Chemical Warfare In World War I
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Chemical Warfare In World War I
The use of toxic chemicals as weapons dates back thousands of years, but the first large scale use of chemical weapons was during World War I. They were primarily used to demoralize, injure, and kill entrenched defenders, against whom the indiscriminate and generally very slow-moving or static nature of gas clouds would be most effective. The types of weapons employed ranged from disabling chemicals, such as tear gas, to lethal agents like phosgene, chlorine, and mustard gas. This chemical warfare was a major component of the first global war and first total war of the 20th century. The killing capacity of gas was limited, with about 90,000 fatalities from a total of 1.3 million casualties caused by gas attacks. Gas was unlike most other weapons of the period because it was possible to develop countermeasures, such as gas masks. In the later stages of the war, as the use of gas increased, its overall effectiveness diminished. The widespread use of these agents of chemical warfare, ...
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Flanders WWI Gas Attack
Flanders (, ; Dutch: ''Vlaanderen'' ) is the Flemish-speaking northern portion of Belgium and one of the communities, regions and language areas of Belgium. However, there are several overlapping definitions, including ones related to culture, language, politics, and history, and sometimes involving neighbouring countries. The demonym associated with Flanders is Fleming, while the corresponding adjective is Flemish. The official capital of Flanders is the City of Brussels, although the Brussels-Capital Region that includes it has an independent regional government. The powers of the government of Flanders consist, among others, of economic affairs in the Flemish Region and the community aspects of Flanders life in Brussels, such as Flemish culture and education. Geographically, Flanders is mainly flat, and has a small section of coast on the North Sea. It borders the French department of Nord to the south-west near the coast, the Dutch provinces of Zeeland, North Brabant and L ...
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Fragmentation (weaponry)
Fragmentation is the process by which the casing, shot, or other components of an anti-personnel weapon, bomb, barrel bomb, land mine, IED, artillery, mortar, tank gun, or autocannon shell, rocket, missile, grenade, etc. are dispersed and/or shattered by the detonation of the explosive filler. The correct term for these pieces is "fragmentation"; "shards" or "splinters" can be used for non-preformed fragments. Preformed fragments can be of various shapes (spheres, cubes, rods, etc.) and sizes, and are normally held rigidly within some form of matrix or body until the high explosive (HE) filling is detonated. The resulting high-velocity fragments produced by either method are the main lethal mechanisms of these weapons, rather than the heat or overpressure caused by detonation, although offensive grenades are often constructed without a frag matrix. These casing pieces are often incorrectly referred to as "shrapnel", particularly by non-military media sources. History The ...
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Chloroacetone
Chloroacetone is a chemical compound with the formula . At STP it is a colourless liquid with a pungent odour. On exposure to light, it turns to a dark yellow-amber colour. It was used as a tear gas in World War I. Synthesis Chloroacetone may be synthesized from the reaction between chlorine and diketene, or by the chlorination of acetone. Applications Chloroacetone is used to make dye couplers for colour photography, and is an intermediate in chemical manufacturing. It is also used in the Feist-Benary synthesis of furans. *Reaction of phenoxide with chloroacetone gives phenoxyacetone, which is used to make a wide variety of different pharmaceuticals. A catalytic amount of potassium iodide is also necessary to facilitate a Finkelstein reaction. Purification Chloroacetone purchased from commercial suppliers contains 5% impurities including mesityl oxide, which is not removed by distillation. Mesityl oxide can be oxidized using acidified KMnO4 to form a diol (followed by s ...
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Triple Entente
The Triple Entente (from French '' entente'' meaning "friendship, understanding, agreement") describes the informal understanding between the Russian Empire, the French Third Republic, and the United Kingdom of Great Britain and Ireland as well as Romania, which joined later. It was built upon the Franco-Russian Alliance of 1894, the Entente Cordiale of 1904 between Paris and London, and the Anglo-Russian Entente of 1907. It formed a powerful counterweight to the Triple Alliance of Germany, Austria-Hungary, and Italy. The Triple Entente, unlike the Triple Alliance or the Franco-Russian Alliance itself, was not an alliance of mutual defence. The Franco-Japanese Treaty of 1907 was a key part of building a coalition as France took the lead in creating alliances with Japan, Russia, and (informally) with Britain. Japan wanted to raise a loan in Paris, so France made the loan contingent on a Russo-Japanese agreement and a Japanese guarantee for France's strategically vulnerable posse ...
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Bromine
Bromine is a chemical element with the symbol Br and atomic number 35. It is the third-lightest element in group 17 of the periodic table (halogens) and is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between those of chlorine and iodine. Isolated independently by two chemists, Carl Jacob Löwig (in 1825) and Antoine Jérôme Balard (in 1826), its name was derived from the Ancient Greek (bromos) meaning "stench", referring to its sharp and pungent smell. Elemental bromine is very reactive and thus does not occur as a native element in nature but it occurs in colourless soluble crystalline mineral halide salts, analogous to table salt. In fact, bromine and all the halogens are so reactive that they form bonds in pairs—never in single atoms. While it is rather rare in the Earth's crust, the high solubility of the bromide ion (Br) has caused its accumulation in the oceans. Commercial ...
