Calcium Magnesium Acetate
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Calcium Magnesium Acetate
Calcium magnesium acetate (CMA) is a deicer and can be used as an alternative to road salt. It is approximately as corrosive as normal tap water, and in varying concentrations can be effective in stopping road ice from forming down to around (its eutectic temperature). CMA can also be used as an H2S capture agent. Production CMA can be produced from a reaction of a magnesium/calcium compound with glacial acetic acid. If it is reacted with dolomite or dolomitic lime, acetic acid does not need to be concentrated to produce CMA. Acetic acid production requires the fermentation of organic material which must be carried out at a pH around 6.0. Separating agents used to recover acetic acid must therefore maintain a high capacity while within this pH range. Amberlite LA-2 in 1-octanol diluent maintains nearly full capacity up to a pH value of 6.0 and is readily regenerated by aqueous, slaked dolomitic lime to form CMA, making it a good acetic acid separating agent for CMA production. Use ...
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De-ice
Deicing is the process of removing snow, ice or frost from a surface. Anti-icing is the application of chemicals that not only deice but also remain on a surface and continue to delay the reformation of ice for a certain period of time, or prevent adhesion of ice to make mechanical removal easier. Deicing can be accomplished by mechanical methods (scraping, pushing); through the application of heat; by use of dry or liquid chemicals designed to lower the freezing point of water (various salts or brines, alcohols, glycols); or by a combination of these different techniques. Application areas Roadways In 2013, an estimated 14 million tons of salt were used for deicing roads in North America. Deicing of roads has traditionally been done with salt, spread by snowplows or dump trucks designed to spread it, often mixed with sand and gravel, on slick roads. Sodium chloride (rock salt) is normally used, as it is inexpensive and readily available in large quantities. However, sinc ...
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Road Salt
Sodium chloride , commonly known as salt (although sea salt also contains other chemical salts), is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chloride ions. With molar masses of 22.99 and 35.45 g/mol respectively, 100 g of NaCl contains 39.34 g Na and 60.66 g Cl. Sodium chloride is the salt most responsible for the salinity of seawater and of the extracellular fluid of many multicellular organisms. In its edible form, salt (also known as ''table salt'') is commonly used as a condiment and food preservative. Large quantities of sodium chloride are used in many industrial processes, and it is a major source of sodium and chlorine compounds used as feedstocks for further chemical syntheses. Another major application of sodium chloride is de-icing of roadways in sub-freezing weather. Uses In addition to the familiar domestic uses of salt, more dominant applications of the approximately 250 million tonnes per year production (2008 da ...
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Tap Water
Tap water (also known as faucet water, running water, or municipal water) is water supplied through a tap, a water dispenser valve. In many countries, tap water usually has the quality of drinking water. Tap water is commonly used for drinking, cooking, washing, and toilet flushing. Indoor tap water is distributed through "indoor plumbing", which has existed since antiquity but was available to very few people until the second half of the 19th century when it began to spread in popularity in what are now developed countries. Tap water became common in many regions during the 20th century, and is now lacking mainly among people in poverty, especially in developing countries. Governmental agencies commonly regulate tap water quality. Household water purification methods such as water filters, boiling, or distillation can be used to treat tap water's microbial contamination to improve its potability. The application of technologies (such as water treatment plants) involved in pr ...
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Eutectic Temperature
A eutectic system or eutectic mixture ( ) is a homogeneous mixture that has a melting point lower than those of the constituents. The lowest possible melting point over all of the mixing ratios of the constituents is called the ''eutectic temperature''. On a phase diagram, the eutectic temperature is seen as the eutectic point (see plot on the right). Non-eutectic mixture ratios would have different melting temperatures for their different constituents, since one component's lattice will melt at a lower temperature than the other's. Conversely, as a non-eutectic mixture cools down, each of its components would solidify (form a lattice) at a different temperature, until the entire mass is solid. Not all binary alloys have eutectic points, since the valence electrons of the component species are not always compatible, in any mixing ratio, to form a new type of joint crystal lattice. For example, in the silver-gold system the melt temperature (liquidus) and freeze temperature (so ...
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Glacial Acetic Acid
Acetic acid , systematically named ethanoic acid , is an acidic, colourless liquid and organic compound with the chemical formula (also written as , , or ). Vinegar is at least 4% acetic acid by volume, making acetic acid the main component of vinegar apart from water and other trace elements. Acetic acid is the second simplest carboxylic acid (after formic acid). It is an important chemical reagent and industrial chemical, used primarily in the production of cellulose acetate for photographic film, polyvinyl acetate for wood glue, and synthetic fibres and fabrics. In households, diluted acetic acid is often used in descaling agents. In the food industry, acetic acid is controlled by the food additive code E260 as an acidity regulator and as a condiment. In biochemistry, the acetyl group, derived from acetic acid, is fundamental to all forms of life. When bound to coenzyme A, it is central to the metabolism of carbohydrates and fats. The global demand for acetic acid is ...
