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Devil's Venom
Devil's venom was a nickname coined by Soviet rocket scientists for a liquid rocket fuel composed of a dangerous combination of red fuming nitric acid and hydrazine—specifically, hypergolic UDMH-nitric acid. Both propellants are extremely dangerous individually: Nitric acid is highly corrosive and causes offgassing of toxic nitrogen dioxide during reactions, or even simply while exposed to air in its highly concentrated "red fuming" form used as rocket propellant. UDMH is both toxic and corrosive. Despite these dangers, the pairing has been used in rocketry because this combination of fuel and oxidizer is hypergolic (it does not require an external ignition source), which makes rockets using these materials simpler. Further, both the fuel and oxidizer have high boiling points compared to other rocket fuels (such as liquid hydrogen) and oxidizers (such as liquid oxygen), allowing rockets to be stored ready for launch for long periods without the fuel or oxidizer boiling off and ne ...
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Red Fuming Nitric Acid
Red fuming nitric acid (RFNA) is a storable oxidizer used as a rocket propellant. It consists of 84% nitric acid (), 13% dinitrogen tetroxide and 1–2% water. The color of red fuming nitric acid is due to the dinitrogen tetroxide, which breaks down partially to form nitrogen dioxide. The nitrogen dioxide dissolves until the liquid is saturated, and produces toxic fumes with a suffocating odor. RFNA increases the flammability of combustible materials and is highly exothermic when reacting with water. It is usually used with an inhibitor (with various, sometimes secret, substances, including hydrogen fluoride; any such combination is called ''inhibited RFNA'', ''IRFNA'') because nitric acid attacks most container materials. Hydrogen fluoride for instance will passivate the container metal with a thin layer of metal fluoride, making it nearly impervious to the nitric acid. It can also be a component of a monopropellant; with substances like amine nitrates dissolved in it, it can ...
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Hydrazine
Hydrazine is an inorganic compound with the chemical formula . It is a simple pnictogen hydride, and is a colourless flammable liquid with an ammonia-like odour. Hydrazine is highly toxic unless handled in solution as, for example, hydrazine hydrate (). Hydrazine is mainly used as a foaming agent in preparing polymer foams, but applications also include its uses as a precursor to polymerization catalysts, pharmaceuticals, and agrochemicals, as well as a long-term storable propellant for in-space spacecraft propulsion. Additionally, hydrazine is used in various rocket fuels and to prepare the gas precursors used in air bags. Hydrazine is used within both nuclear and conventional electrical power plant steam cycles as an oxygen scavenger to control concentrations of dissolved oxygen in an effort to reduce corrosion. the world hydrazine hydrate market amounted to $350 million. About two million tons of hydrazine hydrate were used in foam blowing agents in 2015. Hydrazines r ...
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Hypergolic Propellant
A hypergolic propellant is a rocket propellant combination used in a rocket engine, whose components spontaneously ignite when they come into contact with each other. The two propellant components usually consist of a fuel and an oxidizer. The main advantages of hypergolic propellants are that they can be stored as liquids at room temperature and that engines which are powered by them are easy to ignite reliably and repeatedly. Common hypergolic propellants are difficult to handle due to their extreme toxicity and/or corrosiveness. In contemporary usage, the terms "hypergol" and "hypergolic propellant" usually mean the most common such propellant combination: dinitrogen tetroxide plus hydrazine and/or its relatives monomethylhydrazine (MMH) and unsymmetrical dimethylhydrazine (UDMH). History In 1935, Hellmuth Walter discovered that hydrazine hydrate was hypergolic with high-test peroxide of 80-83%. He was probably the first to discover this phenomenon, and set to work d ...
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Unsymmetrical Dimethylhydrazine
Unsymmetrical dimethylhydrazine (UDMH; 1,1-dimethylhydrazine, НДМГ or codenamed Geptil) is a chemical compound with the formula H2NN(CH3)2 that is used as a rocket propellant. It is a colorless liquid, with a sharp, fishy, ammonia-like smell typical for organic amines. Samples turn yellowish on exposure to air and absorb oxygen and carbon dioxide. It is miscible with water, ethanol, and kerosene. In concentration between 2.5% and 95% in air, its vapors are flammable. It is not sensitive to shock. Symmetrical dimethylhydrazine, 1,2-dimethylhydrazine is also known but is not as useful. Production UDMH is produced industrially by two routes. Based on the Olin Raschig process, one method involves reaction of monochloramine with dimethylamine giving 1,1-dimethylhydrazinium chloride: :(CH3)2NH + NH2Cl → (CH3)2NNH2 ⋅ HCl In the presence of suitable catalysts, acetylhydrazine can be N-dimethylated using formaldehyde and hydrogen to give the N,N-dimethyl-N'-acetylhydrazine, w ...
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Nitric Acid
Nitric acid is the inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but older samples tend to be yellow cast due to decomposition into oxides of nitrogen. Most commercially available nitric acid has a concentration of 68% in water. When the solution contains more than 86% , it is referred to as ''fuming nitric acid''. Depending on the amount of nitrogen dioxide present, fuming nitric acid is further characterized as red fuming nitric acid at concentrations above 86%, or white fuming nitric acid at concentrations above 95%. Nitric acid is the primary reagent used for nitration – the addition of a nitro group, typically to an organic molecule. While some resulting nitro compounds are shock- and thermally-sensitive explosives, a few are stable enough to be used in munitions and demolition, while others are still more stable and used as pigments in inks and dyes. Nitric acid is also commonly used as a strong oxidizing agen ...
