COLEX Process
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COLEX Process
The COLEX process (or COLEX separation) is a chemical method of isotopic separation of lithium-6 and lithium-7, based on the use of mercury. COLEX stands for column exchange. Since the beginning of the atomic era, a variety of lithium enrichments methods have been developed (such as chemical exchange, electromagnetic, laser, centrifugal) and the COLEX process has been the most extensively implemented method so far. Early development In the US, several chemical exchange methods for lithium isotope separation have been under investigation in the 1930s and 1940s to develop a process for lithium-6 production, so that tritium could be obtained for thermonuclear weapons research. The system finally selected was the COLEX process, with aqueous lithium hydroxide (LiOH) contacted with lithium-mercury amalgam. This process was initially used in the US between 1955 and 1963 in the Y12 plant in Oak Ridge, Tennessee. The COLEX plants in Oak Ridge had a very rough start in 1955 with major pr ...
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Isotopic Separation
Isotope separation is the process of concentrating specific isotopes of a chemical element by removing other isotopes. The use of the nuclides produced is varied. The largest variety is used in research (e.g. in chemistry where atoms of "marker" nuclide are used to figure out reaction mechanisms). By tonnage, separating natural uranium into enriched uranium and depleted uranium is the largest application. In the following text, mainly the uranium enrichment is considered. This process is crucial in the manufacture of uranium fuel for nuclear power plants, and is also required for the creation of uranium-based nuclear weapons. Plutonium-based weapons use plutonium produced in a nuclear reactor, which must be operated in such a way as to produce plutonium already of suitable isotopic mix or ''grade''. While different chemical elements can be purified through chemical processes, isotopes of the same element have nearly identical chemical properties, which makes this type of separati ...
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Lithium Element
Lithium (from el, λίθος, lithos, lit=stone) is a chemical element with the symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense solid element. Like all alkali metals, lithium is highly reactive and flammable, and must be stored in vacuum, inert atmosphere, or inert liquid such as purified kerosene or mineral oil. When cut, it exhibits a metallic luster, but moist air corrodes it quickly to a dull silvery gray, then black tarnish. It never occurs freely in nature, but only in (usually ionic) compounds, such as pegmatitic minerals, which were once the main source of lithium. Due to its solubility as an ion, it is present in ocean water and is commonly obtained from brines. Lithium metal is isolated electrolytically from a mixture of lithium chloride and potassium chloride. The nucleus of the lithium atom verges on instability, since the two stable lithium isotopes fou ...
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Isotopes Of Lithium
Naturally occurring lithium (3Li) is composed of two stable isotopes, lithium-6 and lithium-7, with the latter being far more abundant on Earth. Both of the natural isotopes have an unexpectedly low nuclear binding energy per nucleon ( for lithium-6 and for lithium-7) when compared with the adjacent lighter and heavier elements, helium ( for helium-4) and beryllium ( for beryllium-9). The longest-lived radioisotope of lithium is lithium-8, which has a half-life of just . Lithium-9 has a half-life of , and lithium-11 has a half-life of . All of the remaining isotopes of lithium have half-lives that are shorter than 10 nanoseconds. The shortest-lived known isotope of lithium is lithium-4, which decays by proton emission with a half-life of about (), although the half-life of lithium-3 is yet to be determined, and is likely to be much shorter, like helium-2 (diproton) which undergoes proton emission within s. Lithium-7 and lithium-6 are two of the primordial nuclides that wer ...
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ITER
ITER (initially the International Thermonuclear Experimental Reactor, ''iter'' meaning "the way" or "the path" in Latin) is an international nuclear fusion research and engineering megaproject aimed at creating energy by replicating, on Earth, the fusion processes of the Sun. Upon completion of construction of the main reactor and first plasma, planned for late 2025, it will be the world's largest magnetic confinement plasma physics experiment and the largest experimental tokamak nuclear fusion reactor. It is being built next to the Cadarache facility in southern France. ITER will be the largest of more than 100 fusion reactors built since the 1950s, with ten times the plasma volume of any other tokamak operating today. The long-term goal of fusion research is to generate electricity. ITER's stated purpose is scientific research, and technological demonstration of a large fusion reactor, without electricity generation. ITER's goals are to achieve enough fusion to produce 10 ti ...
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Fusion Power
Fusion power is a proposed form of power generation that would generate electricity by using heat from nuclear fusion, nuclear fusion reactions. In a fusion process, two lighter atomic nucleus, atomic nuclei combine to form a heavier nucleus, while releasing energy. Devices designed to harness this energy are known as fusion reactors. Research into fusion reactors began in the 1940s, but as of 2022, only one design, an Inertial confinement fusion, inertial confinement laser-driven fusion machine at the US National Ignition Facility, has conclusively produced a positive fusion energy gain factor, i.e. more power output than input. Fusion processes require fuel and a confined environment with sufficient temperature, pressure, and confinement time to create a plasma (physics), plasma in which fusion can occur. The combination of these figures that results in a power-producing system is known as the Lawson criterion. In stars, the most common fuel is hydrogen, and gravity provides ext ...
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Thermonuclear Bomb
A thermonuclear weapon, fusion weapon or hydrogen bomb (H bomb) is a second-generation nuclear weapon design. Its greater sophistication affords it vastly greater destructive power than first-generation nuclear bombs, a more compact size, a lower mass, or a combination of these benefits. Characteristics of nuclear fusion reactions make possible the use of non-fissile depleted uranium as the weapon's main fuel, thus allowing more efficient use of scarce fissile material such as uranium-235 () or plutonium-239 (). The first full-scale thermonuclear test was carried out by the United States in 1952; the concept has since been employed by most of the world's nuclear powers in the design of their weapons. Modern fusion weapons consist essentially of two main components: a nuclear fission primary stage (fueled by or ) and a separate nuclear fusion secondary stage containing thermonuclear fuel: the heavy hydrogen isotopes deuterium and tritium, or in modern weapons lithium deuteride. ...
