygenation is an organic reaction in which a hydroxy functional group in an organic compound is replaced by a hydrogen to give an alkyl group. It is named after British chemists Sir Derek Harold Richard Barton and Stuart W. McCombie. This deoxygenation reaction is a radical substitution. In the related Barton decarboxylation the reactant is a carboxylic acid. Mechanism The reaction mechanism consists of a catalytic radical initiation step and a propagation step. The alcohol (1) is first converted into a reactive carbonothioyl intermediate such as a thionoester or xanthate 2. Heating of AIBN results in its homolytic cleavage, generating two 2-cyanoprop-2-yl radicals 9 which each abstract a proton from tributylstannane 3 to generate tributylstannyl radicals 4 and inactive 10. The tributyltin radical abstracts the xanthate group from 2 by attack of 4 at the sulfur atom with concurrent homolytic cleavage of the C-S π bond. This leaves a carbon centered ...
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Organic Chemist
Organic chemistry is a subdiscipline within chemistry involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms.Clayden, J.; Greeves, N. and Warren, S. (2012) ''Organic Chemistry''. Oxford University Press. pp. 1–15. . Study of structure determines their structural formula. Study of properties includes physical and chemical properties, and evaluation of chemical reactivity to understand their behavior. The study of organic reactions includes the chemical synthesis of natural products, drugs, and polymers, and study of individual organic molecules in the laboratory and via theoretical (in silico) study. The range of chemicals studied in organic chemistry includes hydrocarbons (compounds containing only carbon and hydrogen) as well as compounds based on carbon, but also containing other elements, especially oxygen, nitrogen, sulfur, phosphorus (included in many ...
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Knights Bachelor Insignia
A knight is a person granted an honorary title of knighthood by a head of state (including the Pope) or representative for service to the monarch, the church or the country, especially in a military capacity. Knighthood finds origins in the Greek ''hippeis'' and '' hoplite'' (ἱππεῖς) and Roman '' eques'' and '' centurion'' of classical antiquity. In the Early Middle Ages in Europe, knighthood was conferred upon mounted warriors. During the High Middle Ages, knighthood was considered a class of lower nobility. By the Late Middle Ages, the rank had become associated with the ideals of chivalry, a code of conduct for the perfect courtly Christian warrior. Often, a knight was a vassal who served as an elite fighter or a bodyguard for a lord, with payment in the form of land holdings. The lords trusted the knights, who were skilled in battle on horseback. Knighthood in the Middle Ages was closely linked with horsemanship (and especially the joust) from its origins in ...
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Priestley Medal
The Priestley Medal is the highest honor conferred by the American Chemical Society (ACS) and is awarded for distinguished service in the field of chemistry. Established in 1922, the award is named after Joseph Priestley, the discoverer of oxygen who immigrated to the United States of America in 1794. The ACS formed in 1876, spearheaded by a group of chemists who had met two years previously in Priestley's home. The Priestley Medal is commonly awarded to scientists who are advanced in their fields, as it is intended to commemorate lifetime achievement. When the ACS started presenting the Priestley Medal in 1923, they intended to award it every three years. This continued until 1944, when it became an annual award. Recipients ;1920s * 1923 Ira Remsen * 1926 Edgar Fahs Smith * 1929 Francis P. Garvan ;1930s * 1932 Charles L. Parsons * 1935 William A. Noyes * 1938 Marston T. Bogert ;1940s * 1941 Thomas Midgley, Jr. * 1944 James Bryant Conant * 1945 Ian Heilbron * 1946 Roger ...
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Copley Medal
The Copley Medal is an award given by the Royal Society, for "outstanding achievements in research in any branch of science". It alternates between the physical sciences or mathematics and the biological sciences. Given every year, the medal is the oldest Royal Society medal awarded and the oldest surviving scientific award in the world, having first been given in 1731 to Stephen Gray (scientist), Stephen Gray, for "his new Electrical Experiments: – as an encouragement to him for the readiness he has always shown in obliging the Society with his discoveries and improvements in this part of Natural Knowledge". __TOC__ History The medal was created following a donation of Pound sterling, £100 to be used for carrying out experiments by Sir Godfrey Copley, 2nd Baronet, Sir Godfrey Copley, for which the interest on the amount was used for several years. The conditions for the medal have been changed several times; in 1736, it was suggested that "a medal or other honorary prize s ...
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Knight Bachelor
The title of Knight Bachelor is the basic rank granted to a man who has been knighted by the monarch but not inducted as a member of one of the organised orders of chivalry; it is a part of the British honours system. Knights Bachelor are the most ancient sort of British knight (the rank existed during the 13th-century reign of King Henry III), but Knights Bachelor rank below knights of chivalric orders. A man who is knighted is formally addressed as "Sir irst Name urname or "Sir irst Name and his wife as "Lady urname. Criteria Knighthood is usually conferred for public service; amongst its recipients are all male judges of His Majesty's High Court of Justice in England. It is possible to be a Knight Bachelor and a junior member of an order of chivalry without being a knight of that order; this situation has become rather common, especially among those recognized for achievements in entertainment. For instance, Sir Michael Gambon, Sir Derek Jacobi, Sir Anthony Hopkins, Sir ...
