Schrödinger Equation
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Schrödinger Equation
The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. It is a key result in quantum mechanics, and its discovery was a significant landmark in the development of the subject. The equation is named after Erwin Schrödinger, who postulated the equation in 1925, and published it in 1926, forming the basis for the work that resulted in his Nobel Prize in Physics in 1933. Conceptually, the Schrödinger equation is the quantum counterpart of Newton's second law in classical mechanics. Given a set of known initial conditions, Newton's second law makes a mathematical prediction as to what path a given physical system will take over time. The Schrödinger equation gives the evolution over time of a wave function, the quantum-mechanical characterization of an isolated physical system. The equation can be derived from the fact that the time-evolution operator must be unitary, and must therefore be generated by t ...
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Introduction To Quantum Mechanics
Quantum mechanics is the study of matter and its interactions with energy on the scale of atomic and subatomic particles. By contrast, classical physics explains matter and energy only on a scale familiar to human experience, including the behavior of astronomical bodies such as the moon. Classical physics is still used in much of modern science and technology. However, towards the end of the 19th century, scientists discovered phenomena in both the large ( macro) and the small ( micro) worlds that classical physics could not explain. The desire to resolve inconsistencies between observed phenomena and classical theory led to two major revolutions in physics that created a shift in the original scientific paradigm: the ''theory of relativity'' and the development of ''quantum mechanics''. This article describes how physicists discovered the limitations of classical physics and developed the main concepts of the quantum theory that replaced it in the early decades of the 20th c ...
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Path Integral Formulation
The path integral formulation is a description in quantum mechanics that generalizes the action principle of classical mechanics. It replaces the classical notion of a single, unique classical trajectory for a system with a sum, or functional integral, over an infinity of quantum-mechanically possible trajectories to compute a quantum amplitude. This formulation has proven crucial to the subsequent development of theoretical physics, because manifest Lorentz covariance (time and space components of quantities enter equations in the same way) is easier to achieve than in the operator formalism of canonical quantization. Unlike previous methods, the path integral allows one to easily change coordinates between very different canonical descriptions of the same quantum system. Another advantage is that it is in practice easier to guess the correct form of the Lagrangian of a theory, which naturally enters the path integrals (for interactions of a certain type, these are ''coordinat ...
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John Von Neumann
John von Neumann (; hu, Neumann János Lajos, ; December 28, 1903 – February 8, 1957) was a Hungarian-American mathematician, physicist, computer scientist, engineer and polymath. He was regarded as having perhaps the widest coverage of any mathematician of his time and was said to have been "the last representative of the great mathematicians who were equally at home in both pure and applied mathematics". He integrated pure and applied sciences. Von Neumann made major contributions to many fields, including mathematics (foundations of mathematics, measure theory, functional analysis, ergodic theory, group theory, lattice theory, representation theory, operator algebras, matrix theory, geometry, and numerical analysis), physics (quantum mechanics, hydrodynamics, ballistics, nuclear physics and quantum statistical mechanics), economics ( game theory and general equilibrium theory), computing ( Von Neumann architecture, linear programming, numerical meteo ...
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David Hilbert
David Hilbert (; ; 23 January 1862 – 14 February 1943) was a German mathematician, one of the most influential mathematicians of the 19th and early 20th centuries. Hilbert discovered and developed a broad range of fundamental ideas in many areas, including invariant theory, the calculus of variations, commutative algebra, algebraic number theory, the foundations of geometry, spectral theory of operators and its application to integral equations, mathematical physics, and the foundations of mathematics (particularly proof theory). Hilbert adopted and defended Georg Cantor's set theory and transfinite numbers. In 1900, he presented a collection of problems that set the course for much of the mathematical research of the 20th century. Hilbert and his students contributed significantly to establishing rigor and developed important tools used in modern mathematical physics. Hilbert is known as one of the founders of proof theory and mathematical logic. Life Early life and edu ...
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Mathematical Formulation Of Quantum Mechanics
The mathematical formulations of quantum mechanics are those mathematical formalisms that permit a rigorous description of quantum mechanics. This mathematical formalism uses mainly a part of functional analysis, especially Hilbert spaces, which are a kind of linear space. Such are distinguished from mathematical formalisms for physics theories developed prior to the early 1900s by the use of abstract mathematical structures, such as infinite-dimensional Hilbert spaces ( ''L''2 space mainly), and operators on these spaces. In brief, values of physical observables such as energy and momentum were no longer considered as values of functions on phase space, but as eigenvalues; more precisely as spectral values of linear operators in Hilbert space. These formulations of quantum mechanics continue to be used today. At the heart of the description are ideas of ''quantum state'' and ''quantum observables'', which are radically different from those used in previous models of physical r ...