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Ethyl Bromoacetate
Ethyl bromoacetate is the chemical compound with the formula CH2BrCO2C2H5. It is the ethyl ester of bromoacetic acid and is prepared in two steps from acetic acid. It is a lachrymator and has a fruity, pungent odor. It is also a highly toxic alkylating agent and may be fatal if inhaled. Applications Ethyl bromoacetate is listed by the World Health Organization as a riot control agent, and was first employed for that purpose by French police in 1912. The French army used rifle grenades 'grenades lacrymogènes' filled with this gas against the Germans beginning in August 1914, but the weapons were largely ineffective, even though ethyl bromoacetate is twice as toxic as chlorine. In the early months of the war the British also used the weaponized use of tear gas agents and more toxic gasses including sulfur dioxide. The German army then used these attacks to justify their subsequent employment of it as odorant or warning agent in odorless, toxic gases and chemical weapons in 1915 und ...
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Grenade
A grenade is an explosive weapon typically thrown by hand (also called hand grenade), but can also refer to a shell (explosive projectile) shot from the muzzle of a rifle (as a rifle grenade) or a grenade launcher. A modern hand grenade generally consists of an explosive charge ("filler"), a detonator mechanism, an internal striker to trigger the detonator, and a safety lever secured by a cotter pin. The user removes the safety pin before throwing, and once the grenade leaves the hand the safety lever gets released, allowing the striker to trigger a primer that ignites a fuze (sometimes called the delay element), which burns down to the detonator and explodes the main charge. Grenades work by dispersing fragments (fragmentation grenades), shockwaves (high-explosive, anti-tank and stun grenades), chemical aerosols (smoke and gas grenades) or fire ( incendiary grenades). Fragmentation grenades ("frags") are probably the most common in modern armies, and when the word ''gren ...
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French Army In World War I
During World War I, France was one of the Triple Entente powers allied against the Central Powers. Although fighting occurred worldwide, the bulk of the conflict in Europe occurred in Belgium, Luxembourg, France and Alsace-Lorraine along what came to be known as the Western Front, which consisted mainly of trench warfare. Specific operational, tactical, and strategic decisions by the high command on both sides of the conflict led to shifts in organizational capacity, as the French Army tried to respond to day-to-day fighting and long-term strategic and operational agendas. In particular, many problems caused the French high command to re-evaluate standard procedures, revise its command structures, re-equip the army, and to develop different tactical approaches. Background France had been the major power in Europe for most of the Early Modern Era: Louis XIV, in the seventeenth century, and Napoleon I in the nineteenth, had extended French power over most of Europe through skill ...
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Tear Gas
Tear gas, also known as a lachrymator agent or lachrymator (), sometimes colloquially known as "mace" after the early commercial aerosol, is a chemical weapon that stimulates the nerves of the lacrimal gland in the eye to produce tears. In addition, it can cause severe eye and respiratory pain, skin irritation, bleeding, and blindness. Common lachrymators both currently and formerly used as tear gas include pepper spray (OC gas), PAVA spray (nonivamide), CS gas, CR gas, CN gas (phenacyl chloride), bromoacetone, xylyl bromide and Mace (a branded mixture). While lachrymatory agents are commonly deployed for riot control by law enforcement and military personnel, its use in warfare is prohibited by various international treaties.E.g. the Geneva Protocol of 1925 prohibited the use of "asphyxiating gas, or any other kind of gas, liquids, substances or similar materials". During World War I, increasingly toxic and deadly lachrymatory agents were used. The short and long-term effec ...
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History Of Chemical Warfare
Chemical weapons have been a part of warfare in most societies, although their use has been particularly controversial since the 20th century. Ancient and medieval times Ancient Greek myths about Heracles poisoning his arrows with the venom of the Hydra monster are the earliest references to toxic weapons in western literature. Homer's epics, the ''Iliad'' and the ''Odyssey'', allude to poisoned arrows used by both sides in the legendary Trojan War (Bronze Age Greece).Adrienne Mayor, "Greek Fire, Poison Arrows & Scorpion Bombs: Biological and Chemical Warfare in the Ancient World" Overlook-Duckworth, 2003, rev ed with new Introduction 2008 Some of the earliest surviving references to toxic warfare appear in the Indian epics ''Ramayana'' and ''Mahabharata.'' The "Laws of Manu," a Hindu treatise on statecraft (c. 400 BC) forbids the use of poison and fire arrows, but advises poisoning food and water. Kautilya's "Arthashastra", a statecraft manual of the same era, contains hundreds ...
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University Of Washington Press
The University of Washington Press is an American academic publishing house. The organization is a division of the University of Washington, based in Seattle. Although the division functions autonomously, they have worked to assist the university's efforts in support of the Burke Museum of Natural History and Culture, the Henry M. Jackson School of International Studies, and the Center for Innovation and Research in Graduate Education. Since 1915, they have published the works of first-time writers, including students, poets, and artists, along with authors known throughout the world for their work in the humanities, arts, and sciences. While the day-to-day functions of the organization are carried out independent of the university, the imprint itself is managed by a committee of faculty members, who have been appointed by the university president. Each manuscript must go through a collaborative approval process overseen by the editors and the University Press Committee before b ...
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