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Dolomite (rock)
Dolomite (also known as dolomite rock, dolostone or dolomitic rock) is a sedimentary carbonate rock that contains a high percentage of the mineral dolomite, CaMg(CO3)2. It occurs widely, often in association with limestone and evaporites, though it is less abundant than limestone and rare in Cenozoic rock beds (beds less than about 66 million years in age). The first geologist to distinguish dolomite rock from limestone was Belsazar Hacquet in 1778. Most dolomite was formed as a magnesium replacement of limestone or of lime mud before lithification. The geological process of conversion of calcite to dolomite is known as dolomitization and any intermediate product is known as dolomitic limestone. The "dolomite problem" refers to the vast worldwide depositions of dolomite in the past geologic record in contrast to the limited amounts of dolomite formed in modern times. Recent research has revealed sulfate-reducing bacteria living in anoxic conditions precipitate dolomite which ind ...
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Journal Of Policy Analysis And Management
The ''Journal of Policy Analysis and Management'' is a quarterly peer-reviewed academic journal covering issues and practices in policy analysis and public management. It was established in 1981 and contains books reviews and a department devoted to discussing ideas and issues of importance to practitioners, researchers, and academics. It is the official journal of the Association for Public Policy Analysis and Management and published by Wiley-Blackwell. The current editor-in-chief is Erdal Tekin. According to the ''Journal Citation Reports'', the journal has a 2017 impact factor of 3.444, ranking it 27th out of 353 journals in the category "Economics" and 5th out of 47 journals in the category "Public Administration". History The Association for Public Policy Analysis and Management established the ''Journal of Policy Analysis and Management'' in 1981 through the merger of two other journals – ''Policy Analysis'' (1975-1981) and ''Public Policy'' (1940-1981). Editors-in-c ...
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Cenosphere
A cenosphere is a lightweight, inert, hollow sphere made largely of silica and alumina and filled with air or inert gas, typically produced as a coal combustion byproduct at thermal power plants. The color of cenospheres varies from gray to almost white and their density is about , which gives them a great buoyancy. Cenospheres are hard and rigid, light, waterproof and insulative. This makes them highly useful in a variety of products, notably fillers. Cenospheres are now used as fillers in cement to produce low-density concrete. A 2016 article reports that some manufacturers have begun filling metals and polymers with cenospheres to make lightweight composite materials with higher strength than other types of foam materials. Such composite materials are called syntactic foam. Aluminum-based syntactic foams are finding applications in the automotive sector. Silver-coated cenospheres are used in conductive coatings, tiles and fabrics. Another use is in conductive paints for ant ...
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Hydrogen Sulfide
Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is poisonous, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs. The underground mine gas term for foul-smelling hydrogen sulfide-rich gas mixtures is ''stinkdamp''. Swedish chemist Carl Wilhelm Scheele is credited with having discovered the chemical composition of purified hydrogen sulfide in 1777. The British English spelling of this compound is hydrogen sulphide, a spelling no longer recommended by the Royal Society of Chemistry or the International Union of Pure and Applied Chemistry. Hydrogen sulfide is toxic to humans and most other animals by inhibiting cellular respiration in a manner similar to hydrogen cyanide. When it is inhaled or it or its salts are ingested in high amounts, damage to organs occurs rapidly with symptoms ranging from breathing difficulties to convulsions and death. Despite this, the ...
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Integrated Gasification Combined Cycle
integrated gasification combined cycle (IGCC) is a technology using a high pressure gasifier to turn coal and other carbon based fuels into pressurized gas—synthesis gas ( syngas). It can then remove impurities from the syngas prior to the electricity generation cycle. Some of these pollutants, such as sulfur, can be turned into re-usable byproducts through the Claus process. This results in lower emissions of sulfur dioxide, particulates, mercury, and in some cases carbon dioxide. With additional process equipment, a water-gas shift reaction can increase gasification efficiency and reduce carbon monoxide emissions by converting it to carbon dioxide. The resulting carbon dioxide from the shift reaction can be separated, compressed, and stored through sequestration. Excess heat from the primary combustion and syngas fired generation is then passed to a steam cycle, similar to a combined cycle gas turbine. This process results in improved thermodynamic efficiency compared to co ...
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Coal
Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when dead plant matter decays into peat and is converted into coal by the heat and pressure of deep burial over millions of years. Vast deposits of coal originate in former wetlands called coal forests that covered much of the Earth's tropical land areas during the late Carboniferous ( Pennsylvanian) and Permian times. Many significant coal deposits are younger than this and originate from the Mesozoic and Cenozoic eras. Coal is used primarily as a fuel. While coal has been known and used for thousands of years, its usage was limited until the Industrial Revolution. With the invention of the steam engine, coal consumption increased. In 2020, coal supplied about a quarter of the world's primary energy and over a third of its electricity. Some iron ...
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Gas Turbine
A gas turbine, also called a combustion turbine, is a type of continuous flow internal combustion engine. The main parts common to all gas turbine engines form the power-producing part (known as the gas generator or core) and are, in the direction of flow: * a rotating gas compressor * a combustor * a compressor-driving turbine. Additional components have to be added to the gas generator to suit its application. Common to all is an air inlet but with different configurations to suit the requirements of marine use, land use or flight at speeds varying from stationary to supersonic. A propelling nozzle is added to produce thrust for flight. An extra turbine is added to drive a propeller (turboprop) or ducted fan (turbofan) to reduce fuel consumption (by increasing propulsive efficiency) at subsonic flight speeds. An extra turbine is also required to drive a helicopter rotor or land-vehicle transmission (turboshaft), marine propeller or electrical generator (power turbine). Greater ...
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