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Nitrogen Dioxide
Nitrogen dioxide is a chemical compound with the formula . It is one of several nitrogen oxides. is an intermediate in the industrial synthesis of nitric acid, millions of tons of which are produced each year for use primarily in the production of fertilizers. At higher temperatures it is a reddish-brown gas. It can be fatal if inhaled in large quantities. Nitrogen dioxide is a paramagnetic, bent molecule with C2v point group symmetry. It is included in the NOx family of atmospheric pollutants. Properties Nitrogen dioxide is a reddish-brown gas with a pungent, acrid odor above , becomes a yellowish-brown liquid below , and converts to the colorless dinitrogen tetroxide () below . The bond length between the nitrogen atom and the oxygen atom is 119.7  pm. This bond length is consistent with a bond order between one and two. Unlike ozone, O3, the ground electronic state of nitrogen dioxide is a doublet state, since nitrogen has one unpaired electron, which decreases ...
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Hypergolic
A hypergolic propellant is a rocket propellant combination used in a rocket engine, whose components spontaneously ignite when they come into contact with each other. The two propellant components usually consist of a fuel and an oxidizer. The main advantages of hypergolic propellants are that they can be stored as liquids at room temperature and that engines which are powered by them are easy to ignite reliably and repeatedly. Common hypergolic propellants are difficult to handle due to their extreme toxicity and/or corrosiveness. In contemporary usage, the terms "hypergol" and "hypergolic propellant" usually mean the most common such propellant combination: dinitrogen tetroxide plus hydrazine and/or its relatives monomethylhydrazine (MMH) and unsymmetrical dimethylhydrazine (UDMH). History In 1935, Hellmuth Walter discovered that hydrazine hydrate was hypergolic with high-test peroxide of 80-83%. He was probably the first to discover this phenomenon, and set to work devel ...
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Liquid Hydrogen
Liquid hydrogen (LH2 or LH2) is the liquid state of the element hydrogen. Hydrogen is found naturally in the molecular H2 form. To exist as a liquid, H2 must be cooled below its critical point of 33  K. However, for it to be in a fully liquid state at atmospheric pressure, H2 needs to be cooled to .IPTS-1968
iupac.org, accessed 2020-01-01
A common method of obtaining liquid hydrogen involves a compressor resembling a jet engine in both appearance and principle. Liquid hydrogen is typically used as a concentrated form of . Storing it as liquid takes less space than storing it as a gas at ...
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Liquid Oxygen
Liquid oxygen—abbreviated LOx, LOX or Lox in the aerospace, submarine and gas industries—is the liquid form of molecular oxygen. It was used as the oxidizer in the first liquid-fueled rocket invented in 1926 by Robert H. Goddard, an application which has continued to the present. Physical properties Liquid oxygen has a pale blue color and is strongly paramagnetic: it can be suspended between the poles of a powerful horseshoe magnet. Liquid oxygen has a density of , slightly denser than liquid water, and is cryogenic with a freezing point of and a boiling point of at . Liquid oxygen has an expansion ratio of 1:861 under and , and because of this, it is used in some commercial and military aircraft as a transportable source of breathing oxygen. Because of its cryogenic nature, liquid oxygen can cause the materials it touches to become extremely brittle. Liquid oxygen is also a very powerful oxidizing agent: organic materials will burn rapidly and energetically in liquid o ...
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Nedelin Catastrophe
The Nedelin catastrophe or Nedelin disaster was a launch pad accident that occurred on 24 October 1960 at Baikonur test range (of which Baikonur Cosmodrome is a part), during the development of the Soviet R-16 (missile), R-16 Intercontinental ballistic missile, ICBM. As a prototype of the missile was being prepared for a test flight, an explosion occurred when the Multistage rocket, second stage engine ignited accidentally, killing an unknown number of military and technical personnel working on the preparations. Despite the magnitude of the disaster, news of it was suppressed for many years and the Soviet government did not acknowledge the event until 1989. The disaster is named after Chief marshal of the branch, Chief marshal of Artillery Mitrofan Nedelin, Mitrofan Ivanovich Nedelin, who was killed in the explosion. As commanding officer of the Soviet Union's Strategic Missile Forces, Strategic Rocket Forces, Nedelin was the head of the R-16 development program. Launch prepa ...
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Smithsonian Institution Press
The Smithsonian Institution ( ), or simply the Smithsonian, is a group of museums and education and research centers, the largest such complex in the world, created by the U.S. government "for the increase and diffusion of knowledge". Founded on August 10, 1846, it operates as a trust instrumentality and is not formally a part of any of the three branches of the federal government. The institution is named after its founding donor, British scientist James Smithson. It was originally organized as the United States National Museum, but that name ceased to exist administratively in 1967. Called "the nation's attic" for its eclectic holdings of 154 million items, the institution's 19 museums, 21 libraries, nine research centers, and zoo include historical and architectural landmarks, mostly located in the District of Columbia. Additional facilities are located in Maryland, New York, and Virginia. More than 200 institutions and museums in 45 states,States without Smithsonian A ...
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Space Program Of The Soviet Union
Space is the boundless three-dimensional extent in which objects and events have relative position and direction. In classical physics, physical space is often conceived in three linear dimensions, although modern physicists usually consider it, with time, to be part of a boundless four-dimensional continuum known as spacetime. The concept of space is considered to be of fundamental importance to an understanding of the physical universe. However, disagreement continues between philosophers over whether it is itself an entity, a relationship between entities, or part of a conceptual framework. Debates concerning the nature, essence and the mode of existence of space date back to antiquity; namely, to treatises like the ''Timaeus'' of Plato, or Socrates in his reflections on what the Greeks called ''khôra'' (i.e. "space"), or in the ''Physics'' of Aristotle (Book IV, Delta) in the definition of ''topos'' (i.e. place), or in the later "geometrical conception of place" as "sp ...
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