Cornubite
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Cornubite
Cornubite is a rare secondary copper arsenate mineral with formula: Cu5(AsO4)2(OH)4. It was first described for its discovery in 1958 in Wheal Carpenter, Gwinear, Cornwall, England, UK.Claringbull, Hey and Davis, ''American Mineralogist'' (1959) 44: 1321 The name is from Cornubia, the medieval Latin name for Cornwall. It is a dimorph of Cornwallite, and the arsenic analogue of pseudomalachite. Physical properties Cleavage is distinct in two directions, both perpendicular to the enlarged faces of the tabular crystals, intersecting at about 70°. Cornubite is fairly soft, with hardness 4, the same as fluorite, and specific gravity 4.64, which is similar to another copper arsenate, clinoclase, at 4.38, but much denser than quartz, at 2.66. Optical properties All triclinic minerals are biaxial; cornubite is biaxial (-). Its refractive indices are quite high, close to 1.9, similar to zircon and garnet. It is green, as are many copper minerals, usually translucent, with a vitreou ...
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Cornwallite
Cornwallite is an uncommon copper arsenate mineral with formula Cu5(AsO4)2(OH)4. It forms a series with the phosphate pseudomalachite and is a dimorph of the triclinic cornubite. It is a green monoclinic mineral which forms as radial to fibrous encrustations. Discovery and occurrence It was first described in 1846, for an occurrence in Wheal Gorland, St Day United Mines of the St Day District, Cornwall, England. It occurs as secondary mineral in the oxidized zone of copper sulfide deposits. Associated minerals include olivenite, cornubite, arthurite, clinoclase, chalcophyllite, strashimirite, lavendulan, tyrolite, spangolite, austinite, conichalcite, brochantite, azurite and malachite. See also * Kernowite Kernowite is a mineral which was first described in 2020. It is named for Cornwall, which in the Cornish language is ''Kernow''. Description Kernowite is a complex arsenate mineral with the composition . It was first described in 2020, and is ..., another mineral na ...
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Arsenate Minerals
Arsenate minerals usually refer to the naturally occurring orthoarsenates, possessing the (AsO4)3− anion group and, more rarely, other arsenates with anions like AsO3(OH)2− (also written HAsO42−) (example: pharmacolite Ca(AsO3OH).2H2O) or (very rarely) sO2(OH)2sup>− (example: andyrobertsite). Arsenite minerals are much less common. Both the Dana and the Strunz mineral classifications place the arsenates in with the phosphate minerals. Example arsenate minerals include: * Annabergite Ni3(AsO4)2·8H2O *Austinite CaZn(AsO4)(OH) *Clinoclase Cu3(AsO4)(OH)3 *Conichalcite CaCu(AsO4)(OH) * Cornubite Cu5(AsO4)2(OH)4 *Cornwallite Cu2+5(AsO4)2(OH)2 *Erythrite Co3(AsO4)2·8H2O *Mimetite Pb5(AsO4)3Cl * Olivenite Cu2(AsO4)OH Nickel–Strunz Classification -08- Phosphates IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses it to modify the Classification of Nickel–Strunz ( mindat.org, 10 ed, pending publication). *Abbreviations: **"*" - discredi ...
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Clinoclase
Clinoclase is a hydrous copper arsenate mineral, Cu3AsO4(OH)3. Clinoclase is a rare secondary copper mineral and forms acicular crystals in the fractured weathered zone above copper sulfide deposits. It occurs in vitreous, translucent dark blue to dark greenish blue colored crystals and botryoidal masses. The crystal system is monoclinic 2/m. It has a hardness of 2.5 - 3 and a relative density of 4.3. Associated minerals include malachite, olivenite, quartz, limonite, adamite, azurite, and brochantite among others. Clinoclase was discovered in 1830 in the county of Cornwall in England. Found at Broken Hill New South Wales, Australia and associated with copper ore deposits in Arizona, California, Montana, New Mexico, Nevada, and Utah in the United States. Also found in France, Germany, Czech Republic, Austria, Romania, Russia, and The Democratic Republic of The Congo. Abichite is another name for clinoclase. The type locality for clinoclase is the Wheal Gorland mine at St Day, Co ...
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Druse (geology)
In geology, druse refers to a coating of fine crystals on a rock fracture surface or vein or within a vug or geode. See also * Crystal habit * Miarolitic cavity Miarolitic cavities (or ''miarolitic texture'') are typically crystal-lined irregular cavities or vugs most commonly found in granitic pegmatites, and also in a variety of igneous rocks. The central portions of pegmatites are often miarolitic as ... References Mineral habits {{petrology-stub ...
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Hydrogen Bonds
In chemistry, a hydrogen bond (or H-bond) is a primarily electrostatic force of attraction between a hydrogen (H) atom which is covalently bound to a more electronegative "donor" atom or group (Dn), and another electronegative atom bearing a lone pair of electrons—the hydrogen bond acceptor (Ac). Such an interacting system is generally denoted , where the solid line denotes a polar covalent bond, and the dotted or dashed line indicates the hydrogen bond. The most frequent donor and acceptor atoms are the second-row elements nitrogen (N), oxygen (O), and fluorine (F). Hydrogen bonds can be intermolecular (occurring between separate molecules) or intramolecular (occurring among parts of the same molecule). The energy of a hydrogen bond depends on the geometry, the environment, and the nature of the specific donor and acceptor atoms and can vary between 1 and 40 kcal/mol. This makes them somewhat stronger than a van der Waals interaction, and weaker than fully covalent ...
