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CCS And Climate Change Mitigation
Carbon capture and storage (CCS) or carbon capture and sequestration is the process of capturing carbon dioxide (CO2) before it enters the atmosphere, transporting it, and storing it (carbon sequestration) for centuries or millennia. Usually the CO2 is captured from large point sources, such as a chemical plant or biomass power plant, and then stored in an underground geological formation. The aim is to prevent the release of CO2 from heavy industry with the intent of mitigating the effects of climate change. CO2 has been injected into geological formations for several decades for enhanced oil recovery and after separation from natural gas, but this has been criticised for producing more emissions when the gas or oil is burned. Carbon capture and utilization (CCU) and CCS are sometimes discussed collectively as carbon capture, utilization, and sequestration (CCUS). This is because CCS is a relatively expensive process yielding a product which is often too cheap. Hence, carbon ...
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Flue Gas
Flue gas is the gas exiting to the atmosphere via a flue, which is a pipe or channel for conveying exhaust gases from a fireplace, oven, furnace, boiler or steam generator. Quite often, the flue gas refers to the combustion exhaust gas produced at power plants. Its composition depends on what is being burned, but it will usually consist of mostly nitrogen (typically more than two-thirds) derived from the combustion of air, carbon dioxide (), and water vapor as well as excess oxygen (also derived from the combustion air). It further contains a small percentage of a number of pollutants, such as particulate matter (like soot), carbon monoxide, nitrogen oxides, and sulfur oxides. Most fossil fuels are combusted with ambient air (as differentiated from combustion with pure oxygen). Since ambient air contains about 79 volume percent gaseous nitrogen (N2), which is essentially non-combustible, the largest part of the flue gas from most fossil-fuel combustion is uncombusted nitr ...
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Absorption (chemistry)
In chemistry, absorption is a physical or chemical phenomenon or a process in which atoms, molecules or ions enter some bulk phase – liquid or solid material. This is a different process from adsorption, since molecules undergoing absorption are taken up by the volume, not by the surface (as in the case for adsorption). A more common definition is that "Absorption is a chemical or physical phenomenon in which the molecules, atoms and ions of the substance getting absorbed enters into the bulk phase (gas, liquid or solid) of the material in which it is taken up." A more general term is '' sorption'', which covers absorption, adsorption, and ion exchange. Absorption is a condition in which something takes in another substance. In many processes important in technology, the chemical absorption is used in place of the physical process, e.g., absorption of carbon dioxide by sodium hydroxide – such acid-base processes do not follow the Nernst partition law (see: solubilit ...
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Fossil Fuel Power Plant
A fossil fuel power station is a thermal power station which burns a fossil fuel, such as coal or natural gas, to produce electricity. Fossil fuel power stations have machinery to convert the heat energy of combustion into mechanical energy, which then operates an electrical generator. The prime mover may be a steam turbine, a gas turbine or, in small plants, a reciprocating gas engine. All plants use the energy extracted from the expansion of a hot gas, either steam or combustion gases. Although different energy conversion methods exist, all thermal power station conversion methods have their efficiency limited by the Carnot efficiency and therefore produce waste heat. Fossil fuel power stations provide most of the electrical energy used in the world. Some fossil-fired power stations are designed for continuous operation as baseload power plants, while others are used as peaker plants. However, starting from the 2010s, in many countries plants designed for baseload supply are ...
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Post Combustion Capture
Post-combustion capture refers to the removal of ''CO2'' from power station flue gas prior to its compression, transportation and storage in suitable geological formations, as part of carbon capture and storage. A number of different techniques are applicable, almost all of which are adaptations of acid gas removal processes used in the chemical and petrochemical industries. Many of these techniques existed before World War II and, consequently, post-combustion capture is the most developed of the various carbon-capture methodologies. Calcium looping is a promising second generation post-combustion capture technology in which calcium oxide, often referred to as the ''sorbent'', is used to separate CO2 from the flue gas. ThANICA projectfocuses on developing a novel indirectly heated carbonate lopping process for lowering the energy penalty and CO2 avoidance costs for CO2 capture from lime and cement plants. See also * Acid gas Acid gas is a particular typology of natural gas or an ...
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Hydrogen Production
Hydrogen production is the family of industrial methods for generating hydrogen gas. As of 2020, the majority of hydrogen (∼95%) is produced from fossil fuels by steam reforming of natural gas and other light hydrocarbons, partial oxidation of heavier hydrocarbons, and coal gasification. Other methods of hydrogen production include biomass gasification, zero-CO2-emission methane pyrolysis, and electrolysis of water. The latter processes, methane pyrolysis as well as water electrolysis can be done directly with any source of electricity, such as solar power. The production of hydrogen plays a key role in any industrialized society, since hydrogen is required for many essential chemical processes. In 2020, roughly 87 million tons of hydrogen was produced worldwide for various uses, such as oil refining, and in the production of ammonia (NH3) (through the Haber process) and methanol (CH3OH) (through reduction of carbon monoxide O, and also as a fuel in transportation. The glob ...