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Pressurized Water Reactor
A pressurized water reactor (PWR) is a type of light-water reactor, light-water nuclear reactor. PWRs constitute the large majority of the world's nuclear power plants (with notable exceptions being the UK, Japan and Canada). In a PWR, the primary nuclear reactor coolant, coolant (water) is pumped under high pressure to the reactor core where it is heated by the energy released by the Nuclear fission, fission of atoms. The heated, high pressure water then flows to a Water-tube boiler, steam generator, where it transfers its thermal energy to lower pressure water of a secondary system where steam is generated. The steam then drives turbines, which spin an electric generator. In contrast to a boiling water reactor (BWR), pressure in the primary coolant loop prevents the water from boiling within the reactor. All light-water reactors use ordinary water as both coolant and neutron moderator. Most use anywhere from two to four vertically mounted steam generators; VVER reactors use horizo ...
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Molten Salt Reactor
A molten salt reactor (MSR) is a class of nuclear fission reactor in which the primary nuclear reactor coolant and/or the fuel is a molten salt mixture. Only two MSRs have ever operated, both research reactors in the United States. The 1950's Aircraft Reactor Experiment was primarily motivated by the compact size that the technique offers, while the 1960's Molten-Salt Reactor Experiment aimed to prove the concept of a nuclear power plant which implements a thorium fuel cycle in a breeder reactor. Increased research into Generation IV reactor designs began to renew interest in the technology, with multiple nations having projects, and , China is on the verge of starting its TMSR-LF1 thorium MSR. MSRs are considered safer than conventional reactors because they operate with fuel already in a molten state, and in some designs in the event of an emergency, the fuel mixture is designed to drain from the core to a containment vessel where it will solidify in fuel drain tanks. This pre ...
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Electric Vehicles
An electric vehicle (EV) is a vehicle that uses one or more electric motors for propulsion. It can be powered by a collector system, with electricity from extravehicular sources, or it can be powered autonomously by a battery (sometimes charged by solar panels, or by converting fuel to electricity using fuel cells or a generator). EVs include, but are not limited to, road and rail vehicles, surface and underwater vessels, electric aircraft and electric spacecraft. For road vehicles, together with other emerging automotive technologies such as autonomous driving, connected vehicles and shared mobility, EVs form a future mobility vision called Connected, Autonomous, Shared and Electric (CASE) Mobility. EVs first came into existence in the late 19th century, when electricity was among the preferred methods for motor vehicle propulsion, providing a level of comfort and ease of operation that could not be achieved by the gasoline cars of the time. Internal combustion en ...
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Li-ion Batteries
A lithium-ion or Li-ion battery is a type of rechargeable battery which uses the reversible reduction of lithium ions to store energy. It is the predominant battery type used in portable consumer electronics and electric vehicles. It also sees significant use for grid-scale energy storage and military and aerospace applications. Compared to other rechargeable battery technologies, Li-ion batteries have high energy densities, low self-discharge, and no memory effect (although a small memory effect reported in LFP cells has been traced to poorly made cells). Chemistry, performance, cost and safety characteristics vary across types of lithium-ion batteries. Most commercial Li-ion cells use intercalation compounds as the active materials. The anode or negative electrode is usually graphite, although silicon-carbon is also being increasingly used. Cells can be manufactured to prioritize either energy or power density. Handheld electronics mostly use lithium polymer batteries ...
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Nuclear Programme Of South Africa
As a member of the nuclear non-proliferation treaty, South Africa uses nuclear science for peaceful means. South Africa's nuclear programme includes both nuclear energy and nuclear medicine. In the past there was also a military component, and South Africa previously possessed nuclear weapons, which were subsequently dismantled. Nuclear energy Koeberg The Koeberg nuclear power station is the only nuclear power station in South Africa and contains two uranium pressurized water reactors based on a design by Framatome of France. The station is located 30 km north of Cape Town. The plant is owned and operated by the country's national electricity supplier, Eskom. PBMR The Pebble bed modular reactor (PBMR) was a particular design of pebble-bed reactor under development by South African company PBMR (Pty) Ltd since 1994. The project entailed the construction of a demonstration power plant at Koeberg near Cape Town and a fuel plant at Pelindaba near Pretoria. Government ...
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Lithium-6
Naturally occurring lithium (3Li) is composed of two stable isotopes, lithium-6 and lithium-7, with the latter being far more abundant on Earth. Both of the natural isotopes have an unexpectedly low nuclear binding energy per nucleon ( for lithium-6 and for lithium-7) when compared with the adjacent lighter and heavier elements, helium ( for helium-4) and beryllium ( for beryllium-9). The longest-lived radioisotope of lithium is lithium-8, which has a half-life of just . Lithium-9 has a half-life of , and lithium-11 has a half-life of . All of the remaining isotopes of lithium have half-lives that are shorter than 10 nanoseconds. The shortest-lived known isotope of lithium is lithium-4, which decays by proton emission with a half-life of about (), although the half-life of lithium-3 is yet to be determined, and is likely to be much shorter, like helium-2 (diproton) which undergoes proton emission within s. Lithium-7 and lithium-6 are two of the primordial nuclides that were ...
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