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Action (physics)
In physics, action is a scalar quantity describing how a physical system has dynamics (physics), changed over time. Action is significant because the equations of motion of the system can be derived through the principle of stationary action. In the simple case of a single particle moving with a constant velocity (uniform linear motion), the action is the momentum of the particle times the distance it moves, integral (mathematics), added up along its path; equivalently, action is twice the particle's kinetic energy times the duration for which it has that amount of energy. For more complicated systems, all such quantities are combined. More formally, action is a functional (mathematics), mathematical functional which takes the trajectory (also called path or history) of the system as its argument and has a real number as its result. Generally, the action takes different values for different paths. Action has dimensional analysis, dimensions of energy × time or momentu ...
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Planck Constant
The Planck constant, or Planck's constant, is a fundamental physical constant of foundational importance in quantum mechanics. The constant gives the relationship between the energy of a photon and its frequency, and by the mass-energy equivalence, the relationship between mass and frequency. Specifically, a photon's energy is equal to its frequency multiplied by the Planck constant. The constant is generally denoted by h. The reduced Planck constant, or Dirac constant, equal to the constant divided by 2 \pi, is denoted by \hbar. In metrology it is used, together with other constants, to define the kilogram, the SI unit of mass. The SI units are defined in such a way that, when the Planck constant is expressed in SI units, it has the exact value The constant was first postulated by Max Planck in 1900 as part of a solution to the ultraviolet catastrophe. At the end of the 19th century, accurate measurements of the spectrum of black body radiation existed, but the distribut ...
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Imaginary Unit
The imaginary unit or unit imaginary number () is a solution to the quadratic equation x^2+1=0. Although there is no real number with this property, can be used to extend the real numbers to what are called complex numbers, using addition and multiplication. A simple example of the use of in a complex number is 2+3i. Imaginary numbers are an important mathematical concept; they extend the real number system \mathbb to the complex number system \mathbb, in which at least one root for every nonconstant polynomial exists (see Algebraic closure and Fundamental theorem of algebra). Here, the term "imaginary" is used because there is no real number having a negative square. There are two complex square roots of −1: and -i, just as there are two complex square roots of every real number other than zero (which has one double square root). In contexts in which use of the letter is ambiguous or problematic, the letter or the Greek \iota is sometimes used instead. For example, ...
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Scalar Potential
In mathematical physics, scalar potential, simply stated, describes the situation where the difference in the potential energies of an object in two different positions depends only on the positions, not upon the path taken by the object in traveling from one position to the other. It is a scalar field in three-space: a directionless value (scalar) that depends only on its location. A familiar example is potential energy due to gravity. A ''scalar potential'' is a fundamental concept in vector analysis and physics (the adjective ''scalar'' is frequently omitted if there is no danger of confusion with ''vector potential''). The scalar potential is an example of a scalar field. Given a vector field , the scalar potential is defined such that: : \mathbf = -\nabla P = - \left( \frac, \frac, \frac \right), where is the gradient of and the second part of the equation is minus the gradient for a function of the Cartesian coordinates . In some cases, mathematicians may use ...
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Complex Number
In mathematics, a complex number is an element of a number system that extends the real numbers with a specific element denoted , called the imaginary unit and satisfying the equation i^= -1; every complex number can be expressed in the form a + bi, where and are real numbers. Because no real number satisfies the above equation, was called an imaginary number by René Descartes. For the complex number a+bi, is called the , and is called the . The set of complex numbers is denoted by either of the symbols \mathbb C or . Despite the historical nomenclature "imaginary", complex numbers are regarded in the mathematical sciences as just as "real" as the real numbers and are fundamental in many aspects of the scientific description of the natural world. Complex numbers allow solutions to all polynomial equations, even those that have no solutions in real numbers. More precisely, the fundamental theorem of algebra asserts that every non-constant polynomial equation with real or ...
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Derivative
In mathematics, the derivative of a function of a real variable measures the sensitivity to change of the function value (output value) with respect to a change in its argument (input value). Derivatives are a fundamental tool of calculus. For example, the derivative of the position of a moving object with respect to time is the object's velocity: this measures how quickly the position of the object changes when time advances. The derivative of a function of a single variable at a chosen input value, when it exists, is the slope of the tangent line to the graph of the function at that point. The tangent line is the best linear approximation of the function near that input value. For this reason, the derivative is often described as the "instantaneous rate of change", the ratio of the instantaneous change in the dependent variable to that of the independent variable. Derivatives can be generalized to functions of several real variables. In this generalization, the derivativ ...
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Calculus
Calculus, originally called infinitesimal calculus or "the calculus of infinitesimals", is the mathematical study of continuous change, in the same way that geometry is the study of shape, and algebra is the study of generalizations of arithmetic operations. It has two major branches, differential calculus and integral calculus; the former concerns instantaneous Rate of change (mathematics), rates of change, and the slopes of curves, while the latter concerns accumulation of quantities, and areas under or between curves. These two branches are related to each other by the fundamental theorem of calculus, and they make use of the fundamental notions of convergence (mathematics), convergence of infinite sequences and Series (mathematics), infinite series to a well-defined limit (mathematics), limit. Infinitesimal calculus was developed independently in the late 17th century by Isaac Newton and Gottfried Wilhelm Leibniz. Later work, including (ε, δ)-definition of limit, codify ...
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