|
Departure Function
In thermodynamics, a departure function is defined for any thermodynamic property as the difference between the property as computed for an ideal gas and the property of the species as it exists in the real world, for a specified temperature ''T'' and pressure ''P''. Common departure functions include those for enthalpy, entropy, and internal energy. Departure functions are used to calculate real fluid extensive properties (i.e. properties which are computed as a difference between two states). A departure function gives the difference between the real state, at a finite volume or non-zero pressure and temperature, and the ideal state, usually at zero pressure or infinite volume and temperature. For example, to evaluate enthalpy change between two points ''h''(''v''1,''T''1) and ''h''(''v''2,''T''2) we first compute the enthalpy departure function between volume ''v''1 and infinite volume at ''T'' = ''T''1, then add to that the ideal gas enthalpy change due to the tempe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamics
Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to a wide variety of topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering and mechanical engineering, but also in other complex fields such as meteorology. Historically, thermodynamics developed out of a desire to increase the efficiency of early steam engines, particularly through the work of French physicist Sadi Carnot (1824) who believed that engine efficiency was the key that could help France win the Napoleonic Wars. Scots-Irish physicist Lord Kelvin was the first to formulate a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reduced Pressure
In thermodynamics, the reduced properties of a fluid are a set of state variables scaled by the fluid's state properties at its critical point. These dimensionless thermodynamic coordinates, taken together with a substance's compressibility factor, provide the basis for the simplest form of the theorem of corresponding states. Reduced properties are also used to define the Peng–Robinson equation of state, a model designed to provide reasonable accuracy near the critical point. They are also used to critical exponents, which describe the behaviour of physical quantities near continuous phase transitions.Hagen Kleinert and Verena Schulte-Frohlinde, ''Critical Properties of φ4-Theories'', pp.8World Scientific (Singapore, 2001) ''(Read online a'' Reduced pressure The reduced pressure is defined as its actual pressure p divided by its critical pressure p_: :p_ = Reduced temperature The reduced temperature of a fluid is its actual temperature, divided by its critical temperatur ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamics
Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to a wide variety of topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering and mechanical engineering, but also in other complex fields such as meteorology. Historically, thermodynamics developed out of a desire to increase the efficiency of early steam engines, particularly through the work of French physicist Sadi Carnot (1824) who believed that engine efficiency was the key that could help France win the Napoleonic Wars. Scots-Irish physicist Lord Kelvin was the first to formulate a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Residual Property (physics)
In thermodynamics a residual property is defined as the difference between a real fluid property and an ideal gas property, both considered at the same density, temperature, and composition. Correlated terms *Departure function References * J. M. Smith, H.C.Van Ness, M. M. Abbot ''Introduction to Chemical Engineering Thermodynamics'' 2000, McGraw-Hill 6TH edition * Robert Perry, Don W. Green Perry's Chemical Engineers' Handbook ''Perry's Chemical Engineers' Handbook'' (also known as ''Perry's Handbook'', ''Perry's'', or ''The Chemical Engineer's Bible'') was first published in 1934 and the most current ninth edition was published in July 2018. It has been a source of c ... 2007 McGraw-Hill 8TH edition Thermodynamic properties {{thermodynamics-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Acentric Factor
The acentric factor is a conceptual number introduced by Kenneth Pitzer in 1955, proven to be useful in the description of fluids. It has become a standard for the phase characterization of single & pure components, along with other state description parameters such as molecular weight, critical temperature, critical pressure, and critical volume (or critical compressibility). Pitzer defined from the relationship :\omega = - \log_ (p^_r) - 1, T_r = 0.7 where p^_r = \frac is the reduced saturation vapor pressure and T_r = \frac is the reduced temperature. The acentric factor is said to be a measure of the non-sphericity (centricity) of molecules. As it increases, the vapor curve is "pulled" down, resulting in higher boiling points. For many monatomic fluids, p_r^ T_r = 0.7 is close to 0.1, which leads to \omega \to 0. In many cases, T_r = 0.7 lies above the boiling temperature of liquids at atmosphere pressure. Values of can be determined for any fluid from accurate exp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Critical Pressure
In thermodynamics, a critical point (or critical state) is the end point of a phase equilibrium curve. The most prominent example is the liquid–vapor critical point, the end point of the pressure–temperature curve that designates conditions under which a liquid and its vapor can coexist. At higher temperatures, the gas cannot be liquefied by pressure alone. At the critical point, defined by a ''critical temperature'' ''T''c and a ''critical pressure'' ''p''c, phase boundaries vanish. Other examples include the liquid–liquid critical points in mixtures, and the ferromagnet–paramagnet transition (Curie temperature) in the absence of an external magnetic field. Liquid–vapor critical point Overview For simplicity and clarity, the generic notion of ''critical point'' is best introduced by discussing a specific example, the vapor–liquid critical point. This was the first critical point to be discovered, and it is still the best known and most studied one. The figur ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Critical Temperature
