Tellurium(VI) Compounds
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Tellurium(VI) Compounds
Tellurium is a chemical element with the symbol Te and atomic number 52. It is a brittle, mildly toxic, rare, silver-white metalloid. Tellurium is chemically related to selenium and sulfur, all three of which are chalcogens. It is occasionally found in native form as elemental crystals. Tellurium is far more common in the Universe as a whole than on Earth. Its extreme rarity in the Earth's crust, comparable to that of platinum, is due partly to its formation of a volatile hydride that caused tellurium to be lost to space as a gas during the hot nebular formation of Earth.Anderson, Don L.; "Chemical Composition of the Mantle" in ''Theory of the Earth'', pp. 147-175 Tellurium-bearing compounds were first discovered in 1782 in a gold mine in Kleinschlatten, Transylvania (now Zlatna, Romania) by Austrian mineralogist Franz-Joseph Müller von Reichenstein, although it was Martin Heinrich Klaproth who named the new element in 1798 after the Latin 'earth'. Gold telluride minerals are ...
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Chemical Element
A chemical element is a species of atoms that have a given number of protons in their nuclei, including the pure substance consisting only of that species. Unlike chemical compounds, chemical elements cannot be broken down into simpler substances by any chemical reaction. The number of protons in the nucleus is the defining property of an element, and is referred to as its atomic number (represented by the symbol ''Z'') – all atoms with the same atomic number are atoms of the same element. Almost all of the baryonic matter of the universe is composed of chemical elements (among rare exceptions are neutron stars). When different elements undergo chemical reactions, atoms are rearranged into new compounds held together by chemical bonds. Only a minority of elements, such as silver and gold, are found uncombined as relatively pure native element minerals. Nearly all other naturally occurring elements occur in the Earth as compounds or mixtures. Air is primarily a mixture o ...
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Martin Heinrich Klaproth
Martin Heinrich Klaproth (1 December 1743 – 1 January 1817) was a German chemist. He trained and worked for much of his life as an apothecary, moving in later life to the university. His shop became the second-largest apothecary in Berlin, and the most productive artisanal chemical research center in Europe. Klaproth was a major systematizer of analytical chemistry, and an independent inventor of gravimetric analysis. His attention to detail and refusal to ignore discrepancies in results led to improvements in the use of apparatus. He was a major figure in understanding the composition of minerals and characterizing the elements. Klaproth discovered uranium (1789) and zirconium (1789). He was also involved in the discovery or co-discovery of titanium (1792), strontium (1793), cerium (1803), and chromium (1797) and confirmed the previous discoveries of tellurium (1798) and beryllium (1798). Klaproth was a member and director of the Berlin Academy of Sciences. H ...
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Garlic
Garlic (''Allium sativum'') is a species of bulbous flowering plant in the genus ''Allium''. Its close relatives include the onion, shallot, leek, chive, Allium fistulosum, Welsh onion and Allium chinense, Chinese onion. It is native to South Asia, Central Asia and northeastern Iran and has long been used as a seasoning worldwide, with a history of several thousand years of human consumption and use. It was known to ancient Egyptians and has been used as both a food flavoring and a traditional medicine. China produces 76% of the world's supply of garlic. Etymology The word ''garlic'' derives from Old English, ''garlēac'', meaning ''gar'' (spear) and leek, as a 'spear-shaped leek'. Description ''Allium sativum'' is a perennial flowering plant growing from a bulb. It has a tall, erect flowering stem that grows up to . The leaf blade is flat, linear, solid, and approximately wide, with an acute apex. The plant may produce pink to purple flowers from July to September in the Nort ...
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Dimethyl Telluride
Dimethyl telluride is an organotelluride compound, formula ( CH3)2 Te, also known by the abbreviation DMTe. This was the first material used to grow epitaxial cadmium telluride and mercury cadmium telluride using metalorganic vapour phase epitaxy. Dimethyl telluride as a product of microbial metabolism was first discovered in 1939. It is produced by some fungi and bacteria (''Penicillium brevicaule'', ''P. chrysogenum'', and '' P. notatum'' and the bacterium ''Pseudomonas fluorescens''). The toxicity of DMTe is unclear. It is produced by the body when tellurium or one of its compounds are ingested. It is noticeable by the garlic smelling breath it gives those exposed, similar to the effect of DMSO. Tellurium is known to be toxic Toxicity is the degree to which a chemical substance or a particular mixture of substances can damage an organism. Toxicity can refer to the effect on a whole organism, such as an animal, bacterium, or plant, as well as the effect on a subst .... ...
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Tellurocysteine
Tellurocysteine (in some publications referred to as Te-Cys) is an amino acid analogous to serine, cysteine and selenocysteine with tellurium in place of oxygen, sulfur or selenium in its side chain. It is not naturally found in organisms. Properties Perhaps due to its low bond energy with carbon (200 kJ/mol compared to 234 kJ/mol for selenium, or 272 kJ/mol for sulfur), tellurocysteine is not present in any known natural organisms and is hence relatively understudied in comparison to selenocysteine. Despite so, certain organisms such as fungi ''Aspergillus fumigatus'' is capable of incorporating tellurocysteine and telluromethionine into amino acids and proteins when exposed to a sulfur-free environment. It has been observed that when incorporated into glutathione transferase, tellurocysteine efficiently inhibited aminoacylation and increased the efficiency of glutathione peroxidase. Synthesis L-Tellurocysteine has been prepared from elemental tellurium by first reacting it wit ...