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Natural Gas Processing
Natural-gas processing is a range of industrial processes designed to purify raw natural gas by removing impurities, contaminants and higher molecular mass hydrocarbons to produce what is known as ''pipeline quality'' dry natural gas. Natural gas has to be processed in order to prepare it for final use and ensure that elimination of contaminants. Natural-gas processing starts underground or at the well-head. If the gas is being produced, for instance, alongside crude oil, the separation process already transpires as the fluid flows through the reservoir rocks until it reaches the well tubing. The process beginning at the wellhead extracts the composition of natural gas according to the type, depth, and location of the underground deposit and the geology of the area. Oil and natural gas are often found together in the same reservoir. The natural gas produced from oil wells is generally classified as ''associated-dissolved gas'' meaning that the gas had been associated with or dis ...
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FutureGen
FutureGen was a project to demonstrate capture and sequestration of waste carbon dioxide from a coal-fired electrical generating station. The project (renamed FutureGen 2.0) was retrofitting a shuttered coal-fired power plant in Meredosia, Illinois, with oxy-combustion generators. The waste CO2 would be piped approximately to be sequestered in underground saline formations. FutureGen was a partnership between the United States government and an alliance of primarily coal-related corporations. Costs were estimated at US$1.65 billion, with $1.0 billion provided by the Federal Government. First announced by President George W. Bush in 2003, construction started in 2014 after restructuring, canceling, relocating, and restarting. Citing an inability to commit and spend the funds by deadlines in 2015, the Department of Energy withdrew funds and suspended FutureGen 2.0 in February, 2015. The government also cited the Alliance's inability to raise the requisite amount of pri ...
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National Energy Technology Laboratory
The National Energy Technology Laboratory (NETL) is a U.S national laboratory under the Department of Energy Office of Fossil Energy. NETL focuses on applied research for the clean production and use of domestic energy resources. NETL performs research and development on the supply, efficiency, and environmental constraints of producing and using fossil energy resources, while maintaining their affordability. NETL has sites in Albany, Oregon; Morgantown, West Virginia; and Pittsburgh, Pennsylvania. Together, these sites have 117 buildings and 242 acres of land. More than 1,400 employees work at NETL's three sites, including federal employees and contractors. NETL funds and manages contracted research in the United States and more than 40 foreign countries through arrangements with both private organizations and other government agencies. This work is augmented by onsite applied research in computational and basic sciences, energy system dynamics, geological and environmental ...
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Pyrogenic Carbon Capture And Storage
Pyrogenic carbon capture and storage (PyCCS) is a proposed carbon sequestration technology that can mitigate climate change while improving soil fertility. It is discussed as a promising technology for greenhouse gas removal.Constanze Werner et al. (2018): ''Biogeochemical potential of biomass pyrolysis systems for limiting global warming to 1.5° C.'' Environmental Research Letters, 13(4), 044036. Principle The principle of PyCCS is that the biomass (e.g. trees) removes CO2 from the atmosphere during its growth via photosynthesis. This biomass is then harvested and pyrolyzed (see below), with a portion of the carbon dioxide bound in the biomass being captured in the ground, after being reduced to carbon and viscous compounds (charcoal). The flammable gas mixture, which is the lightest fraction in pyrolysis, is collected and used as fuel; the carbon dioxide produced when combusting it is captured traditionally. Technology Pyrolysis in the context of carbon capture and stora ...
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Carbonate
A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate group C(=O)(O–)2. The term is also used as a verb, to describe carbonation: the process of raising the concentrations of carbonate and bicarbonate ions in water to produce carbonated water and other carbonated beverageseither by the addition of carbon dioxide gas under pressure or by dissolving carbonate or bicarbonate salts into the water. In geology and mineralogy, the term "carbonate" can refer both to carbonate minerals and carbonate rock (which is made of chiefly carbonate minerals), and both are dominated by the carbonate ion, . Carbonate minerals are extremely varied and ubiquitous in chemically precipitated sedimentary rock. The most common are calcite or calcium carbonate, CaCO3, the chief constituent of limestone (as we ...
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Mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Minerals'; p. 1. In the series ''Geology: Landforms, Minerals, and Rocks''. Rosen Publishing Group. The Geology, geological definition of mineral normally excludes compounds that occur only in living organisms. However, some minerals are often biogenic (such as calcite) or are organic compounds in the sense of chemistry (such as mellite). Moreover, living organisms often synthesize inorganic minerals (such as hydroxylapatite) that also occur in rocks. The concept of mineral is distinct from rock (geology), rock, which is any bulk solid geologic material that is relatively homogeneous at a large enough scale. A rock may consist of one type of mineral, or may be an aggregate (geology), aggregate of two or more different types of m ...
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Gas Hydrate
Clathrate hydrates, or gas hydrates, clathrates, hydrates, etc., are crystalline water-based solids physically resembling ice, in which small non-polar molecules (typically gases) or polar molecules with large hydrophobic moieties are trapped inside "cages" of hydrogen bonded, frozen water molecules. In other words, clathrate hydrates are clathrate compounds in which the host molecule is water and the guest molecule is typically a gas or liquid. Without the support of the trapped molecules, the lattice structure of hydrate clathrates would collapse into conventional ice crystal structure or liquid water. Most low molecular weight gases, including , , , , , , , , and , as well as some higher hydrocarbons and freons, will form hydrates at suitable temperatures and pressures. Clathrate hydrates are not officially chemical compounds, as the enclathrated guest molecules are never bonded to the lattice. The formation and decomposition of clathrate hydrates are first order pha ...
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