Critical or Critically may refer to: *Critical, or critical but stable, medical states **Critical, or intensive care medicine *Critical juncture, a discontinuous change studied in the social sciences. *Critical Software, a company specializing in mission and business critical information systems *Critical theory, a school of thought that critiques society and culture by applying knowledge from the social sciences and the humanities * Critically endangered, a risk status for wild species *Criticality (status), the condition of sustaining a nuclear chain reaction Art, entertainment, and media * ''Critical'' (novel), a medical thriller written by Robin Cook * ''Critical'' (TV series), a Sky 1 TV series * "Critical" (''Person of Interest''), an episode of the American television drama series ''Person of Interest'' *"Critical", a 1999 single by Zion I People *Cr1TiKaL (born 1994), an American YouTuber and Twitch streamer See also *Critic *Criticality (other) *Critical Conditi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Compressibility Factor
In thermodynamics, the compressibility factor (Z), also known as the compression factor or the gas deviation factor, describes the deviation of a real gas from ideal gas behaviour. It is simply defined as the ratio of the molar volume of a gas to the molar volume of an ideal gas at the same temperature and pressure. It is a useful thermodynamic property for modifying the ideal gas law to account for the real gas behaviour.Properties of Natural Gases . Includes a chart of compressibility factors versus reduced pressure and reduced temperature (on last page of the PDF document) In general, deviation from ideal behaviour becomes more significant the closer a gas is to a |
Reduced Temperature
In thermodynamics, the reduced properties of a fluid are a set of state variables scaled by the fluid's state properties at its critical point. These dimensionless thermodynamic coordinates, taken together with a substance's compressibility factor, provide the basis for the simplest form of the theorem of corresponding states. Reduced properties are also used to define the Peng–Robinson equation of state, a model designed to provide reasonable accuracy near the critical point. They are also used to critical exponents, which describe the behaviour of physical quantities near continuous phase transitions.Hagen Kleinert and Verena Schulte-Frohlinde, ''Critical Properties of φ4-Theories'', pp.8World Scientific (Singapore, 2001) ''(Read online a'' Reduced pressure The reduced pressure is defined as its actual pressure p divided by its critical pressure p_: :p_ = Reduced temperature The reduced temperature of a fluid is its actual temperature, divided by its critical temperatur ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ideal Gas
An ideal gas is a theoretical gas composed of many randomly moving point particles that are not subject to interparticle interactions. The ideal gas concept is useful because it obeys the ideal gas law, a simplified equation of state, and is amenable to analysis under statistical mechanics. The requirement of zero interaction can often be relaxed if, for example, the interaction is perfectly elastic or regarded as point-like collisions. Under various conditions of temperature and pressure, many real gases behave qualitatively like an ideal gas where the gas molecules (or atoms for monatomic gas) play the role of the ideal particles. Many gases such as nitrogen, oxygen, hydrogen, noble gases, some heavier gases like carbon dioxide and mixtures such as air, can be treated as ideal gases within reasonable tolerances over a considerable parameter range around standard temperature and pressure. Generally, a gas behaves more like an ideal gas at higher temperature and lower pressu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Equation Of State
In physics, chemistry, and thermodynamics, an equation of state is a thermodynamic equation relating state variables, which describe the state of matter under a given set of physical conditions, such as pressure, volume, temperature, or internal energy. Most modern equations of state are formulated in the Helmholtz free energy. Equations of state are useful in describing the properties of pure substances and mixtures in liquids, gases, and solid states as well as the state of matter in the interior of stars. Overview At present, there is no single equation of state that accurately predicts the properties of all substances under all conditions. An example of an equation of state correlates densities of gases and liquids to temperatures and pressures, known as the ideal gas law, which is roughly accurate for weakly polar gases at low pressures and moderate temperatures. This equation becomes increasingly inaccurate at higher pressures and lower temperatures, and fails to predict ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gibbs Free Energy
In thermodynamics, the Gibbs free energy (or Gibbs energy; symbol G) is a thermodynamic potential that can be used to calculate the maximum amount of work that may be performed by a thermodynamically closed system at constant temperature and pressure. It also provides a necessary condition for processes such as chemical reactions that may occur under these conditions. The Gibbs free energy change , measured in joules in SI) is the ''maximum'' amount of non-expansion work that can be extracted from a closed system (one that can exchange heat and work with its surroundings, but not matter) at fixed temperature and pressure. This maximum can be attained only in a completely reversible process. When a system transforms reversibly from an initial state to a final state under these conditions, the decrease in Gibbs free energy equals the work done by the system to its surroundings, minus the work of the pressure forces. The Gibbs energy is the thermodynamic potential that is minim ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
.jpg "Click for more on -> Thermodynamics")