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Hydroxyl
In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula and composed of one oxygen atom covalently bonded to one hydrogen atom. In organic chemistry, alcohols and carboxylic acids contain one or more hydroxy groups. Both the negatively charged anion , called hydroxide, and the neutral radical , known as the hydroxyl radical, consist of an unbonded hydroxy group. According to IUPAC definitions, the term ''hydroxyl'' refers to the hydroxyl radical () only, while the functional group is called a ''hydroxy group''. Properties Water, alcohols, carboxylic acids, and many other hydroxy-containing compounds can be readily deprotonated due to a large difference between the electronegativity of oxygen (3.5) and that of hydrogen (2.1). Hydroxy-containing compounds engage in intermolecular hydrogen bonding increasing the electrostatic attraction between molecules and thus to higher boiling and melting points than found for compounds that lack this f ...
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Octahedron
In geometry, an octahedron (plural: octahedra, octahedrons) is a polyhedron with eight faces. The term is most commonly used to refer to the regular octahedron, a Platonic solid composed of eight equilateral triangles, four of which meet at each vertex. A regular octahedron is the dual polyhedron of a cube. It is a rectified tetrahedron. It is a square bipyramid in any of three orthogonal orientations. It is also a triangular antiprism in any of four orientations. An octahedron is the three-dimensional case of the more general concept of a cross polytope. A regular octahedron is a 3-ball in the Manhattan () metric. Regular octahedron Dimensions If the edge length of a regular octahedron is ''a'', the radius of a circumscribed sphere (one that touches the octahedron at all vertices) is :r_u = \frac a \approx 0.707 \cdot a and the radius of an inscribed sphere (tangent to each of the octahedron's faces) is :r_i = \frac a \approx 0.408\cdot a while the midradius, which ...
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Unit Cell
In geometry, biology, mineralogy and solid state physics, a unit cell is a repeating unit formed by the vectors spanning the points of a lattice. Despite its suggestive name, the unit cell (unlike a unit vector, for example) does not necessarily have unit size, or even a particular size at all. Rather, the primitive cell is the closest analogy to a unit vector, since it has a determined size for a given lattice and is the basic building block from which larger cells are constructed. The concept is used particularly in describing crystal structure in two and three dimensions, though it makes sense in all dimensions. A lattice can be characterized by the geometry of its unit cell, which is a section of the tiling (a parallelogram or parallelepiped) that generates the whole tiling using only translations. There are two special cases of the unit cell: the primitive cell and the conventional cell. The primitive cell is a unit cell corresponding to a single lattice point, it is the ...
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Electron Microprobe
An electron microprobe (EMP), also known as an electron probe microanalyzer (EPMA) or electron micro probe analyzer (EMPA), is an analytical tool used to non-destructively determine the chemical composition of small volumes of solid materials. It works similarly to a scanning electron microscope: the sample is bombarded with an electron beam, emitting x-rays at wavelengths characteristic to the elements being analyzed. This enables the abundances of elements present within small sample volumes (typically 10-30 cubic micrometers or less) to be determined,Wittry, David B. (1958). "Electron Probe Microanalyzer"US Patent No 2916621 Washington, DC: U.S. Patent and Trademark Office when a conventional accelerating voltage of 15-20 kV is used. The concentrations of elements from lithium to plutonium may be measured at levels as low as 100 parts per million (ppm), material dependent, although with care, levels below 10 ppm are possible. The ability to quantify lithium by EPMA became a real ...
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Rotational Symmetry
Rotational symmetry, also known as radial symmetry in geometry, is the property a shape has when it looks the same after some rotation by a partial turn. An object's degree of rotational symmetry is the number of distinct orientations in which it looks exactly the same for each rotation. Certain geometric objects are partially symmetrical when rotated at certain angles such as squares rotated 90°, however the only geometric objects that are fully rotationally symmetric at any angle are spheres, circles and other spheroids. Formal treatment Formally the rotational symmetry is symmetry with respect to some or all rotations in ''m''-dimensional Euclidean space. Rotations are direct isometries, i.e., isometries preserving orientation. Therefore, a symmetry group of rotational symmetry is a subgroup of ''E''+(''m'') (see Euclidean group). Symmetry with respect to all rotations about all points implies translational symmetry with respect to all translations, so space is homo ...
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Reflection Symmetry
In mathematics, reflection symmetry, line symmetry, mirror symmetry, or mirror-image symmetry is symmetry with respect to a reflection. That is, a figure which does not change upon undergoing a reflection has reflectional symmetry. In 2D there is a line/axis of symmetry, in 3D a plane of symmetry. An object or figure which is indistinguishable from its transformed image is called mirror symmetric. In conclusion, a line of symmetry splits the shape in half and those halves should be identical. Symmetric function In formal terms, a mathematical object is symmetric with respect to a given operation such as reflection, rotation or translation, if, when applied to the object, this operation preserves some property of the object. The set of operations that preserve a given property of the object form a group. Two objects are symmetric to each other with respect to a given group of operations if one is obtained from the other by some of the operations (and vice versa). The symm ...
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Garnet
Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. All species of garnets possess similar physical properties and crystal forms, but differ in chemical composition. The different species are pyrope, almandine, spessartine, grossular (varieties of which are hessonite or cinnamon-stone and tsavorite), uvarovite and andradite. The garnets make up two solid solution series: pyrope-almandine-spessartine (pyralspite), with the composition range ; and uvarovite-grossular-andradite (ugrandite), with the composition range . Etymology The word ''garnet'' comes from the 14th-century Middle English word ''gernet'', meaning 'dark red'. It is borrowed from Old French ''grenate'' from Latin ''granatus,'' from ''granum'' ('grain, seed'). This is possibly a reference to ''mela granatum'' or even ''pomum granatum'' ('pomegranate', ''Punica granatum''), a plant whose fruits contain abundant and vivid red seed covers ( arils), whic ...
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