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Amino Acid
Amino acids are organic compounds that contain both amino and carboxylic acid functional groups. Although hundreds of amino acids exist in nature, by far the most important are the alpha-amino acids, which comprise proteins. Only 22 alpha amino acids appear in the genetic code. Amino acids can be classified according to the locations of the core structural functional groups, as Alpha and beta carbon, alpha- , beta- , gamma- or delta- amino acids; other categories relate to Chemical polarity, polarity, ionization, and side chain group type (aliphatic, Open-chain compound, acyclic, aromatic, containing hydroxyl or sulfur, etc.). In the form of proteins, amino acid '' residues'' form the second-largest component (water being the largest) of human muscles and other tissues. Beyond their role as residues in proteins, amino acids participate in a number of processes such as neurotransmitter transport and biosynthesis. It is thought that they played a key role in enabling life ...
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Technology-critical Element
A technology-critical element (TCE) is a chemical element that is critical to modern and emerging technologies. Technology-critical elements are elements for which a striking acceleration in usage has emerged, relative to past consumption. Many advanced engineering applications, such as clean-energy production, communications and computing, use emergent technologies that utilize numerous chemical elements. Other similar terms used in literature include: critical elements, critical materials, critical raw materials, energy critical elements and elements of security. In 2013, the U.S. Department of Energy (DOE) created the Critical Materials Institute (CMI) to address the issue. In 2015, the European COST Action TD1407 created a network of scientists working and interested on TCEs, from an environmental perspective to potential human health threats. A study estimated losses of 61 metals to help the development of circular economy strategies, showing that usespans of, often scarce, t ...
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Cadmium Telluride
Cadmium telluride (CdTe) is a stable crystalline compound formed from cadmium and tellurium. It is mainly used as the semiconducting material in cadmium telluride photovoltaics and an infrared optical window. It is usually sandwiched with cadmium sulfide to form a p–n junction solar PV cell. Applications CdTe is used to make thin film solar cells, accounting for about 8% of all solar cells installed in 2011. They are among the lowest-cost types of solar cell, although a comparison of total installed cost depends on installation size and many other factors, and has changed rapidly from year to year. The CdTe solar cell market is dominated by First Solar. In 2011, around 2 GWp of CdTe solar cells were produced; For more details and discussion see cadmium telluride photovoltaics. CdTe can be alloyed with mercury to make a versatile infrared detector material (HgCdTe). CdTe alloyed with a small amount of zinc makes an excellent solid-state X-ray and gamma ray detector ( Cd ...
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CdTe Solar Panel
Cadmium telluride (CdTe) photovoltaics is a photovoltaic (PV) technology based on the use of cadmium telluride in a thin semiconductor layer designed to absorb and convert sunlight into electricity. Cadmium telluride PV is the only thin film technology with lower costs than conventional solar cells made of crystalline silicon in multi-kilowatt systems.K. Zweibel, J. Mason, V. Fthenakis,A Solar Grand Plan, ''Scientific American'', Jan 2008. CdTe PV is the cheapest example of PV technologies and prices are about 16¢/kWh with US Southwest sunlight. , on a lifecycle basis, CdTe PV has the smallest carbon footprint, lowest water use and shortest energy payback time of any current photo voltaic technology. CdTe's energy payback time of less than a year allows for faster carbon reductions without short-term energy deficits. The toxicity of cadmium is an environmental concern during production and when the panels are disposed of. Some of this might be mitigated by recycling of CdT ...
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Machinability
Machinability is the ease with which a metal can be cut (machined) permitting the removal of the material with a satisfactory finish at low cost.Degarmo, p. 542. Materials with good machinability (free machining materials) require little power to cut, can be cut quickly, easily obtain a good finish, and do not cause significant wear on the tooling. Factors that typically improve a material's performance often degrade its machinability, presenting a significant engineering challenge. Machinability can be difficult to predict due to the large number of variables involved in the machining process. Two sets of factors are the condition of work materials and the physical properties of work materials. The condition of the work material includes at least eight factors: microstructure, grain size, heat treatment, chemical composition, fabrication, hardness, yield strength, and tensile strength.Schneider, "Machinability." Physical properties are those of the individual material groups, such ...
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Alloy
An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, opacity (optics), opacity, and lustre (mineralogy), luster, but may have properties that differ from those of the pure metals, such as increased strength or hardness. In some cases, an alloy may reduce the overall cost of the material while preserving important properties. In other cases, the mixture imparts synergistic properties to the constituent metal elements such as corrosion resistance or mechanical strength. Alloys are defined by a metallic bonding character. The alloy constituents are usually measured by mass percentage for practical applications, and in Atomic ratio, atomic fraction for basic science studies. Alloys are usually classified as substitutional or interstitial alloys, depending on the atomic arrangement that forms the ...
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Tellurium Copper
Tellurium copper is an alloy of copper and tellurium. Tellurium improves the machinability of copper. Overview Tellurium is usually added to copper to improve machinability ("free cutting"). ASTM specification B301 has 0.5% tellurium; at concentrations of up to 0.75% machinability is improved while electrical conductivity and hot working behavior is maintained. Mechanical properties are similar to ''tough pitch copper'', while machinability is similar to brass - the hardness of the alloy is increased by precipitation of the copper telluride: weissite. Tellurium copper is not suited to welding, but it can be welded with gas shielded arc welding or resistance welding. It can be readily soft soldered, silver soldered, or brazed. Tellurium copper can be used as the electrode in electrical discharge machining (EDM) - the alloy is used to replace copper when grinding wheel Grinding wheels contains abrasive compounds for grinding and abrasive machining operations. Such wheels are a ...
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