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Royal Medal
The Royal Medal, also known as The Queen's Medal and The King's Medal (depending on the gender of the monarch at the time of the award), is a silver-gilt medal, of which three are awarded each year by the Royal Society, two for "the most important contributions to the advancement of natural knowledge" and one for "distinguished contributions in the applied sciences", done within the Commonwealth of Nations. Background The award was created by George IV of the United Kingdom, George IV and awarded first during 1826. Initially there were two medals awarded, both for the most important discovery within the year previous, a time period which was lengthened to five years and then shortened to three. The format was endorsed by William IV of the United Kingdom, William IV and Victoria of the United Kingdom, Victoria, who had the conditions changed during 1837 so that mathematics was a subject for which a Royal Medal could be awarded, albeit only every third year. The conditions were chang ...
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Nobel Prize In Chemistry
) , image = Nobel Prize.png , alt = A golden medallion with an embossed image of a bearded man facing left in profile. To the left of the man is the text "ALFR•" then "NOBEL", and on the right, the text (smaller) "NAT•" then "MDCCCXXXIII" above, followed by (smaller) "OB•" then "MDCCCXCVI" below. , awarded_for = Outstanding contributions in chemistry , presenter = Royal Swedish Academy of Sciences , location = Stockholm, Sweden , reward = 9 million SEK (2017) , year = 1901 , holder = Carolyn R. Bertozzi, Morten P. Meldal and Karl Barry Sharpless (2022) , most_awards = Frederick Sanger and Karl Barry Sharpless (2) , website nobelprize.org, previous = 2021 , year2=2022, main=2022, next=2023 The Nobel Prize in Chemistry is awarded annually by the Royal Swedish Academy of Sciences to scientists in the various fields of chemistry. It is one of the five Nobel Prizes established by the will of Alfred Nobel in 1895, awarded for ...
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Davy Medal
The Davy Medal is awarded by the Royal Society of London "for an outstandingly important recent discovery in any branch of chemistry". Named after Humphry Davy, the medal is awarded with a monetary gift, initially of £1000 (currently £2000). History The medal was first awarded in 1877 to Robert Wilhelm Bunsen and Gustav Robert Kirchhoff "for their researches & discoveries in spectrum analysis", and has since been awarded 140 times. The medal is awarded annually and, unlike other Royal Society medals (such as the Hughes), has been awarded without interruption since its inception. The medal has been awarded to multiple individuals in the same year: in 1882, for example, it was awarded to Dmitri Mendeleev and Julius Lothar Meyer "for their discovery of the periodic relations of the atomic weights"; in 1883 to Marcellin Berthelot and Julius Thomsen "for their researches in thermo-chemistry"; in 1893 to Jacobus Henricus van 't Hoff and Joseph Achille Le Bel "In recognition of thei ...
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Ernest Guenther Award
The Ernest Guenther Award in the Chemistry of Natural Products is an American Chemical Society (ACS) award in the field of the chemistry of natural products. The purpose of the award is to recognize and encourage outstanding achievements in the analysis, structure elucidation, and chemical synthesis of natural products, with special consideration given to the independence of thought and originality. The award is granted regardless of race, gender, age, religion, ethnicity, nationality, sexual orientation, gender expression, gender identity, presence of disabilities, and educational background. The award consists of $6,000, a medallion, and a certificate. The medallion is presented during an award address. The award was established in 1948 by Fritzsche Dodge and Olcott Inc. to mark the 75th anniversary of the founding of the company. Since 1969,''Fritsche Award in Essential Oils Named for Dr. Guenther.'' In: ''Journal of the American Oil Chemists' Society.'' 44, 1967, S. A626– ...
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Fellow Of The Royal Society
Fellowship of the Royal Society (FRS, ForMemRS and HonFRS) is an award granted by the judges of the Royal Society of London to individuals who have made a "substantial contribution to the improvement of natural science, natural knowledge, including mathematics, engineering science, and medical science". Fellow, Fellowship of the Society, the oldest known scientific academy in continuous existence, is a significant honour. It has been awarded to many eminent scientists throughout history, including Isaac Newton (1672), Michael Faraday (1824), Charles Darwin (1839), Ernest Rutherford (1903), Srinivasa Ramanujan (1918), Albert Einstein (1921), Paul Dirac (1930), Winston Churchill (1941), Subrahmanyan Chandrasekhar (1944), Dorothy Hodgkin (1947), Alan Turing (1951), Lise Meitner (1955) and Francis Crick (1959). More recently, fellowship has been awarded to Stephen Hawking (1974), David Attenborough (1983), Tim Hunt (1991), Elizabeth Blackburn (1992), Tim Berners-Lee (2001), Venki R ...
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